Citation: Zongfei YANG, Xiaosen ZHAO, Jing LI, Wenchang ZHUANG. Research advances in heteropolyoxoniobates[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306 shu

Research advances in heteropolyoxoniobates

School of Materials and Chemical Engineering, Xuzhou University of Technology, Xuzhou, Jiangsu 221000, China

Corresponding author: Zongfei YANG, yzf951020@xzit.edu.cn Wenchang ZHUANG, windchant@xzit.edu.cn
Received Date: 11 August 2023
Revised Date: 18 December 2023

Figures(9)

Polyoxometalates, abbreviated as POMs, are a special kind of versatile nanosized metal-oxygen clusters formed by the assembly of high-valent early transition-metal atoms (typically V⁵⁺, Nb⁵⁺, Ta⁵⁺, Mo⁶⁺ and W⁶⁺). They have various structures and unique physicochemical properties and are widely used in the fields of catalysis, magnetism, materials science, medicine, and optics. In the past few decades, polyoxoniobates (PONbs), a subfamily of POMs, have drawn considerable attention due to their structural diversity and application prospects in alkaline catalysis and photocatalytic hydrogen production, etc. According to whether they contain heteroatoms or not, PONbs can be classified into two categories, namely, isopolyoxoniobates and heteropolyoxoniobates (HPONbs). In this review, we systematically summarise typical HPONbs with main group elements (ⅢA/ⅣA/ⅤA/ⅥA) or transition metal elements (V/Fe/Cu) as heteroatoms reported in the past several decades, including their assembly methodologies, structure regulation, properties, and related applications. Moreover, the current challenges and prospects of these materials are also discussed. We hope that this review can provide some helpful enlightenment and promising directions for exploring and discovering innovative PONb-based materials with unique functions and practicability.
- polyoxoniobate,
- polyoxometalate,
- structure regulation,
- strategies synthesis
1. [1]
  Ma P T, Hu F, Wang J P, Niu J Y. Carboxylate covalently modified polyoxometalates: From synthesis, structural diversity to applications[J]. Coord. Chem. Rev., 2019,378:281-309. doi: 10.1016/j.ccr.2018.02.010
2. [2]
  Yang Z F, Li J, Niu J Y, Wang J P. Polyoxotantalate chemistry: From synthetic strategies to structural diversity and applications[J]. Dalton Trans., 2023,52(15):4632-4642. doi: 10.1039/D2DT03319D
3. [3]
  Li X X, Zhao D, Zheng S T. Recent advances in POM-organic frameworks and POM-organic polyhedra[J]. Coord. Chem. Rev., 2019,397:220-240. doi: 10.1016/j.ccr.2019.07.005
4. [4]
  Wang Z M, Xin X, Zhang M, Li Z, Lv H J, Yang G Y. Recent advances of mixed-transition-metal-substituted polyoxometalates[J]. Sci. Chi. Chem., 2022,65:1515-1525. doi: 10.1007/s11426-022-1276-4
5. [5]
  WU L Z, LI Y W, CHANG Y D, YANG N, GE X Y, HUI J F, LIU B, XUE G L. Syntheses, structures, and magnetic properties of sandwich-type tungstobismuthate containing manganese[J]. Chinese J. Inorg. Chem., 2022,38(10):2056-2064.
6. [6]
  YANG Z F, MU Q S, WANG Y P, MA P T, WANG J P, NIU J Y. Synthesis, structure and properties of a sandwich-type polyoxomolybdate containing mixed-valence antimony[J]. Chinese J. Inorg. Chem., 2019,35(11):2101-2107.
