Citation: Guo-Li YANG, Min LI, Jian-Qing LI, Yong-Qiang CHEN, Qi YANG. Synthesis, structure, detonation performance, and catalytic property of energetic coordination polymer[Co₄(HBTI)₄(H₂O)₈][J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(11): 2188-2196. doi: 10.11862/CJIC.2023.181 shu

Synthesis, structure, detonation performance, and catalytic property of energetic coordination polymer[Co₄(HBTI)₄(H₂O)₈]

Guo-Li YANG ¹ ,
Min LI ¹ ,
Jian-Qing LI ¹ ,
Yong-Qiang CHEN ^1,, ,
Qi YANG ^2,,

1.
Department of Chemistry and Chemical Engineering, Jinzhong University, Jinzhong, Shanxi 030619, China
2.
College of Chemistry and Materials Science, Northwest University, Xi'an 710127, China

Corresponding author: Yong-Qiang CHEN, chenjzxy@126.com Qi YANG, yangqi@nwu.edu.cn
Received Date: 12 May 2023
Revised Date: 27 September 2023

Figures(9)

Based on the energetic ligand 4, 5-bis(tetrazol-5-yl)imidazole (H₃BTI), a novel energetic coordination polymer[Co₄(HBTI)₄(H₂O)₈] (1) was prepared under hydrothermal conditions. The crystal structure measurement indicates that 1 exhibits a tetranuclear structure with the central ion Co (Ⅱ) adopting octahedral geometry. The non-isothermal kinetic parameters of 1 were determined using two different methods including Kissinger and Ozawa-Doyle. Through the density functional theory (DFT) calculation, its explosive performance was further conducted. Additionally, its friction sensitivity and impact sensitivity were larger than 360 N and 40 J, respectively. Further-more, during the combustion decomposition process, compound 1 could effectively advance the decomposition temperature of ammonium perchlorate (AP) and 1, 3, 5-trinitro-1, 3, 5-triazacyclohexane (RDX) by 25 and 11℃, respectively.
- energetic coordination polymer,
- 4, 5-bistetrazole-imidazole,
- detonation performance,
- combustion catalysis
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, structure, detonation performance, and catalytic property of energetic coordination polymer[Co4(HBTI)4(H2O)8]

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通讯作者: 陈斌, bchen63@163.com

Synthesis, structure, detonation performance, and catalytic property of energetic coordination polymer[Co₄(HBTI)₄(H₂O)₈]