Citation: Tiantian MA, Sumei LI, Chengyu ZHANG, Lu XU, Yiyan BAI, Yunlong FU, Wenjuan JI, Haiying YANG. Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351 shu

Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine

Tiantian MA ¹ ,
Sumei LI ¹ ,
Chengyu ZHANG ¹ ,
Lu XU ¹ ,
Yiyan BAI ² ,
Yunlong FU ¹ ,
Wenjuan JI ^1,, ,
Haiying YANG ^{1, 2,,}

1.
Key Laboratory of Magnetic Molecules and Magnetic Information Materials, College of Chemistry and Materials Science, Shanxi Normal University, Taiyuan 030032, China
2.
Department of Applied Chemistry, Yuncheng University, Yuncheng, Shanxi 044000, China

Corresponding author: Wenjuan JI, jiwj@sxnu.edu.cn Haiying YANG, hyyang@ycu.edu.cn
Received Date: 22 September 2023
Revised Date: 30 January 2024

Figures(11)

A Cd-based metal-organic framework (MOF) [Cd(BDC)(BPZ)(H₂O)]_n (1), where BPZ=3,3′,5,5′-tetramethyl-1H,1′H-4,4′-bipyrazole and H₂BDC=terephthalic acid, was designed and synthesized. Compound 1 possesses a 3D pore structure with —CH₃ groups and free carboxyl oxygen atoms on the pore walls. The presence of methyl groups significantly enhances the hydrophobicity and stability of MOF. Moreover, the methyl group and uncoordinated carboxyl oxygen atoms can interact with dopamine (DA) molecules through hydrogen bonding or van der Waals interactions, endowing in 1 with sensitive electrochemical sensing properties for DA. The differential pulse voltammetry (DPV) test of the prepared 1/GCE electrode showed that it had a wide linear range of 0.4 to 764.7 μmol·L^-1 for detecting DA, and the detection limit was as low as 56.8 nmol·L^-1. The DPV response current of the electrode remained unchanged in the presence of common interferents. When the electrode was applied for real sample analysis, the recovery rates ranged from 95.23% to 100.90%.
- metal-organic framework,
- electrochemical sensing,
- dopamine
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