Citation: Silu WANG, Fengfeng ZHANG, Cheng ZHANG, Xiao WANG, Long TANG, Erlin YUE, Jijiang WANG, Xiangyang HOU. Design and synthesis of Eu³⁺/Tb³⁺-functionalized coordination polymers as visible fluorescent probes for trace monitoring Zr⁴⁺, Fe³⁺, Cr₂O₇^2-, HPO₄^2- and identifying fingerprints[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(2): 441-450. doi: 10.11862/CJIC.20230145 shu

Design and synthesis of Eu³⁺/Tb³⁺-functionalized coordination polymers as visible fluorescent probes for trace monitoring Zr⁴⁺, Fe³⁺, Cr₂O₇^2-, HPO₄^2- and identifying fingerprints

Department of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

Corresponding author: Xiangyang HOU, houxiangyang7@126.com
Received Date: 17 April 2023
Revised Date: 1 November 2023

Figures(5)

The isomorphic terbium and europium coordination polymers (CPs) {[Eu(PLIA)_1.5(H₂O)₂] ·H₂O}_n (1) and {[Tb(PLIA)_1.5(H₂O)₂]·H₂O}_n (2), where H₂PLIA=5-((pyridin-4-yl-methyl)oxy)benzene-1,3-dicarboxylic acid, were synthesized by using aromatic π-conjugated and nitrogen-containing organic linkers. The structure determination, characterization, and fluorescence trace identification of the CPs were studied. The two isomorphic complexes have an ideal 3D frame structure and their chemical stability is enhanced by weak interactions such as π…π packing and hydrogen bonds. The characterization shows that CPs 1 and 2 have good fluorescence deletion properties, crystallinity, thermodynamic stability, and structural integrity, and can be used as fluorescence sensing materials. 1 and 2 have fluorescence recognition ability for Zr⁴⁺, Cr₂O₇^2- and Fe³⁺, HPO₄^2- in aqueous solution, respectively, with good selectivity and high sensitivity. The detection limits of these four ions by 1 and 2 were 0.139 μmol·L^-1 (1, Zr⁴⁺), 0.626 μmol·L^-1 (1, Cr₂O₇^2-), 0.430 μmol·L^-1 (2, Fe³⁺), 1.36 μmol·L^-1 (2, HPO₄^2-), respectively. The fluorescence quenching mechanism of 1 and 2 as probes was investigated in detail. More interestingly, the two complexes have potential fingerprint recognition properties. Their fluorescent fingerprint patterns were clear and coherent, and the details were obvious and could be clearly observed.
- Eu³⁺/Tb³⁺-coordination polymers,
- synthesis,
- characterization,
- fluorescent probe,
- fingerprint recognition
1. [1]
  Golden H E, Evenson G R, Christensen J R, Lane C R. Dvancing watershed legacy nitrogen modeling to improve global water quality[J]. Environ. Sci. Technol., 2023,57:2691-2697. doi: 10.1021/acs.est.2c06983
2. [2]
  Melanie W, Melitza C M, Graciela R T, Rodriguez R A, Hernandez M, Fernando L R O, Korak J A. Water quality in Puerto Rico after Hurricane Maria: Challenges associated with water quality assessments and implications for resilience[J]. ACS ES&T Wat., 2023,3:354-365.
3. [3]
  Zhu S Y, Yan B. A novel sensitive luminescent probe of S₂O₈^2- and Fe³⁺ based on covalent post-functionalization of a zirconium(Ⅳ) metal-organic framework[J]. Dalton Trans., 2018,47:11586-11592. doi: 10.1039/C8DT02051E
4. [4]
  Wang K, Hu X L, Li X, Su Z M, Zhou E L. Solvent induced two Cd-MOFs as luminescent sensors for picric acid, Fe³⁺ and Cr₂O₇^2-[J]. J. Solid State Chem., 2021,298122128. doi: 10.1016/j.jssc.2021.122128
