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Citation: Peiran ZHAO, Yuqian LIU, Cheng HE, Chunying DUAN. A functionalized Eu3+ metal-organic framework for selective fluorescent detection of pyrene[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355 shu

A functionalized Eu3+ metal-organic framework for selective fluorescent detection of pyrene

  • State Key Lab of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

  • Corresponding author: Chunying DUAN, cyduan@dlut.edu.cn
  • Received Date: 26 September 2023
    Revised Date: 11 January 2024

Figures(20)

  • A functional 3D lanthanide metal-organic framework (Eu-4L) was successfully designed and synthesized by solvothermal method. The ligand of Eu-4L is a kind of diphenylamine tetracarboxylic acid derivative (named H4L). The specific surface area of Eu-4L was high, which made Eu-4L have an excellent 3D structure. Eu-4L had good thermostability and can remain stable in water of pH from 3 to 11. Eu-4L can be used as a fluorescent probe for sensing pyrene. The limit of detection of Eu-4L for sensing pyrene was 5 μmol·L-1, which displays high sensitivity. Eu-4L is also a kind of recyclable material. The fluorescence sensing mechanism of Eu-4L for sensing pyrene belongs to the static mechanism. Moreover, the selectivity and competition of Eu-4L are also discussed.
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