Citation: Lin-Tao YU, Qi-Yang LI, Zhi SHEN, Wen-Jun Lü, Qiang ZHAO. Synthesis, fluorescence, and magnetic characterization of nicotinic acid ligand-based dysprosium, holmium, erbium, and thulium complexes[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(11): 2181-2187. doi: 10.11862/CJIC.2023.187 shu

Synthesis, fluorescence, and magnetic characterization of nicotinic acid ligand-based dysprosium, holmium, erbium, and thulium complexes

College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, Henan 473061, China

Corresponding author: Qiang ZHAO, zhaoqiang0522@126.com
Received Date: 31 May 2023
Revised Date: 28 September 2023

Fund Project: 河南省青年骨干教师资助项目 2020GGJS180南阳师范学院培育项目 2023PY001

Figures(6)

Four isomorphic rare earth complexes[M(Hcpna)(cpna)(H₂O)₃]_n, where M=Dy (1), Ho (2), Er (3), Tm (4), have been synthesized by a solvothermal method based on 5-(4-carboxyphenoxy)nicotinic acid ligand (H₂cpna) and rare earth metal ions Dy³⁺, Ho³⁺, Er³⁺, and Tm³⁺. Single crystal X-ray diffraction analyses reveal that complexes 1, 2, 3, and 4 are isostructural, and the structures are all 1D chain structures. The complexes were characterized by IR, elemental analysis, and powder X-ray diffraction, while the fluorescence and magnetic properties of the complexes were studied. The fluorescence test results show that the fluorescence intensity of complexes 1-4 were all lower than that of the H₂cpna ligand. The magnetism of complexes 1-4 were studied in the 2-300 K range at 1 kOe dc field. The χ_mT values of complexes 1, 2, 3, and 4 were 14.04, 14.15, 11.08, and 6.83 cm³·mol^-1·K respectively at room temperature.
- dysprosium(Ⅲ),
- holmium(Ⅲ),
- erbium(Ⅲ),
- thulium(Ⅲ),
- fluorescence,
- magnetism
1. [1]
  Martins V, Xu J, Wang X L, Chen K Z, Hung I A, Gan Z H, Gervais C, Bonhomme C, Jiang S J, Zheng A M, Lucier B E G, Huang Y N. Higher magnetic fields, finer MOF structural information: ¹⁷O solid-state NMR at 35.2 T[J]. J. Am. Chem.Soc., 2020,142:14877-14889. doi: 10.1021/jacs.0c02810
2. [2]
  Baranets S, Bobev S. Caught in action. The late rare earths thulium and lutetium substituting aluminum atoms in the structure of Ca₁₄AlBi₁₁[J]. J. Am. Chem. Soc., 2021,143:65-68. doi: 10.1021/jacs.0c11026
3. [3]
  Lin L, Li L H, Wu C, Huang Z P, Humphrey M G, Zhang C. Incorporating rare-earth cations with moderate electropositivity into iodates for the optimized second-order nonlinear optical performance[J]. Inorg. Chem. Front., 2020,7:2736-2746. doi: 10.1039/D0QI00162G
4. [4]
  SUN W Y. Coordination chemistry. 2nd ed. Beijing: Chemical Industry Press, 2010: 123-126
5. [5]
  HUANG J X, ZHAO H, LIU S Q, ZHANG J J. Two-dimensional luminescent coordination polymer based on dinuclear {Zn₂(COO)₄} second buildings units: Crystal structure and detection of Fe³⁺[J]. Chinese J. Inorg. Chem., 2021,37(8):1513-1518.
6. [6]
  Thielemann D T, Wagner A T, Rösch E, Kölmel D K, Heck J G, Rudat B, Neumaier M, Feldmann C, Schepers U, Bräse S, Roesky P W. Luminescent cell-penetrating pentadecanuclear lanthanide clusters[J]. J. Am. Chem. Soc., 2013,135:7454-7457. doi: 10.1021/ja403539t
7. [7]
  Liu Y C, Lin P, Du S W. Two novel homochiral enantiomorphicanic 3D metal-organic frameworks: Synthesis, crystal structure, luminescent and SHG properties[J]. Chin. J. Struct. Chem., 2013,10:1509-1516.
8. [8]
  Li H C, Li M F, He C, DUAN C Y. Construction of a noble-meta-free nickel metal-organic macrocycle for photocatalytic hydrogen production[J]. Chinese J. Inorg. Chem., 2018,34(1):11-19.
9. [9]
  Allendorf M D, Bauer C A, Bhakta R K. Luminescent metal-organic frameworks[J]. Chem. Soc. Rev., 2009,38:1330-1352. doi: 10.1039/b802352m
