Citation: Yujia LI, Tianyu WANG, Fuxue WANG, Chongchen WANG. Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314 shu

Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole

Yujia LI ^{1, 2} ,
Tianyu WANG ^{1, 2} ,
Fuxue WANG ^{1, 2} ,
Chongchen WANG ^{1, 2,,}

1.
Beijing Key Laboratory of Functional Materials for Building Structure and Environment Remediation, Beijing University of Civil Engineering and Architecture, Beijing 100044, China
2.
School of Environment and Energy Engineering, Beijing University of Civil Engineering and Architecture, Beijing 100044, China

Corresponding author: Chongchen WANG, chongchenwang@126.com
Received Date: 18 August 2023
Revised Date: 6 January 2024

Figures(13)

A series of MIL-100(Fe)/BiOBr direct Z-scheme heterojunctions was fabricated by the in-situ precipitation method. The crystal structures, micromorphology, optical adsorption property, and chemical states were estimated by powder X-ray diffraction (PXRD), Fourier transforms infrared (FTIR) spectra, UV-Vis diffuse reflectance spectra (UV-Vis DRS), scanning electron microscopy (SEM), high-resolution transmission electron microscope (HRTEM) and X-ray photoelectron spectra (XPS). The performance of photo-Fenton degradation for sulfamethoxazole (SMX) under low-powered light emitting diode lamp irradiation was explored. The catalytic degradation efficiency of SMX (5 mg·L^-1) in the optimal reaction system (MB-7/Vis/H₂O₂, MB-7 was prepared when the mass of MIL-100 (Fe) was 70% of the mass of BiOBr) could reach 99.8% upon 70 min illumination. Meanwhile, the effects of H₂O₂ concentration, catalyst dosage, pH, and co-existing inorganic anions on SMX removal over MB-7/Vis/H₂O₂ were studied. The removal efficiency of SMX could reach above 95% after five consecutive operations, suggesting that MB-7 had good stability and reusability. The possible catalytic mechanism was unraveled by photoluminescence (PL) spectra, electrochemical measurements, radical trapping experiments, and electronic spin resonance (ESR) technique. The enhanced photo-Fenton reactivity could be attributed to the fabrication of heterostructures accelerated separation photocarriers and then induced the generation of reactive species and Fe³⁺/Fe²⁺ redox cycle.
- photo-Fenton,
- heterojunction,
- MIL-100(Fe),
- BiOBr,
- sulfamethoxazole
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