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Citation: Wen YANG, Didi WANG, Ziyi HUANG, Yaping ZHOU, Yanyan FENG. La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO2 methanation performance[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276 shu

La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO2 methanation performance

  • Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials, Department of Chemistry and Bioengineering, Guilin University of Technology, Guilin, Guangxi 541004, China

  • Corresponding author: Yanyan FENG, feng1988glut@163.com
  • Received Date: 24 July 2023
    Revised Date: 13 November 2023

Figures(8)

  • The Ni-La/Al2O3 catalysts derived from hydrotalcite were prepared by an in-situ growth method and applied in CO2 methanation to investigate the influence of La doping amount on the morphology, structure, and catalytic performance of the catalysts. The morphology and structure of the obtained catalysts were analyzed by inductively-coupled plasma emission spectroscopy, X-ray diffraction, H2 temperature programmed reduction, low-temperature N2 adsorption-desorption, scanning electron microscopy, and transmission electron microscopy, respectively. The characterization results indicated that an appropriate amount of La doping could improve the dispersion of active metal Ni on the support, weaken the interaction between Ni and the support, improve the pore structure of the catalyst, and increase the specific surface area of the catalyst. The results of CO2 methanation showed that the catalyst 30Ni-10La/Al2O3 with the Ni loading (mass fraction) of 30% and La doping of 10% possessed the outstanding catalytic performance, which exhibited the CO2 conversion of 91.9% and CH4 yield of 91.5% under 350℃. Moreover, the catalyst 30Ni-10La/Al2O3 remained highly active after the stability test of 60 h.
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