10. [10]
  Liu S J, Han S D, Zhao J P, Xu J L, Bu X H. In-situ synthesis of molecular magnetorefrigerant materials[J]. Coord. Chem. Rev., 2019,394:39-52. doi: 10.1016/j.ccr.2019.05.009
11. [11]
  Gao X S, Ding M J, Zhang J, Zhao L D, Ren X M. Phase selectivity and tunable photophysical nature of rare earth metal-organic frameworks of Eu_xY_1-x-PTC (H₃PTC=2, 4, 6-pyridine tricarboxylic acid; x= 0-1)[J]. Dalton Trans., 2020,49:14985-14994. doi: 10.1039/D0DT03150J
12. [12]
  Gu J Z, Liang X X, Cai Y, Wu J, Shi Z F, Kirillov A M. Hydrothermal assembly, structures, topologies, luminescence, and magnetism of a novel series of coordination polymers driven by a trifunctional nicotinic acid building block[J]. Dalton Trans., 2017,46:10908-10925. doi: 10.1039/C7DT01742A
13. [13]
  Shen Z, Zhao Q, Xie H Q, Feng Y Q, Chen S Y, Shi Z. Synthesis, optical and magnetic research of nicotinic acid ligand Zn, Cd, Mn and Co complexes[J]. J. Solid State Chem., 2021,302:122437-122443. doi: 10.1016/j.jssc.2021.122437
14. [14]
  Sheldrick G M. SADABS, Area-detector absorption correction. Siemens Industrial Automation, Inc., Madison, WI, 2001.
15. [15]
  Sheldrick G M. SHELXL-2018, Program for X-ray crystal structure solution. University of Göttingen, Germany, 2018.
16. [16]
  Chen G J, Gao C Y, Tian J L, Tang J K, Gu W, Liu X. Coordination-perturbed single-molecule magnet behavior of mononuclear dysprosium complexes[J]. Dalton Trans., 2011,40:5579-5583. doi: 10.1039/c1dt10050e
17. [17]
  Zhang Z Q, Wang P Y, Rong HW, Li L W. Structural and cryogenic magnetic properties of RE₂Ni₂In (RE=Pr, Nd, Dy and Ho) compounds[J]. Dalton Trans., 2019,48:17792-17799. doi: 10.1039/C9DT03245B
18. [18]
  Rasamsetty A, Das C, Sañudo E C, Shanmugam M, Baskar V. Effect of coordination geometry on the magnetic properties of a series of Ln₂ and Ln₄ hydroxo clusters[J]. Dalton Trans., 2018,47:1726-1738. doi: 10.1039/C7DT00172J
19. [19]
  Latendresse T P, Vieru V, Upadhyay A, Bhuvanesh N S, Chibotaru L F, Nippe M. Trends in trigonal prismatic Ln-[1] ferrocenophane complexes and discovery of a Ho³⁺ single-molecule magnet[J]. Chem. Sci, 2020,11:3936-3951. doi: 10.1039/D0SC01197E
20. [20]
  Gavrikov AV, Koroteev P S, Efimov N N, Dobrokhotova Z V, Ilyukhin A B, Kostopoulos A K, Ariciub A M, Novotortsev V M. Novel mononuclear and 1D-polymeric derivatives of lanthanides and (η⁶-benzoic acid) tricarbonylchromium: Synthesis, structure and magnetism[J]. Dalton Trans., 2017,46:3369-3380. doi: 10.1039/C6DT04895A
21. [21]
  Wang J, Miao H, Xiao Z X, Zhou Y, Deng L D, Zhang Y Q, Wang X Y. Syntheses, structures and magnetic properties of the lanthanide complexes of the pyrimidyl-substituted nitronyl nitroxide radical[J]. Dalton Trans., 2017,46:10452-10461. doi: 10.1039/C7DT01037K
22. [22]
  Huizi-Rayo U, Zabala-Lekuona A, Terenzi A, Cruz C. M, Cuerva J M, Rodríguez-Diéguez A, García J A, Seco J M, Sebastian E S, Cepeda J. Influence of thermally induced structural transformations on the magnetic and luminescence properties of tartrate-based chiral lanthanide organic-frameworks[J]. J. Mater. Chem. C, 2020,8:8243-8256. doi: 10.1039/D0TC00736F
23. [23]
  Anwar M U, Dawe L N, Tandon S S, Bungec S D, Thompson L K. Polynuclear lanthanide (Ln) complexes of a tri-functional hydrazone ligand mononuclear (Dy), dinuclear (Yb, Tm), tetranuclear (Gd), and hexanuclear (Gd, Dy, Tb) examples[J]. Dalton Trans., 2013,42:7781-7794. doi: 10.1039/c3dt32732a
24. [24]
  Kahn O. Molecular magnetism. Weinheim, New York: VCH-Verlag, 1993: 43-51
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