Citation: Xing-Han CHEN, Min SHU, Feng LI, Rui ZHANG, Jian LIU. Synthesis and properties of electrochromic materials based on terpyridine-Fe(Ⅱ) coordination polymers[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(12): 2279-2286. doi: 10.11862/CJIC.2023.196 shu

Synthesis and properties of electrochromic materials based on terpyridine-Fe(Ⅱ) coordination polymers

Xing-Han CHEN ¹ ,
Min SHU ¹ ,
Feng LI ^2,, ,
Rui ZHANG ¹ ,
Jian LIU ^1,,

1.
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China
2.
Shandong Peninsula Engineering Research Center of Comprehensive Brine Utilization, Weifang University of Science and Technology, Weifang, Shandong 262700, China

Corresponding author: Feng LI, fengli81@163.com Jian LIU, liu.jian@njfu.edu.cn
Received Date: 15 August 2023
Revised Date: 1 November 2023

Figures(7)

In this work, novel terpyridine-Fe(Ⅱ) coordination polymers were prepared by introducing an aromatic ring as a π-spacer between two terpyridine units to construct multi-dented ligands, which were coordinated with Iron(Ⅱ) tetrafluoroborate hexahydrate. The electrochromic properties of the terpyridine-Fe(Ⅱ) coordination polymers were investigated. The results indicated that the introduction of fluorine atoms on the aromatic ring had a certain effect on their electrochromic properties. Among them, coordination polymer Fe-F2 prepared derived from the ligand F2 containing two fluorine atoms showed excellent electrochromic properties (optical contrast up to 69%, response time as short as 0.5 s, coloration efficiency over 320 cm²·C^-1).
- terpyridine,
- Fe(Ⅱ) coordination polymers,
- electrochromism
1. [1]
  Chen H J, Wang W Y, Zhu J J, Han Y Y, Liu J. Electropolymerization of D-A type EDOT-based monomers consisting of camphor substituted quinoxaline unit for electrochromism with enhanced performance[J]. Polymer, 2022,240124485. doi: 10.1016/j.polymer.2021.124485
2. [2]
  Fu W A, Chen H J, Han Y Y, Wang W Y, Zhang R, Liu J. Electropolymerization of D-A-D type monomers consisting of triphenylamine and substituted quinoxaline moieties for electrochromic devices[J]. New J. Chem., 2021,45(40):19082-19087. doi: 10.1039/D1NJ04074J
3. [3]
  Zhu J J, Wang W Y, Chen H J, Han Y Y, Liu J. Electropolymerization of D-A-D type monomers consisting of thiophene and quionaxline moieties for electrochromic devices and supercapacitors[J]. J. Solid State Chem., 2022,307122739. doi: 10.1016/j.jssc.2021.122739
4. [4]
  Cong S, Geng F X, Zhao Z G. Tungsten oxide materials for optoelectronic applications[J]. Adv. Mater., 2016,28(47):10518-10528. doi: 10.1002/adma.201601109
5. [5]
  Guo W B, Cong Z F, Guo Z H, Zhang P P, Chen Y H, Hu W G, Wang Z L, Pu X. Multifunctional self-charging electrochromic supercapacitors driven by direct-current triboelectric nanogenerators[J]. Adv. Funct. Mater., 2021,31(36)2104348. doi: 10.1002/adfm.202104348
6. [6]
  Jo M H, Kim K H, Ahn H J. P-doped carbon quantum dot graft-functionalized amorphous WO₃ for stable and flexible electrochromic energy-storage devices[J]. Chem. Eng. J., 2022,445136826. doi: 10.1016/j.cej.2022.136826
7. [7]
  Banasz R, Wałęsa-Chorab M. Polymeric complexes of transition metal ions as electrochromic materials: Synthesis and properties[J]. Coord. Chem. Rev., 2019,389:1-18. doi: 10.1016/j.ccr.2019.03.009
8. [8]
  Lu H C, Kao S Y, Yu H F, Chang T H, Kung C W, Ho K C. Achieving low-energy driven viologens-based electrochromic devices utilizing polymeric ionic liquids[J]. ACS Appl. Mater. Interfaces, 2016,8(44):30351-30361. doi: 10.1021/acsami.6b10152
9. [9]
  Lo C K, Shen D E, Reynolds J R. Fine-tuning the color hue of π-conjugated black-to-clear electrochromic random copolymers[J]. Macromolecules, 2019,52(17):6773-6779. doi: 10.1021/acs.macromol.9b01443
