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Citation: Peng XU, Shasha WANG, Nannan CHEN, Ao WANG, Dongmei YU. Preparation of three-layer magnetic composite Fe3O4@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239 shu

Preparation of three-layer magnetic composite Fe3O4@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water

  • College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China

  • Corresponding author: Peng XU, xupeng@njfu.deu.cn
  • Received Date: 20 June 2023
    Revised Date: 9 January 2024

Figures(10)

  • A magnetic composite material (Fe3O4@PAA@ZIF-8) was designed and synthesized with magnetic nanoparticles as the nucleus, polymer as the intermediate layer, and zeolitic imidazolate framework-8 (ZIF-8) as the outer layer. First, Fe3O4 nanoparticles were prepared by solvothermal method, and then polyacrylic acid (PAA) layer was coated on the surface of Fe3O4 nanoparticles by distillation precipitation polymerization, and finally ZIF-8 was coated on the surface of the Fe3O4@PAA by in-situ deposition method (composite method). Based on the characterization of the composition, structure and morphology of Fe3O4@PAA@ZIF-8, the adsorption properties of malachite green (MG) were studied in depth. Transmission electron microscope (TEM) showed that Fe3O4@PAA@ZIF-8 had a distinct three-layer structure, with an average particle size of 117 nm for Fe3O4, a thickness of about 17 nm for the PAA layer, and a thickness of about 14 nm for the ZIF-8 layer. The adsorption capacity of Fe3O4@PAA@ZIF-8 for MG increased with the increase of pH, and the adsorption process conformed to the quasi-second-order kinetic model and the Langmuir isothermal model, and the maximum adsorption capacity could reach 9 759 mg·g-1. In addition, Fe3O4@PAA@ZIF-8 had good reusability, and the maximum adsorption capacity of MG (500 mg·L-1) could still reach 982 mg·g-1 after 8 cycles.
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