Citation: Limei CHEN, Mengfei ZHAO, Lin CHEN, Ding LI, Wei LI, Weiye HAN, Hongbin WANG. Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312 shu

Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material

Limei CHEN ¹ ,
Mengfei ZHAO ¹ ,
Lin CHEN ¹ ,
Ding LI ¹ ,
Wei LI ¹ ,
Weiye HAN ¹ ,
Hongbin WANG ^2,,

1.
College of Engineering and Technology, Jilin Agricultural University, Changchun 130118, China
2.
College of Resources and Environment, Jilin Agricultural University, Changchun 130118, China

Corresponding author: Hongbin WANG, wanghongbin@jlau.edu.cn
Received Date: 17 August 2023
Revised Date: 4 January 2024

Figures(8)

Through alkali treatment, the pore structure of diatomite (DIA) was optimized, the porosity was increased, and the paraffin loading was increased. A novel paraffin/alkali-modified DIA/expanded graphite (EG-alDIAP) composite with stable properties was prepared by direct impregnation method. The relationship between structure and properties of the material was studied. The results showed that the paraffin loading of the composite phase change material increased from 47.4% to 61.1%, thereby improving the heat storage performance of the composite material. The addition of expanded graphite (EG) to the modified diatomite improved the heat transfer capacity of the composite material. The addition of mass fraction of 10% EG increased the thermal conductivity by 113% (from 0.276 to 0.589 W·m^-1·K^-1). With the increase of EG content, the latent heat of the composite phase change material increased slightly, but the chemical compatibility and stability did not change significantly. The paraffin/alkali-modified DIA composite containing 10% expanded graphite had reliable energy storage, good temperature regulation performance and heat storage and release capacity.
- composite phase change material,
- paraffin,
- alkaline modified diatomite,
- expanded graphite
1. [1]
  Omrany H, Ghaffarianhoseini A, Ghaffarianhoseini A, Raahemifar K, Tookey J. Application of passive wall systems for improving the energy efficiency in buildings: A comprehensive review[J]. Renew. Sust. Energ. Rev., 2016,62:1252-1269. doi: 10.1016/j.rser.2016.04.010
2. [2]
  Pacheco-Torgal F. High tech startup creation for energy efficient built environment[J]. Renew. Sust. Energ. Rev., 2017,71:618-629. doi: 10.1016/j.rser.2016.12.088
3. [3]
  Guo X, Zhang S D, Cao J Z. An energy-efficient composite by using expanded graphite stabilized paraffin as phase change material[J]. Compos. Pt. A-Appl. Sci. Manuf., 2018,107:83-93. doi: 10.1016/j.compositesa.2017.12.032
4. [4]
  Niu M Y, Li X Y, Ouyang J, Yang H M. Lithium orthosilicate with halloysite as silicon source for high temperature CO₂ capture[J]. RSC Adv., 2016,6(50):44106-44112. doi: 10.1039/C6RA05004B
5. [5]
  Ding W J, Yang H M, Ouyang J, Long H M. Modified wollastonite sequestrating CO₂ and exploratory application of the carbonation products[J]. RSC Adv., 2016,6(81):78090-78099. doi: 10.1039/C6RA13908F
6. [6]
  Li M, Wu Z S. A review of intercalation composite phase change material: Preparation, structure and properties[J]. Renew. Sust. Energ. Rev., 2012,16(4):2094-2101. doi: 10.1016/j.rser.2012.01.016
7. [7]
  Sarı A. Thermal energy storage characteristics of bentonite-based composite PCMs with enhanced thermal conductivity as novel thermal storage building materials[J]. Energ. Convers. Manage., 2016,117:132-141. doi: 10.1016/j.enconman.2016.02.078
8. [8]
  Zhou X F, Xiao H N, Feng J, Zhang C R, Jiang Y G. Preparation and thermal properties of paraffin/porous silica ceramic composite[J]. Compos. Sci. Technol., 2009,69(7/8):1246-1249.