7. [7]
  Mialane P, Mellot-Draznieks C, Gairola P, Duguet M, Benseghir Y, Oms O, Dolbecq A. Heterogenisation of polyoxometalates and other metal-based complexes in metal-organic frameworks: From synthesis to characterization and applications in catalysis[J]. Chem. Soc. Rev., 2021,50(10):6152-6220. doi: 10.1039/D0CS00323A
8. [8]
  Nyman M. Polyoxoniobate chemistry in the 21st century[J]. Dalton Trans., 2011,40(32):8049-8058. doi: 10.1039/c1dt10435g
9. [9]
  Dong J, Hu J F, Chi Y N, Lin Z G, Zou B, Yang S, Hill C L, Hu C W. A polyoxoniobate-polyoxovanadate double-anion catalyst for simultaneous oxidative and hydrolytic decontamination of chemical warfare agent simulants[J]. Angew. Chem. Int. Ed., 2017,56(16):4473-4477. doi: 10.1002/anie.201700159
10. [10]
  Liu H F, Liu C P, Zhen N, Dong J, Chi Y N, Hu C W. Amphiphilic polyoxoniobate-based recoverable Pickering emulsion for effective oxidative desulfurization[J]. Appl. Catal. A-Gen., 2023,656119133. doi: 10.1016/j.apcata.2023.119133
11. [11]
  Huang P, Qin C, Su Z M, Xing Y, Wang X L, Shao K Z, Lan Y Q, Wang E B. Self-assembly and photocatalytic properties of polyoxoniobates: {Nb₂₄O₇₂}, {Nb₃₂O₉₆}, and {K₁₂Nb₉₆O₂₈₈} clusters[J]. J. Am. Chem. Soc., 2012,134(34):14004-14010. doi: 10.1021/ja303723u
12. [12]
  Zhen N, Dong J, Lin Z G, Lu W, Li J, Chi Y N, Hu C W. A rhombus-like tetrameric vanadoniobate containing pseudo-sandwich-type {Li⊂V₂O₈(Nb₅O₁₄)₂} and its electrocatalytic activity for the selective oxidation of benzyl alcohol[J]. Inorg. Chem., 2023,62(34):13824-13831. doi: 10.1021/acs.inorgchem.3c01575
13. [13]
  Li D H, Shi N, Wang Y J, Cai P W, Sun Y Q, Zheng S T. An organic-inorganic hybrid polyoxoniobate decorated by a Co(Ⅲ)-amine complex for electrocatalytic urea splitting[J]. Inorg. Chem. Front., 2023,10(16):4789-4796. doi: 10.1039/D3QI01066J
14. [14]
  Zhang T T, Cui X B. The syntheses of a series of polyoxoniobate-based compounds: Their characterizations and catalytic applications in styrene epoxidation[J]. Polyhedron, 2023,243116532. doi: 10.1016/j.poly.2023.116532
15. [15]
  Guo Z W, Lin L H, Ye J P, Chen Y, Li X X, Lin S, Huang J D, Zheng S T. Core-shell-type all-inorganic heterometallic nanoclusters: Record high-nuclearity cobalt polyoxoniobates for visible-light-driven photocatalytic CO₂ reduction[J]. Angew. Chem. Int. Ed., 2023,62e202305260. doi: 10.1002/anie.202305260
16. [16]
  Lindqvist I. The structure of the hexaniobate ion in 7Na₂O·6Nb₂O₅·32H₂O[J]. Arkiv for Kemi, 1953,5(3):247-250.
17. [17]
  Nyman M, Alam T M, Bonhomme F, Rodriguez M A, Frazer C S, Welk M E. Solid-state structures and solution behavior of alkali salts of the[Nb₆O₁₉]^8--Lindqvist ion[J]. J. Clust. Sci., 2006,17(2):197-219. doi: 10.1007/s10876-006-0049-x
18. [18]
  Graeber E J, Morosin B. The molecular configuration of the decaniobate ion (Nb₁₀O₂₈)^6-[J]. Acta Crystallogr. Sect. B, 1977,B33:2137-2143.
