Citation: Bo YANG, Gongxuan LÜ, Jiantai MA. Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346 shu

Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen

Bo YANG ^{1, 2, 3} ,
Gongxuan LÜ ^1,, ,
Jiantai MA ³

1.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: Gongxuan LÜ, gxlu@lzb.ac.cn
Received Date: 16 September 2023
Revised Date: 16 January 2024

Figures(12)

Nickel phosphide (Ni₂P) modified phosphorus doped gallium oxide (Ga₂O₃) (x-Ni₂P/Ga₂O₃-P_y, x represents the molar ratio of Ni²⁺ and Ga₂O₃, y represents the molar ratio of NaH₂PO·H₂O and Ga₂O₃) photocatalyst was prepared by impregnation and low temperature phosphating method using Ga₂O₃ semiconductor as a precursor. 5%-Ni₂P/Ga₂O₃-P₆ exhibits excellent photocatalytic hydrogen evolution activity in pure water and has a photo quantum efficiency of 0.22% under 430 nm monochromatic light irradiation. The mechanism study shows that phosphorus doping and Ni₂P cocatalyst modification extend the photo-response range and promote carrier separation and migration efficiency. The long-term photocatalytic stability is better than that of a non-phosphating catalyst.
- gallium oxide,
- phosphorus doping,
- nickel phosphide,
- photocatalytic hydrogen evolution
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沈阳化工大学材料科学与工程学院沈阳 110142