5. [5]
  Wang X, Han Y, Han X X, Hou X Y, Wang J J, Fu F. Highly selective and sensitive detection of Hg²⁺, Cr₂O₇^2-, and nitrobenzene/2,4-dinitrophenol in water via two fluorescent Cd-CPs[J]. J. Solid State Chem., 2022,315123523. doi: 10.1016/j.jssc.2022.123523
6. [6]
  Wang X, Li B, Wu Y P, Tsamis A, Yu H G, Liu S, Zhao J, Li Y S, Li D S. Investigation on the component evolution of a tetranuclear nickel-cluster-based metal-organic framework in an electrochemical oxidation reaction[J]. Inorg. Chem., 2020,59:4764-4771. doi: 10.1021/acs.inorgchem.0c00024
7. [7]
  García-Mesa J, Montoro-Leal P, Maireles-Rivas S, Guerrero M L, Alonso E V. Sensitive determination of mercury by magnetic dispersive solid-phase extraction combined with flow-injection-cold vapour-graphite furnace atomic absorption spectrometry[J]. J. Anal. At. Spectrom., 2021,36:892-899. doi: 10.1039/D0JA00516A
8. [8]
  Perelonia K B S, Benitez K C D, Banicod R J S, Tadifa G C, Cambia F D, Montojo U M. Validation of an analytical method for the determination of cadmium, lead and mercury in fish and fishery resources by graphite furnace and cold vapor atomic absorption spectrometry[J]. Food Control, 2021,130108363. doi: 10.1016/j.foodcont.2021.108363
9. [9]
  Chen Y J, He M, Chen B B, Hu B. Thiol-grafted magnetic polymer for preconcentration of Cd, Hg, Pb from environmental water followed by inductively coupled plasma mass spectrometry detection[J]. Spectroc. Acta Pt. B-Atom. Spectr., 2021,177106071. doi: 10.1016/j.sab.2021.106071
10. [10]
  Wei J H, Yi J W, Han M L, Li B, Liu S, Wu Y P, Ma L F, Li D S. A water-stable terbium(Ⅲ)-organic framework as a chemosensor for inorganic ions, nitro-containing compounds and antibiotics in aqueous solutions[J]. Chem. Asian J., 2019,14:3694-3701. doi: 10.1002/asia.201900706
11. [11]
  Hu R, Zhang X, Chi K N, Yang T, Yang Y H. Bifunctional MOFs-based ratiometric electrochemical sensor for multiplex heavy metal ions[J]. ACS Appl. Mater. Interfaces, 2020,12:30770-30778. doi: 10.1021/acsami.0c06291
12. [12]
  Wang Y, Ma J X, Zhang Y, Xu N, Wang X L. A series of cobalt-based coordination polymer crystalline materials as highly sensitive electrochemical sensors for detecting trace Cr(Ⅵ), Fe(Ⅲ) ions, and ascorbic acid[J]. Cryst. Growth Des., 2021,21:4390-4397. doi: 10.1021/acs.cgd.1c00311
13. [13]
  Sun Y, Zhang N, Guan Q L, Liu C H, Li B, Zhang K Y, Li G H, Xing Y H, Bai F Y, Sun L X. Sensing of Fe³⁺ and Cr₂O₇^2- in water and white light: Synthesis, characterization, and fluorescence properties of a crystalline bismuth-1,3,5-benzenetricarboxylic acid framework[J]. Cryst. Growth Des., 2019,19:7217-7229. doi: 10.1021/acs.cgd.9b01098
14. [14]
  Cai D G, Qiu C Q, Zhu Z H, Zheng T F, Wei W J, Chen J L, Liu S J, Wen H R. Fabrication and DFT calculation of amine-functionalized metal-organic framework as a turn-on fluorescence sensor for Fe³⁺ and Al³⁺ ions[J]. Inorg. Chem., 2022,61:14770-14777. doi: 10.1021/acs.inorgchem.2c02195
15. [15]