9. [9]
  Chen C Z, Liu W M, Wang H W, Peng K L. Synthesis and performances of novel solid-solid phase change materials with hexahydroxy compounds for thermal energy storage[J]. Appl. Energy, 2015,152:198-206. doi: 10.1016/j.apenergy.2014.12.004
10. [10]
  Da Cunha J P, Eames P. Thermal energy storage for low and medium temperature applications using phase change materials-A review[J]. Appl. Energy, 2016,177:227-238. doi: 10.1016/j.apenergy.2016.05.097
11. [11]
  Zheng H B, Song C, Bao C, Liu X L, Xuan Y M, Li Y L, Ding Y L. Dark calcium carbonate particles for simultaneous full-spectrum solar thermal conversion and large-capacity thermochemical energy storage[J]. Sol. Energy Mater. Sol. Cells, 2020,207:110364-110364. doi: 10.1016/j.solmat.2019.110364
12. [12]
  Milián Y E, Gutierrez A, Grageda M, Ushak S. A review on encapsulation techniques for inorganic phase change materials and the influence on their thermophysical properties[J]. Renew. Sust. Energ. Rev., 2017,73:983-999. doi: 10.1016/j.rser.2017.01.159
13. [13]
  Yang Z W, Li J H, Luan X Z, Song S. Effects of acid leaching and organic intercalation on the thermophysical properties of paraffin/expanded vermiculite composite phase change materials[J]. Appl. Clay Sci., 2020,196105754. doi: 10.1016/j.clay.2020.105754
14. [14]
  HU D H, XU X Y, LIN K, LI Q. Study on heat conductivity of paraffin/expanded graphite/graphite sheet composite material[J]. Journal of Engineering Thermophysics, 2021,42(9):2414-2418.
15. [15]
  LIU Z H, ZHANG X S, WANG C L, ZHANG M X. Experimental study on melting performance of paraffin and paraffin/expanded graphite[J]. CIESC Journal, 2020,71(7):3362-3371.
16. [16]
  Tian G H, Lv H L, Huang J E, Liu P, Feng W. Preparation and thermal features of composite paraffin room temperature phase change mortar[J]. J. Test. Eval., 2019,47(1):511-524. doi: 10.1520/JTE20160513
17. [17]
  LIN K, XU X Y, LI Q, HU D H. Study on thermal conductivity of paraffin‑expanded graphite composite phase change materials[J]. CIESC Journal, 2021,72(8):4425-4432.
18. [18]
  Qian T T, Li J H, Deng Y. Pore structure modified diatomite-supported PEG composites for thermal energy storage[J]. Sci. Rep., 2016,6(1)32392. doi: 10.1038/srep32392
19. [19]
  Lv P Z, Liu C Z, Rao Z H. Experiment study on the thermal properties of paraffin/kaolin thermal energy storage form-stable phase change materials[J]. Appl. Energy, 2016,182:475-487. doi: 10.1016/j.apenergy.2016.08.147
20. [20]
  Korunic Z. Diatomaceous earths, a group of natural insecticides[J]. Stored Prod. Res., 1998,34(3/4):87-97.
21. [21]
  Luo Y, Xiong S Y, Huang J T, Zhang F, Li C C, Min Y G, Peng R T, Liu Y D. Preparation, characterization and performance of paraffin/sepiolite composites as novel shape-stabilized phase change materials for thermal energy storage[J]. Sol. Energy Mater. Sol. Cells, 2021,231111300. doi: 10.1016/j.solmat.2021.111300
22. [22]
  MENG D, WANG A Q, YANG J. Preparation, encapsulation and characterization of paraffin/expanded perlite form-stable composite phase change materials[J]. Journal of Functional Materials, 2019,50(11):11194-11198.
23. [23]
  Karaman S, Karaipekli A, Sari A, Bicer A. Polyethylene glycol (PEG)/diatomite composite as a novel form-stable phase change material for thermal energy storage[J]. Sol. Energy Mater. Sol. Cells, 2011,95(7):1647-1653. doi: 10.1016/j.solmat.2011.01.022
24. [24]
  Xu B W, Li Z J. Paraffin/diatomite composite phase change material incorporated cement-based composite for thermal energy storage[J]. Appl. Energy, 2013,105:229-237. doi: 10.1016/j.apenergy.2013.01.005
25. [25]
  Nomura T, Okinaka N, Akiyama T. Impregnation of porous material with phase change material for thermal energy storage[J]. Mater. Chem. Phys., 2009,115(2/3):846-850.
26. [26]
  Sarı A, Biçer A. Thermal energy storage properties and thermal reliability of some fatty acid esters/building material composites as novel form-stable PCMs[J]. Sol. Energy Mater. Sol. Cells, 2012,101:114-122. doi: 10.1016/j.solmat.2012.02.026
27. [27]
  GUO X Q, DENG X C, ZHU C L, FU X, WANG R R, MA W X, FAN J, ZUO F T, QING B J. Preparation and adsorption properties for Cs⁺ of modified diatomite-supported copper hexacyanoferrate composite[J]. Chinese J. Inorg. Chem., 2023,39(5):815-829.
