Citation: Wen-Ze ZHAO, Qi-Long ZHANG. Syntheses, crystal structures of two silver coordination polymers based on β-diketone ligand[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(12): 2295-2300. doi: 10.11862/CJIC.2023.198 shu

Syntheses, crystal structures of two silver coordination polymers based on β-diketone ligand

Wen-Ze ZHAO ¹ ,
Qi-Long ZHANG ^2,,

1.
Shandong Vocational College of Industry, Zibo, Shandong 256414, China
2.
School of Basic Medical Sciences, Guizhou Medical University, Guiyang 550025, China

Corresponding author: Qi-Long ZHANG, gzuqlzhang@126.com
Received Date: 23 July 2023
Revised Date: 1 November 2023

Figures(8)

We performed a coordination reaction between ligand 3-(5-(3-pyridyl)-2-(1, 3, 4-oxadiazoles))thio)-2, 4-glutaric ketone (L₁) and AgSbF₆ to obtain a coordination polymer {[Ag(L₁)₂]SbF₆}_n (1). The ligand 3-((5-(4-pyridyl)-2-(1, 3, 4-oxadiazole))thio-2, 4-pentanedione (L₂) was used to react with AgCF₃SO₃ to obtain a coordination polymer [Ag(L₂)(CF₃SO₃)]_n (2). The structures of the two complexes were characterized by powder X-ray diffraction, infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. In the solid state, coordination polymers 1 and 2 form 1D chain structures, and the coordination configuration of Ag(Ⅰ) ions is a twisted tetrahedron. The carbonyl oxygen atoms of the β-diketone units in the two complexes do not coordinate with Ag(Ⅰ) ions, providing the possibility for constructing heteronuclear complexes.
- β-diketone,
- Ag(Ⅰ) coordination polymers,
- crystal structure
1. [1]
  Kimura S, Matsuoka R, Kimura S, Nishihara H, Kusamoto T. Radical-based coordination polymers as a platform for magnetoluminescence[J]. J. Am. Chem. Soc., 2021,143:5610-5615. doi: 10.1021/jacs.1c00661
2. [2]
  Tsurui M, Kitagawa Y, Shoji S, Fushimi K, Hasegawa Y. Enhanced circularly polarized luminescence of chiral Eu(Ⅲ) coordination polymers with structural strain[J]. Dalton Trans., 2023,52:796-805. doi: 10.1039/D2DT03422K
3. [3]
  Zhao D S, Li W Q, Wen R M, Lei N N, Li W C, Liu X, Zhang X T, Fan L M. Eu(Ⅲ)-functionalized MOF-based dual-emission ratiometric sensor integrated with logic gate operation for efficient detection of hippuric acid in urine and serum[J]. Inorg. Chem., 2023,62:2715-2725. doi: 10.1021/acs.inorgchem.2c03828
4. [4]
  Li W Q, Zhao D S, Li W C, Wen R M, Liu X, Liu L Y, Li T, Fan L M. Chemorobust dye-encapsulated framework as dual-emission self-calibrating ratiometric sensor for intelligent detection of toluene exposure biomarker in urine[J]. Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 2023,296122637. doi: 10.1016/j.saa.2023.122637
5. [5]
  Wang F, Zhao D S, Li W Q, Zhang H H, Li B, Hu T P, Fan L M. Rod-shaped units based cobalt(Ⅱ) organic framework as an efficient electrochemical sensor for uric acid detection in serum[J]. Microchem. J., 2023,185108154. doi: 10.1016/j.microc.2022.108154
6. [6]
  LING G L, WANG M M, TANG X X, ZHANG R, NI Z H. Synthesis, crystal structure, and magnetic properties of a cyanide-bridged Fe₄^ⅢNi₂^Ⅱ hexa-nuclear complex based on tricyanideferrate(Ⅲ)[J]. Chinese J. Inorg. Chem., 2023,39(8):1564-1570.
7. [7]
  HUANG C, WANG K T, CHEN D M, ZHU B X, LU J H. Synthesis, crystal structures, luminescence, and vapor adsorption properties of 1D mercury(Ⅱ) coordination polymers based on two dipyridylamide ligands[J]. Chinese J. Inorg. Chem., 2022,38(11):2291-2298. doi: 10.11862/CJIC.2022.236
8. [8]