19. [19]
  Maekawa M, Ozawa Y, Yagasaki A. Icosaniobate: A new member of the isoniobate family[J]. Inorg. Chem., 2006,45(24):9608-9609. doi: 10.1021/ic0601788
20. [20]
  Jin L, Zhu Z K, Wu Y L, Qi Y J, Li X X, Zheng S T. Record high-nuclearity polyoxoniobates: Discrete nanoclusters {Nb₁₁₄}, {Nb₈₁}, and {Nb₅₂}, and extended frameworks based on {Cu₃Nb₇₈} and {Cu₄Nb₇₈}[J]. Angew. Chem. Int. Ed., 2017,56(51):16288-16292. doi: 10.1002/anie.201709565
21. [21]
  Wu Y L, Li X L, Qi Y J, Yu H, Jin L, Zheng S T. {Nb₂₈₈O₇₆₈(OH)₄₈(CO₃)₁₂}: A macromolecular polyoxometalate with niobium atoms close to 300[J]. Angew. Chem. Int. Ed., 2018,57(28):8572-8576. doi: 10.1002/anie.201804088
22. [22]
  Nyman M, Bonhomme F, Alam T M, Rodriguez M A, Cherry B R, Krumhansl J L, Nenoff T M, Sattler A M. A general synthetic procedure for heteropolyniobates[J]. Science, 2002,297(5583):996-998. doi: 10.1126/science.1073979
23. [23]
  Hou Y, Nyman M, Rodriguez M A. Soluble heteropolyniobates from the bottom of group ⅠA[J]. Angew. Chem. Int. Ed., 2011,50(52):12514-12517. doi: 10.1002/anie.201104478
24. [24]
  Dopta J, Mahnke L K, Bensch W. New pronounced progress in the synthesis of group 5 polyoxometalates[J]. CrystEngComm, 2020,22(19):3254-3268. doi: 10.1039/D0CE00315H
25. [25]
  Abramov P, Sokolov M, Vicent C. Polyoxoniobates and polyoxotantalates as ligands-revisited[J]. Inorganics., 2015,3(2):160-177. doi: 10.3390/inorganics3020160
26. [26]
  Wu H L, Zhang Z M, Li Y G, Wang X L, Wang E B. Recent progress in polyoxoniobates decorated and stabilized via transition metal cations or clusters[J]. CrystEngComm, 2015,17(33):6261-6268. doi: 10.1039/C5CE00909J
27. [27]
  Zhao H Y, Li Y Z, Zhao J W, Wang L, Yang G Y. State-of-the-art advances in the structural diversities and catalytic applications of polyoxoniobate-based materials[J]. Coord. Chem. Rev., 2021,443213966. doi: 10.1016/j.ccr.2021.213966
28. [28]
  Stewart T A, Trudell D E, Alam T M, Ohlin C A, Lawler C, Casey W H, Jett S, Nyman M. Enhanced water purification: A single atom makes a difference[J]. Environ. Sci. Technol., 2009,43(14):5416-5422. doi: 10.1021/es803683t
29. [29]
  Hou Y, Alam T M, Rodriguez M A, Nyman M. Aqueous compatibility of group ⅢA monomers and Nb-polyoxoanions[J]. Chem.Commun., 2012,48(48):6004-6006. doi: 10.1039/c2cc31284k
30. [30]
  Keggin J F. Structure of the molecule of 12-phosphotungstic acid[J]. Nature, 1933,131:908-909.
31. [31]
  Li D D, Ma P T, Niu J Y, Wang J P. Recent advances in transition-metal-containing Keggin-type polyoxometalate-based coordination polymers[J]. Coord. Chem. Rev., 2019,392:49-80. doi: 10.1016/j.ccr.2019.04.008
32. [32]
  Liu J X, Zhang X B, Li Y L, Huang S L, Yang G Y. Polyoxometalate functionalized architectures[J]. Coord. Chem. Rev., 2020,414213260. doi: 10.1016/j.ccr.2020.213260
33. [33]