28. [28]
  Zhang G L, Cai D Q, Wang M, Zhang C L, Zhang J, Wu Z Y. Microstructural modification of diatomite by acid treatment, high-speed shear, and ultrasound[J]. Microporous Mesoporous Mat., 2013,165:106-112. doi: 10.1016/j.micromeso.2012.08.005
29. [29]
  Cao L, Tang F, Fang G Y. Preparation and characteristics of microencapsulated palmitic acid with TiO₂ shell as shape-stabilized thermal energy storage materials[J]. Sol. Energy Mater. Sol. Cells, 2014,123:183-188. doi: 10.1016/j.solmat.2014.01.023
30. [30]
  LI G, OUYANG T, JIANG C, CHEN Y B. Preparation and characterization of paraffin phase change compositesreinforced by carbon fiber-graphite nanoplatelets network[J]. Acta Materiae Compositae Sinica, 2020,37(5):1130-1137.
31. [31]
  Wang J F, Xie H Q, Xin Z, Li Y, Yin C. Investigation on thermal properties of heat storage composites containing carbon fibers[J]. J. Appl. Phys., 2011,110(9)094302. doi: 10.1063/1.3656991
32. [32]
  Yin Z Y, Huang Z H, Wen R L, Zhang X G, Tan B, Liu Y G, Wu X W, Fang M H. Preparation and thermal properties of phase change materials based on paraffin with expanded graphite and carbon foams prepared from sucroses[J]. RSC Adv., 2016,6(97):95085-95091. doi: 10.1039/C6RA13758J
33. [33]
  HU W S, ZHANG S J, ZHANG C J, LUO J H, YANG F, SUN P F. Experiment on heat storage and release characteristics of GR/paraffin composite phasechange materials based on solar energy heating[J]. New Chemical Materials, 2020,48(3):119-124.
34. [34]
  GAO R, WANG Z Y, WANG L, CHEN P, LIU S, MA Z P, SHAO G J. Ni₂P nanosheets on graphene as sulfur-based composite cathode material for lithium-sulfur batteries[J]. Chinese J. Inorg. Chem., 2022,38(4):685-694.
35. [35]
  Cheng F, Wen R L, Huang Z H, Fang M H, Liu Y G, Wu X W, Min X. Preparation and analysis of lightweight wall material with expanded graphite (EG)/paraffin composites for solar energy storage[J]. Appl. Therm. Eng., 2017,120:107-114. doi: 10.1016/j.applthermaleng.2017.03.129
36. [36]
  Tang X H, Zhu B, Xu M H, Zhang W, Yang Z, Zhang Y F, Yin G L, He D N, Wei H, Zhai X Q. Shape-stabilized phase change materials based on fatty acid eutectics/expanded graphite composites for thermal storage[J]. Energy Build., 2015,109:353-360. doi: 10.1016/j.enbuild.2015.09.074
37. [37]
  ZHAO J G, GUO Q G, LIU L, WEI X H, ZHANG J X. Polyethylene glycol/expanded graphite phase change composites for thermal storage[J]. Modern Chemical Industry, 2008,28(9):46-47.
38. [38]
  WANG J J, XU X L, LIANG K Y, WANG G. Thermal conductivity enhancement of porous shape-stabilized composite phase change materials for thermal energy storage applications: A review[J]. Chinese Journal of Engineering, 2020,42(1):26-38.
39. [39]
  Zhang N, Yuan Y P, Wang X, Cao X L, Yang X J, Hu S C. Preparation and characterization of lauric-myristic-palmitic acid ternary eutectic mixtures/expanded graphite composite phase change material for thermal energy storage[J]. Chem. Eng. J., 2013,231:214-219. doi: 10.1016/j.cej.2013.07.008
40. [40]
  Wen R L, Zhang X G, Huang Z H, Fang M H, Liu Y G, Wu X W, Min X, Gao W, Huang S F. Preparation and thermal properties of fatty acid/diatomite form-stable composite phase change material for thermal energy storage[J]. Sol. Energy Mater. Sol. Cells, 2018,178:273-279. doi: 10.1016/j.solmat.2018.01.032
41. [41]
  Karakassides M A, Gournis D, Petridis D. An infrared reflectance study of Si—O vibrations in thermally treated alkali-saturated montmorillonites[J]. Clay Min., 1999,34(3):429-438. doi: 10.1180/000985599546334
42. [42]
  Li C C, Wang M F, Xie B S, Ma H, Chen J. Enhanced properties of diatomite-based composite phase change materials for thermal energy storage[J]. Renew. Energy, 2020,147:265-274. doi: 10.1016/j.renene.2019.09.001
43. [43]
  Yang D, Shi S L, Xiong L, Guo H J, Zhang H R, Chen X F, Wang C, Chen X D. Paraffin/palygorskite composite phase change materials for thermal energy storage[J]. Sol. Energy Mater. Sol. Cell, 2016,144:228-234. doi: 10.1016/j.solmat.2015.09.002
44. [44]
  Atinafu D G, Dong W J, Huang X B, Gao H Y, Wang J J, Yang M, Wang G. One-pot synthesis of light-driven polymeric composite phase change materials based on N-doped porous carbon for enhanced latent heat storage capacity and thermal conductivity[J]. Sol. Energy Mater. Sol. Cells, 2018,179:392-400. doi: 10.1016/j.solmat.2018.01.035
45. [45]
  YAN J S, HAN X Y, DANG Z H, LI J G, HE X M. Preparation and performance of paraffin/expanded graphite/graphene composite phase change heat storage material[J]. Chem. J. Chinese Universities, 2022,43(6):326-332.
