Citation: Zhongxuan XU, Jun WU, Yuanting ZHANG, Mengjie WU. Four-connected helical chiral coordination polymers based on lactate synthons: Syntheses, structures, and photo-catalytic properties[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(2): 336-344. doi: 10.11862/CJIC.20230266 shu

Four-connected helical chiral coordination polymers based on lactate synthons: Syntheses, structures, and photo-catalytic properties

Zhongxuan XU ^{1, 2, 3,,} ,
Jun WU ³ ,
Yuanting ZHANG ³ ,
Mengjie WU ³

1.
Guangxi Key Laboratory of Sericulture Ecology and Applied Intelligent Technology, Hechi University, Hechi, Guangxi 546300, China
2.
Guangxi Collaborative Innovation Center of Modern Sericulture and Silk, Hechi University, Hechi, Guangxi 546300, China
3.
School of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi, Guizhou 563002, China

Corresponding author: Zhongxuan XU, xuzhongxuan4201@163.com
Received Date: 12 July 2023
Revised Date: 14 November 2023

Figures(8)

Enantiomeric lactic derivatives and 3-bromo-4-hydroxybenzoate were used as starting materials to obtain a pair of enantiomers 3-bromo-4-(((1R)-1-carboxyethyl)oxy)benzoic acid (R-H₂bba) and 3-bromo-4-(((1S)-1-carboxy-ethyl)oxy)benzoic acid (S-H₂bba). As new synthons, R-H₂bba and S-H₂bba can provide variable coordination modes by two carboxylate groups and chiral source by lactate unit. In the presence of 1, 3-di(pyridine-4-yl)propane (1, 3-dpp), R-H₂bba and S-H₂bba further assembled with Ni²⁺ ions under the hydrothermal condition to obtain a pair of chiral coordination polymers (CCPs) {[Ni(R-bba)(1, 3-dpp)(H₂O)_0.5]·1.5H₂O}_n (HU12-R) and {[Ni(S-bba) (1, 3-dpp) (H₂O)_0.5]·1.5H₂O}_n (HU12-S), respectively. Structural analysis revealed complexes HU12-R and HU12-S are 3D helical frameworks with 4-connected dia net. In complexes HU12-R and HU12-S, R-bba^2- and S-bba^2- anions are respectively connected by Ni²⁺ centers to form a pair of small enantiomeric helical chains around 2₁ screw axis. In contrast, 1, 3-dpp ligands and Ni²⁺ centers construct another pair of large enantiomeric helical chains around 4₁ or 4₃ screw axis, respectively. Moreover, the results of electrochemical testing indicated that complex HU12-R is an n-type semiconductor and has a strong absorbing ability for UV-Vis light and low resistance in charge transportation. By comparing with R-H₂bba, 1, 3-dpp, and Ni²⁺ ions, HU12-R indicates obvious catalytic activity in the degradation of dyes under ultraviolet light.
- chiral complex,
- lactate synthon,
- dia net,
- helical structure,
- photo-catalytic activity
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