  Nyman M, Bonhomme F, Alam T M, Parise J B, Vaughan G M B. [SiNb₁₂O₄₀]^16- and[GeNb₁₂O₄₀]^16-: Highly charged Keggin ions with sticky surfaces[J]. Angew. Chem. Int. Ed., 2004,43(21):2787-2792. doi: 10.1002/anie.200353410
34. [34]
  Bonhomme F, Larentzos J P, Alam T M, Maginn E J, Nyman M. Synthesis, structural characterization, and molecular modeling of dodecaniobate Keggin chain materials[J]. Inorg. Chem., 2005,44:1774-1785. doi: 10.1021/ic048847+
35. [35]
  Zhang Z Y, Lin Q P, Kurunthu D, Wu T, Zuo F, Zheng S T, Bardeen C J, Bu X H, Feng P Y. Synthesis and photocatalytic properties of a new heteropolyoxoniobate compound: K₁₀[Nb₂O₂(H₂O)₂][SiNb₁₂O₄₀]·12H₂O[J]. J. Am. Chem. Soc., 2011,133(18):6934-6937. doi: 10.1021/ja201670x
36. [36]
  Hou Y, Zakharov L N, Nyman M. Observing assembly of complex inorganic materials from polyoxometalate building blocks[J]. J. Am. Chem. Soc., 2013,135(44):16651-16657. doi: 10.1021/ja4086484
37. [37]
  Zhang Y, Shen J Q, Zheng L H, Zhang Z M, Li Y X, Wang E B. Four polyoxonibate-based inorganic-organic hybrids assembly from bicapped heteropolyoxonibate with effective antitumor activity[J]. Cryst. Growth Des., 2014,14(1):110-116. doi: 10.1021/cg401227g
38. [38]
  Zhang Z Y, Peng J, Shi Z Y, Zhou W L, Khan S U, Liu H S. Antimony-dependent expansion for the Keggin heteropolyniobate family[J]. Chem. Commun., 2015,51(15):3091-3093. doi: 10.1039/C4CC09612F
39. [39]
  Shen J Q, Yao S, Zhang Z M, Wu H H, Zhang T Z, Wang E B. Self-assembly and photocatalytic property of germanoniobate[H₆Ge₄Nb₁₆O₅₆]^10-: Encapsulating four {GeO₄} tetrahedra within a {Nb₁₆} cage[J]. Dalton Trans., 2013,42(16):5812-5817. doi: 10.1039/c3dt32855d
40. [40]
  Zhang X, Liu S X, Li S J, Gao Y H, Wang X N, Tang Q, Liu Y W. Two members of the {X₄Nb₁₆O₅₆} family (X=Ge, Si) based on[(GeOH)₂ Ge₂Nb₁₆H₂O₅₄]^12- and[K(GeOH)₂Ge₂Nb₁₆H₃O₅₄]^10-[J]. Eur. J. Inorg. Chem., 2013(10/11):1706-1712.
41. [41]
  Huang P, Qin C, Wang X L, Sun C Y, Xing Y, Wang H N, Shao K Z, Su Z M. A new organic-inorganic hybrid based on the crescent-shaped polyoxoanion[H₆SiNb₁₈O₅₄]^8- and copper-organic cations[J]. Dalton Trans., 2012,41:6075-6077. doi: 10.1039/c2dt30265a
42. [42]
  Zhong Z H, Jing J X, Sun Y Q, Li X X, Zheng S T. Two new 3D tubular polyoxoniobates frameworks based on {SiNb₁₈O₅₄} clusters with proton conduction properties[J]. Inorg. Chem. Commun., 2021,132108813. doi: 10.1016/j.inoche.2021.108813
43. [43]
  Shi N, Wang Y J, Li X X, Sun Y Q, Zheng S T. An inorganic Co-containing heteropolyoxoniobate: Reversible chemochromism and H₂O-dependent proton conductivity properties[J]. Inorg. Chem. Front., 2021,8(24):5225-5233. doi: 10.1039/D1QI01065D
44. [44]
  Zhu Z K, Lin Y Y, Lai R D, Li X X, Sun Y Q, Zheng S T. A series of high-nuclear planar equilateral triangle-shaped {Ln₆(μ₃-OH)₆} cluster encapsulated polyoxoniobates with frequency dependent magnetic property[J]. Chin. Chem. Lett., 2023,34(7)107773. doi: 10.1016/j.cclet.2022.107773
45. [45]