  ZHANG Q L, XU H, FENG G W, HUANG Y L. Syntheses, structures and luminescent properties of two silver coordination complexes based on bis(β-diketone) Schiff bases[J]. Chinese J. Inorg. Chem., 2016,32(8):1421-1426.
9. [9]
  Zuffa C, Cappuccino C, Marchini M, Contini L, Farinella F, Maini L. AgX-based hybrid coordination polymers: Mechanochemical synthesis, structure and luminescence property characterization[J]. Faraday Discuss., 2023,241:448-465. doi: 10.1039/D2FD00093H
10. [10]
  Ok M, Kim K Y, Choi H, Kim S, Lee S S, Cho J, Jung S H, Jung J H. Helicity-driven chiral self-sorting supramolecular polymerization with Ag⁺: Right- and left-helical aggregates[J]. Chem. Sci., 2022,13:3109-3117. doi: 10.1039/D1SC06413D
11. [11]
  Zhao C, Kong X Y, Shuang S M, Wang Y, Dong C. An anthraquinone-imidazole-based colorimetric and fluorescent sensor for the sequential detection of Ag⁺ and biothiols in living cells[J]. Analyst, 2020,145:3029-3037. doi: 10.1039/D0AN00164C
12. [12]
  Lee E, Hosoi Y, Temma H, Ju H, Ikeda M, Kuwahara S, Habata Y. Silver ion-induced chiral enhancement by argentivorous molecules[J]. Chem. Commun., 2020,56:3373-3376. doi: 10.1039/D0CC00798F
13. [13]
  Feng W X, Huang Y J, Zhao Y, Tian W, Yan H X. Water-soluble cationic Eu³⁺-metallopolymer with high quantum yield and sensitivity for intracellular temperature sensing[J]. ACS Appl. Mater. Interfaces, 2023,15:17211-17221. doi: 10.1021/acsami.3c00478
14. [14]
  Li X L, Wang A L, Li Y N, Gao C L, Cui M H, Xiao H P, Zhou L M. Two chiral Yb^Ⅲ enantiomeric pairs with distinct enantiomerically pure N-donor ligands presenting significant differences in photoluminescence, circularly polarized luminescence, and second-harmonic generation[J]. Inorg. Chem., 2023,62:4351-4360. doi: 10.1021/acs.inorgchem.3c00106
15. [15]
  Gildenast H, Hempelmann G, Gruszien L, Englert U. A rigid linker for site-selective coordination of transition metal cations: Combining an acetylacetone with a caged phosphine[J]. Inorg. Chem., 2023,62:3178-3185. doi: 10.1021/acs.inorgchem.2c04101
16. [16]
  Mao P D, Yao N T, Sun H Y, Yan F F, Zhang Y Q, Meng Y S, Liu T. Design of heterometallic {Ln^Ⅲ-M^Ⅴ} (Ln=Dy, Er; M=W, Mo) molecular nanomagnets: Protonation induced structural diversification[J]. Cryst. Growth Des., 2023,23:450-464. doi: 10.1021/acs.cgd.2c01112
17. [17]
  Sakovich M, Sokolova D, Alekseev I, Lentin I, Gorbunov A, Malakhova M, Ershov I, Zairov R, Korniltsev I, Podyachev S, Bezzubov S, Kovalev V, Vatsouro I. Enriching calixarene functionality with 1, 3-diketone groups[J]. Org. Chem. Front., 2023,10:3619-3636. doi: 10.1039/D3QO00759F
18. [18]
  ZHANG Q L, SUN L T, YANG X J, XU H, LI L L, YANG X S. Synthesis and crystal structure of Cu(Ⅱ)/Zn(Ⅱ)/Mn(Ⅱ) complexes containing 3-((5-(pyridin-3-yl)-1, 3, 4-oxadiazol-2-yl)thio)pentane-2, 4-dione ligand[J]. Chinese J. Inorg. Chem., 2021,37(6):989-994.
19. [19]
  Titov A A, Filippov O A, Smol'yakov A F, Godovikov I A, Shakirova J R, Tunik S P, Podkorytov I S, Shubina E S. Luminescent complexes of the trinuclear silver(Ⅰ) and copper(Ⅰ) pyrazolates supported with bis(diphenylphosphino)methane[J]. Inorg. Chem., 2019,58:8645-8656. doi: 10.1021/acs.inorgchem.9b00991
20. [20]
  Singh M P, Baruah J B. Photophysical properties of Ag, Zn and Cd-N-(4-pyridylmethyl)-1, 8-naphthalimide complexes: Influences of π-stacking and C—H…O interactions[J]. CrystEngComm, 2020,22:4374-4385. doi: 10.1039/D0CE00555J
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沈阳化工大学材料科学与工程学院沈阳 110142