  WANG Z W, WU H D, Yaseen M, LIANG A L, LIU H, NING Z A, WANG S, WANG G, QUAN W, WANG H. Two-dimensional coordination polymer[Tb(1,4-bdc)_1.5(phen)(H₂O)]_n: Synthesis, crystal structure and luminescent detection of Fe³⁺[J]. Chinese J. Inorg. Chem., 2022,38(3):551-558. doi: 10.11862/CJIC.2022.056
16. [16]
  WANG X Q, MA X H, FENG D D, TANG J, WU D. Synthesis of a water-stable Zn²⁺-based metal-organic framework for luminescence detecting Fe³⁺ and 2,6-dichloro-4-nitroaniline[J]. Chinese J. Inorg. Chem., 2022,38(1):137-144. doi: 10.11862/CJIC.2022.015
17. [17]
  Hakansson K, Coorey R V, Zubarev R A, Talrose V L, Hakansson P J. Low-mass ions observed in plasma desorption mass spectrometry of high explosives[J]. J. Mass Spectrom., 2000,35:337-346. doi: 10.1002/(SICI)1096-9888(200003)35:3<337::AID-JMS940>3.0.CO;2-7
18. [18]
  Qiang R B, Sun W M, Hou K M, Li Z P, Zhang J Y, Ding Y, Wang J Q, Yang S R. Electrochemical trimming of graphene oxide affords graphene quantum dots for Fe³⁺ detection[J]. ACS Appl. Nano Mater., 2021,4:5220-5229. doi: 10.1021/acsanm.1c00621
19. [19]
  Benito-Pena E, Urraca J L, Moreno-Bondi M C. Quantitative determination of penicillin V and amoxicillin in feed samples by pressurized liquid extraction and liquid chromatography with ultraviolet detection[J]. J. Pharm. Biomed. Anal., 2009,49:289-294. doi: 10.1016/j.jpba.2008.11.016
20. [20]
  Miao W N, Liu B, Li H, Zheng S J, Jiao H, Xu L. Fluorescent Eu³⁺/Tb³⁺ metal-organic frameworks for ratiometric temperature sensing regulated by ligand energy[J]. Inorg. Chem., 2022,61:14322-14332. doi: 10.1021/acs.inorgchem.2c02025
21. [21]
  Wang S L, L Q, Zhang C, Wang X, Li S Y, Hou X Y, Tang L, Yue E L, Fu F, Wang J J. Fluorescence sensor based on highly stable Cd(Zn)-coordination polymers for efficient detection of Cr₂O₇^2-/Nitrobenzene and recognition mechanism[J]. J. Solid State Chem., 2022,316123492. doi: 10.1016/j.jssc.2022.123492
22. [22]
  Fan M Y, Sun B, Li X, Pan Q Q, Sun J, Ma P F, Su Z M. Highly fluorescent cadmium based metal organic frameworks for rapid detection of antibiotic residues, Fe³⁺ and Cr₂O₇^2- ions[J]. Inorg. Chem., 2021,60:9148-9156. doi: 10.1021/acs.inorgchem.1c01165
23. [23]
  Meng Z X, Yang F N, Wang X J, Shan W L, Liu D D, Zhang L Y, Yuan G Z. Trefoil-shaped metal-organic cages as fluorescent chemosensors for multiple detection of Fe³⁺, Cr₂O₇^2-, and antibiotics[J]. Inorg. Chem., 2023,62:1297-1305. doi: 10.1021/acs.inorgchem.2c03639
24. [24]
  Mukherjee D, Pal A, Pal S C, Saha A, Das M C. A Highly selective MOF-based probe for turn-on luminescent detection of Al³⁺, Cr³⁺, and Fe³⁺ in solution and test paper strips through absorbance caused enhancement mechanism[J]. Inorg. Chem., 2022,61:16952-16962. doi: 10.1021/acs.inorgchem.2c03152
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Design and synthesis of Eu3+/Tb3+-functionalized coordination polymers as visible fluorescent probes for trace monitoring Zr4+, Fe3+, Cr2O72-, HPO42- and identifying fingerprints

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通讯作者: 陈斌, bchen63@163.com

Design and synthesis of Eu³⁺/Tb³⁺-functionalized coordination polymers as visible fluorescent probes for trace monitoring Zr⁴⁺, Fe³⁺, Cr₂O₇^2-, HPO₄^2- and identifying fingerprints