Citation: Zizheng LU, Wanyi SU, Qin SHI, Honghui PAN, Chuanqi ZHAO, Chengfeng HUANG, Jinguo PENG. Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225 shu

Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation

Zizheng LU ¹ ,
Wanyi SU ¹ ,
Qin SHI ^{1, 2,,} ,
Honghui PAN ^{1, 2,,} ,
Chuanqi ZHAO ¹ ,
Chengfeng HUANG ³ ,
Jinguo PENG ⁴

1.
Guangxi Key Laboratory of Advanced Structural Materials and Carbon Neutralization, Guangxi Colleges and Universities Key Laboratory of Environmental-Friendly Materials and Ecological Remediation, Soil and Groundwater Environment Research Institute, School of Materials and Environment, Guangxi Minzu University, Nanning 530006, China
2.
Guangxi Research Institute of Chemical Industry Co., Ltd., Nanning 530006, China
3.
College of Chemistry and Chemical Engineering, Guangxi Minzu University, Nanning 530006, China
4.
Guangxi Huatou Testing Technology Co., Ltd., Nanning 530006, China

Corresponding author: Qin SHI, jackshiqin@outlook.com Honghui PAN, honghui_pan@gxmzu.edu.cn
Received Date: 8 June 2023
Revised Date: 27 November 2023

Figures(10)

A simple immersion method was used for surface W doping of BiVO₄ photoanode. Ciprofloxacin (CIP) was used as a pharmaceuticals and personal care products (PPCPs) model contaminant to study the surface state behavior of W-BiVO₄ photoanode for CIP degradation. The results show that low concentration of W doping has no significant effect on the crystal structure, surface morphology and optical absorption performance of BiVO₄ photoanode. However, W doping replaces V⁵⁺ on the surface of BiVO₄ photoanode, inhibiting the V⁵⁺/V⁴⁺ reduction process on the surface of BiVO₄ photoanode and reducing the surface state acting as recombination centre. It can also introduce more oxygen vacancies and increase the surface state acting as reaction sites. CIP degradation reaction is controlled by surface active sites. Surface W doping can effectively promote the charge transfer for CIP degradation, thereby improving the photoelectrocatalytic degradation performance of BiVO₄ photoanode.
- BiVO₄,
- W-doping,
- photoelectrocatalytic oxidation technology,
- ciprofloxacin,
- surface state
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沈阳化工大学材料科学与工程学院沈阳 110142

Surface state behavior of W doped BiVO4 photoanode for ciprofloxacin degradation

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通讯作者: 陈斌, bchen63@163.com

Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation