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Citation: Jun LI, Hua ZHAO, Hui-Peng LI, Jing-Jin LIU, Yu-Cheng WANG. Erythrocyte-like Bi3OXy(WO6)1-y (X=Cl, Br, I) solid solution with strong adsorption and visible light catalytic activity[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(11): 2169-2180. doi: 10.11862/CJIC.2023.188 shu

Erythrocyte-like Bi3OXy(WO6)1-y (X=Cl, Br, I) solid solution with strong adsorption and visible light catalytic activity

  • School of Petrochemical Engineering, Liaoning Petrochemical University, Fushun, Liaoning 113001, China

  • Corresponding author: Hua ZHAO, zh.113@126.com
  • Received Date: 7 June 2023
    Revised Date: 18 October 2023

    Fund Project: 辽宁省教育厅项目 LJKMZ20220721

Figures(10)

  • Bi3OXy(WO6)1-y (X=Cl, Br, I) solid solution materials were successfully prepared by a simple two-step hydrothermal method, which enhanced the adsorption and photocatalytic properties while changing the morphology. The structures and properties of the three composites were characterized in detail by X-ray diffraction (XRD), scanning electron microscopy (SEM), ultraviolet-visible diffuse reflection spectroscopy (UV-Vis DRS), X-ray photoelectron spectroscopy (XPS), and photoluminescence spectroscopy (PL). Solid solutions were speculated in principle. Compared to the BW monomer, the formation of the BI solid solution in Bi3OXy((WO6)1-y resulted in a decreased band-gap, which led to an enhanced capacity for absorbing visible light. Furthermore, it helped to reduce the recombination rate of electron-hole pairs generated by light. Bi3OXy((WO6)1-y exhibited a strong adsorption capacity for rhodamine B (RhB) cationic dye. Adsorption kinetics of different materials were investigated through adsorption experiments conducted at high concentrations.
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