  Liu Z Y, Ye J P, Li Y L, Sun Y Q, Li X X, Sun C, Zheng S T. Cadmium-containing windmill-like heteropolyoxoniobate macrocycle with high yield for catalyzing Knoevenagel condensation[J]. Dalton Trans., 2023,52(5):1193-1197. doi: 10.1039/D2DT03706H
46. [46]
  Nyman M, Celestian A J, Parise J B, Holland G P, Alam T M. Solid-state structural characterization of a rigid framework of lacunary heteropolyniobates[J]. Inorg. Chem., 2006,45(3):1043-1052. doi: 10.1021/ic051155g
47. [47]
  Liang Z J, Yu J, Zhang Y, Ma P T, Mao Q H, Wang J P. A lacunary heteropolyniobate linked by[Co(H₂O)₆]²⁺ ions[J]. Inorg. Chem. Commun., 2020,111107612. doi: 10.1016/j.inoche.2019.107612
48. [48]
  Son J H, Ohlin C A, Johnson R L, Yu P, Casey W H. A soluble phosphorus-centered Keggin polyoxoniobate with bicapping vanadyl groups[J]. Chem.-Eur. J., 2013,19(16):5191-5197. doi: 10.1002/chem.201204563
49. [49]
  Shen J Q, Zhang Y, Zhang Z M, Li Y G, Gao Y Q, Wang E B. Polyoxoniobate-based 3D framework materials with photocatalytic hydrogen evolution activity[J]. Chem. Commun., 2014,50(45):6017-6019. doi: 10.1039/c3cc49245a
50. [50]
  Shen J Q, Wu Q, Zhang Y, Zhang Z M, Li Y G, Lu Y, Wang E B. Unprecedented high-nuclear transition-metal-cluster-substituted heteropolyoxoniobates: Synthesis by {V₈} ring insertion into the POM matrix and antitumor activities[J]. Chem.-Eur. J., 2014,20(10):2840-2848. doi: 10.1002/chem.201303995
51. [51]
  Lan Q, Zhang Z M, Li Y G, Wang E B. Extended structural materials composed of transition-metal-substituted arsenicniobates and their photocatalytic activity[J]. RSC Adv., 2015,5(55):44198-44203. doi: 10.1039/C5RA08262E
52. [52]
  Hu J F, Wang Y, Zhang X N, Chi Y N, Yang S, Li J K, Hu C W. Controllable assembly of vanadium-containing polyoxoniobate-based three-dimensional organic-inorganic hybrid compounds and their photocatalytic properties[J]. Inorg. Chem., 2016,55(15):7501-7507. doi: 10.1021/acs.inorgchem.6b00823
53. [53]
  Li N, Liu Y W, Lu Y, He D F, Liu S M, Wang X Q, Li Y G, Liu S X. An arsenicniobate-based 3D framework with selective adsorption and anion-exchange properties[J]. New J. Chem., 2016,40(3):2220-2224. doi: 10.1039/C5NJ02163D
54. [54]
  Son J H, Casey W H. Reversible capping/uncapping of phosphorous-centered Keggin-type polyoxoniobate clusters[J]. Chem. Commun., 2015,51(8):1436-1438. doi: 10.1039/C4CC05689B
55. [55]
  Son J H, Casey W H. A new Keggin-like niobium-phosphate cluster that reacts reversibly with hydrogen peroxide[J]. Chem. Commun., 2015,51(64):12744-12747. doi: 10.1039/C5CC03782D
56. [56]
  Yang Z F, Shang J J, He Y Z, Qiao Y Y, Ma P T, Niu J Y, Wang J P. A 1D helical chain heterpolyniobate templated by AsO₃^3-[J]. Inorg. Chem., 2020,59(3):1967-1972. doi: 10.1021/acs.inorgchem.9b03313
57. [57]
  Wu Y L, Zhong Z H, Wu P X, Sun Y Q, Li X X, Zheng S T. A peanut-like Sb-embedded polyoxoniobate cage for hydrolytic decomposition for chemical warfare agent[J]. Eur. J. Inorg. Chem., 2021(15):1501-1509.