10. [10]
  Sato T, Higuchi M. An alternately introduced heterometallo-supramolecular polymer: synthesis and solid-state emission switching by electrochemical redox[J]. Chem. Commun., 2013,49(46):5256-5258. doi: 10.1039/c3cc41176a
11. [11]
  XING J N, SHU M, WANG W Y, ZHANG R, LIU J. Synthesis and properties of electrochromic material based on phenanthroline Fe(Ⅱ) complex with triphenylamine moiety[J]. Chinese J. Inorg. Chem., 2021,37(10):1847-1852.
12. [12]
  Malik N, Dov N E, de Ruiter G, Lahav M, van der Boom M E. On-surface self-assembly of stimuli-responsive metallo-organic films: Automated ultrasonic spray-coating and electrochromic devices[J]. ACS Appl. Mater. Interfaces, 2019,11(25):22858-22868. doi: 10.1021/acsami.9b05512
13. [13]
  Schott M, Szczerba W, Posset U, Vuk A S, Beck M, Riesemeier H, Thünemann A F, kurth D G. In operando XAFS experiments on flexible electrochromic devices based on Fe(Ⅱ)-metallo-supramolecular polyelectrolytes and vanadium oxide[J]. Sol. Energy Mater. Sol. Cells, 2016,147:61-67. doi: 10.1016/j.solmat.2015.10.015
14. [14]
  Shu M, Tao J Y, Han Y Y, Fu W A, Li X W, Zhang R, Liu J. Molecular engineering of terpyridine-Fe(Ⅱ) coordination polymers consisting of quinoxaline-based π-spacers toward enhanced electrochromic performance[J]. Polymer, 2022,256125231. doi: 10.1016/j.polymer.2022.125231
15. [15]
  Xing J N, Yue Y F, Zhang R, Liu J. Molecular engineering of head-tail terpyridine-Fe(Ⅱ) coordination polymers employing alkyl chain linkers toward enhanced electrochromic performance[J]. Dyes Pigment., 2021,189109233. doi: 10.1016/j.dyepig.2021.109233
16. [16]
  Mukkatt I, Mohanachandran A P, Nirmala A, Patra D, Sukumaran P A, Pillai R S, Rakhi R B, Shankar S, Ajayaghosh A. Tunable capacitive behavior in metallopolymer-based electrochromic thin film supercapacitors[J]. ACS Appl. Mater. Interfaces, 2022,14(28):31900-31910. doi: 10.1021/acsami.2c05744
17. [17]
  Mondal S, Santra D C, Ninomiya Y, Yoshida T, Higuchi M. Dualredox system of metallo-supramolecular polymers for visible-to-near-IR modulable electrochromism and durable device fabrication[J]. ACS Appl. Mater. Interfaces, 2020,12(52):58277-58286. doi: 10.1021/acsami.0c18109
18. [18]
  Chen W, Xue G. Low potential electrochemical syntheses of heteroaromatic conducting polymers in a novel solvent system based on trifluroborate-ethyl ether[J]. Prog. Polym. Sci., 2005,30(7):783-811. doi: 10.1016/j.progpolymsci.2005.03.002
1. [1]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
2. [2]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
3. [3]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
4. [4]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
5. [5]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
6. [6]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
7. [7]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
8. [8]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
9. [9]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
10. [10]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
11. [11]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
12. [12]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
13. [13]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
14. [14]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
15. [15]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
16. [16]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
17. [17]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
18. [18]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
19. [19]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
20. [20]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(440)
HTML views(52)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142