46. [46]
  Fang G Y, Li H, Chen Z, Liu X. Preparation and properties of palmitic acid/SiO₂ composites with flame retardant as thermal energy storage materials[J]. Sol. Energy Mater. Sol. Cells, 2011,95(7):1875-1881. doi: 10.1016/j.solmat.2011.02.010
47. [47]
  Zhong L M, Zhang X W, Luan Y, Wang G, Feng Y H, Feng D L. Preparation and thermal properties of porous heterogeneous composite phase change materials based on molten salts/expanded graphite[J]. Sol. Energy, 2014,107:63-73. doi: 10.1016/j.solener.2014.05.019
48. [48]
  Feng L L, Zhao W, Zheng J, Frisoc S, Song P, Li X G. The shape-stabilized phase change materials composed of polyethylene glycol and various mesoporous matrices (AC, SBA-15 and MCM-41)[J]. Sol. Energy Mater. Sol. Cells, 2011,95(12):3550-3556. doi: 10.1016/j.solmat.2011.08.020
49. [49]
  Li X Y, Sanjayan J G, Wilson J L. Fabrication and stability of form-stable diatomite/paraffin phase change material composites[J]. Energy Build., 2014,76:284-294. doi: 10.1016/j.enbuild.2014.02.082
50. [50]
  Alkan C, Sari A. Fatty acid/poly (methyl methacrylate) (PMMA) blends as form-stable phase change materials for latent heat thermal energy storage[J]. Sol. Energy, 2008,82(2):118-124. doi: 10.1016/j.solener.2007.07.001
51. [51]
  Wang Q, Zhang J, Da J, Zhao H, Ran K. Study on the thermal properties of paraffin/expansion perlite composite phase change mortar[J]. Adv. Mater. Res., 2012,374:1274-1277.
52. [52]
  Yang X J, Yuan Y P, Zhang N, Cao X L, Liu C. Preparation and properties of myristic-palmitic-stearic acid/expanded graphite composites as phase change materials for energy storage[J]. Sol. Energy, 2014,99:259-266. doi: 10.1016/j.solener.2013.11.021
53. [53]
  Lu Z Y, Xu B W, Zhang J R, Zhu Y, Sun G X, Li Z J. Preparation and characterization of expanded perlite/paraffin composite as form-stable phase change material[J]. Sol. Energy, 2014,108:460-466. doi: 10.1016/j.solener.2014.08.008
54. [54]
  LIN Z Q, ZHAO Z X, SONG J L, LIU Z J, TANG Z F. Preparation and heat transfer and storage properties of low melting point chloride/expanded graphite composites[J]. Journal of Functional Materials, 2023,54(10):10180-10185.
55. [55]
  Yang Z W, Li J H, Luan X Z, Song S. Effects of acid leaching and organic intercalation on the thermophysical properties of paraffin/expanded vermiculite composite phase change materials[J]. Appl. Clay Sci., 2020,196105754. doi: 10.1016/j.clay.2020.105754
56. [56]
  Li C C, Zhang B, Xie B S, Zhao X B, Chen J, Chen Z S, Long Y. Stearic acid/expanded graphite as a composite phase change thermal energy storage material for tankless solar water heater[J]. Sust. Cities Soc., 2019,44:458-464. doi: 10.1016/j.scs.2018.10.041
57. [57]
  Jiang F Y, Wang X D, Wu D Z. Design and synthesis of magnetic microcapsules based on n-eicosane core and Fe₃O₄/SiO₂ hybrid shell for dual-functional phase change materials[J]. Appl. Energy, 2014,134:456-468. doi: 10.1016/j.apenergy.2014.08.061
1. [1]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
2. [2]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
3. [3]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
4. [4]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
5. [5]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
6. [6]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
7. [7]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
8. [8]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
9. [9]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
10. [10]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
11. [11]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
12. [12]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
13. [13]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
14. [14]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
15. [15]
  Xinxin JING , Weiduo WANG , Hesu MO , Peng TAN , Zhigang CHEN , Zhengying WU , Linbing SUN . Research progress on photothermal materials and their application in solar desalination. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1033-1064. doi: 10.11862/CJIC.20230371
16. [16]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
17. [17]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
18. [18]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
19. [19]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
20. [20]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(111)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142