58. [58]
  Geng Q H, Liu Q S, Ma P T, Wang J P, Niu J Y. Synthesis, crystal structure and photocatalytic properties of an unprecedented arsenic-disubstituted Lindqvist-type peroxopolyoxoniobate ion: {As₂Nb₄(O₂)₄ O₁₄H_1.5}^4.5-[J]. Dalton Trans., 2014,43(26):9843-9846. doi: 10.1039/C4DT00875H
59. [59]
  Son J H, Park D H, Keszler D A, Casey W H. Acid-stable peroxoniobophosphate clusters to make patterned films[J]. Chem.-Eur. J., 2015,21(18):6727-6731. doi: 10.1002/chem.201500684
60. [60]
  Zhao S F, Liang Z J, Geng Q H, Ma P T, Zhang C, Niu J Y, Wang J P. Assembly of niobium-phosphate cluster and in situ transition-metal-containing derivatives[J]. CrystEngComm, 2017,19(20):2768-2774. doi: 10.1039/C7CE00603A
61. [61]
  Wang H Y, Li J, Sun J J, Wang Y Y, Liang Z J, Ma P T, Zhang D D, Wang J P, Niu J Y. Synthesis, structure, and luminescent properties of a family of lanthanide-functionalized peroxoniobiophosphates[J]. Sci. Rep., 2017,7(1)10653. doi: 10.1038/s41598-017-10811-2
62. [62]
  Yang Z F, Mu Q S, Liang Z J, Ma P T, Niu J Y, Wang J P. A novel peroxopolyoxoniobate incorporating mixed heteroatoms: [P₂Se₂Nb₆(O₂)₆O₂₂]^8-[J]. Dalton Trans., 2019,48(35):13135-13138. doi: 10.1039/C9DT02860A
63. [63]
  Yang Z F, Yan B, Li X, Wu J K, Ma P T, Niu J Y, Wang J P. Three types of lanthanide-containing polyoxoniobates and their luminescence properties[J]. Inorg. Chem., 2022,61(31):12181-12189. doi: 10.1021/acs.inorgchem.2c01203
64. [64]
  Hu J F, Han T, Chi Y N, Lin Z G, Xu Y Q, Yang S, Wei D, Zheng Y Z, Hu C W. Sulfur-centred polyoxoniobate-based 3D organic-inorganic hybrid compound and its magnetic behavior[J]. Chem. Commun., 2016,52(72):10846-10849. doi: 10.1039/C6CC03915D
65. [65]
  Son J H, Wang J R, Osterloh F E, Yu P, Casey W H. A tellurium-substituted Lindqvist-type polyoxoniobate showing high H₂ evolution catalyzed by tellurium nanowires via photodecomposition[J]. Chem. Commun., 2014,50(7):836-838. doi: 10.1039/C3CC47001F
66. [66]
  Abramov P A, Zemerova T P, Moroz N K, Kompankov N B, Zhdanov A A, Tsygankova A R, Vicent C, Sokolov M N. Synthesis and characterization of[(OH)TeNb₅O₁₈]^6- in water solution, comparison with[Nb₆O₁₉]^8-[J]. Inorg. Chem., 2016,55(4):1381-1389. doi: 10.1021/acs.inorgchem.5b01806
67. [67]
  Liang Z J, Sun J J, Zhang D D, Ma P T, Zhang C, Niu J Y, Wang J P. Assembly of TeO₃^2- ions embedded in an Nb/O cage with selective decolorization of organic dye[J]. Inorg. Chem., 2017,56(17):10119-10122. doi: 10.1021/acs.inorgchem.7b00860
68. [68]
  Liang Z J, Zhang L, Li Y Y, Ma P T, Niu J Y, Wang J P. Two novel heteropolyniobates using TeO₃^2- as template and linker[J]. Inorg. Chem., 2019,58(1):27-30. doi: 10.1021/acs.inorgchem.8b02528
69. [69]
  Liang Z J, He Y Z, Qiao Y Y, Ma P T, Niu J Y, Wang J P. Sandwich-type heteropolyniobate templated by mixed heteroanions[J]. Inorg. Chem., 2020,59(12):7895-7899. doi: 10.1021/acs.inorgchem.0c00312
70. [70]
  Yang Z F, Shang J J, Yang Y Y, Ma P T, Niu J Y, Wang J P. Synthesis, structures and stability of three V-substituted polyoxoniobate clusters based on[TeNb₉O₃₃]^17- units[J]. Dalton Trans., 2021,50(22):7610-7620. doi: 10.1039/D1DT00223F
71. [71]
  Cheng M Y, Liu Y F, Li N, Shi J W, Du W X, Zhang D D, Yang G P, Wang G, Niu J Y. Two novel telluroniobates with efficient catalytic activity for the imidation/amidation reaction[J]. Chem. Commun., 2022,58(8):1167-1170. doi: 10.1039/D1CC06781H
72. [72]
  Jing Z, Wang W Y, Wan R, Ma X Y, Qiao Y Y, Bai Y F, Ma P T, Niu J Y, Wang J P. Rocket-shaped telluroniobate with efficient catalytic activity in the transesterification reaction[J]. Inorg. Chem., 2022,61(42):16528-1653. doi: 10.1021/acs.inorgchem.2c02665
73. [73]
  Lai R D, Feng H L, Sun Y Q, Li X X, Zheng S T. A lanthanide-tellurium heterometal encapsulated sandwich-type heteropolyoxoniobate with a 3D pcu-type hydrogen-bonded network[J]. Dalton Trans., 2022,51(27):10571-10577. doi: 10.1039/D2DT01472F
74. [74]
  Zhen N, Dong J, Lin Z G, Li Z, Liu C P, Li X X, Geng W J, Chi Y N, Hu C W. {V₆} ring sandwiched polyoxoniobate as molecular electrocatalyst for oxidant-free synthesis of sulfoxides[J]. Chem.-Eur. J., 2023,29(23)e202203903. doi: 10.1002/chem.202203903
75. [75]
  Guo G L, Xu Y Q, Cao J, Hu C W. An unprecedented vanadoniobate cluster with 'trans-vanadium' bicapped Keggin-type {VNb₁₂O₄₀ (VO)₂}[J]. Chem. Commun., 2011,47(33):9411-9413. doi: 10.1039/c1cc12329g
76. [76]
  Son J H, Ohlin C A, Larson E C, Yu D, Casey W H. Synthesis and characterization of a soluble vanadium-containing Keggin polyoxoniobate by ESI-MS and ⁵¹V NMR: (TMA)₉[V₃Nb₁₂O₄₂]·18H₂O[J]. Eur. J. Inorg. Chem., 2013(10/11):1748-1753.
77. [77]
  Huang P, Zhou E L, Wang X L, Sun C Y, Wang H N, Xing Y, Shao K Z, Su Z M. New heteropolyniobates based on a bicapped Keggin-type {VNb₁₄} cluster with selective adsorption and photocatalytic properties[J]. CrystEngComm, 2014,16(41):9582-9585. doi: 10.1039/C4CE00960F
78. [78]
  Huang P, Qin C, Wang X L, Sun C Y, Yang G S, Shao K Z, Jiao Y Q, Zhou K, Su Z M. An unprecedented organic-inorganic hybrid based on the first {Nb₁₀V₄O₄₀(OH)₂}^12- clusters and copper cations[J]. Chem. Commun., 2012,48(1):103-105. doi: 10.1039/C1CC15684E
79. [79]
  Guo G L, Xu Y Q, Cao J, Hu C W. The {V₄Nb₆O₃₀} cluster: A new type of vanadoniobate anion structure[J]. Chem.-Eur. J., 2012,18(12):3493-3497. doi: 10.1002/chem.201103390
80. [80]
  Abramov P A, Davletgildeeva A T, Moroz N K, Kompankov N B, Santiago-Schübel B, Sokolov M N. Cation-dependent self-assembly of vanadium polyoxoniobates[J]. Inorg. Chem., 2016,55(24):12807-12814. doi: 10.1021/acs.inorgchem.6b02108
81. [81]
  Zhen N, Dong J, Lin Z G, Li X X, Chi Y N, Hu C W. Self-assembly of polyoxovanadate-capped polyoxoniobates and their catalytic decontamination of sulfur mustard simulants[J]. Chem. Commun., 2020,56(90):13967-13970. doi: 10.1039/D0CC06277D
82. [82]
  Liang Z J, Wang K, Zhang D D, Ma P T, Niu J Y, Wang J P. {Fe₃Nb₂₅} cluster based on an Fe-centred Keggin unit[J]. Dalton Trans., 2017,46(5):1368-1371. doi: 10.1039/C6DT04223F
1. [1]
  Huan LI , Shengyan WANG , Long Zhang , Yue CAO , Xiaohan YANG , Ziliang WANG , Wenjuan ZHU , Wenlei ZHU , Yang ZHOU . Growth mechanisms and application potentials of magic-size clusters of groups Ⅱ-Ⅵ semiconductors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1425-1441. doi: 10.11862/CJIC.20240088
2. [2]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
3. [3]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
4. [4]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
5. [5]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
6. [6]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
7. [7]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
8. [8]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
9. [9]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
10. [10]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
11. [11]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
12. [12]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
13. [13]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
14. [14]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
15. [15]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
16. [16]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
17. [17]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
18. [18]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
19. [19]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
20. [20]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(135)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142