Citation: Ming-Hui LI, Qun YANG, Xing-Yu ZOU, Wu-Lin SONG, Da-Wen ZENG. Synthesis of erythrocyte-like CuS with twin structure and photo-Fenton catalytic performance[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(11): 2143-2150. doi: 10.11862/CJIC.2023.178 shu

Synthesis of erythrocyte-like CuS with twin structure and photo-Fenton catalytic performance

Ming-Hui LI ^{1, 2} ,
Qun YANG ³ ,
Xing-Yu ZOU ¹ ,
Wu-Lin SONG ^{1, 2,,} ,
Da-Wen ZENG ¹

1.
State Key Laboratory of Materials Processing and Die& Mould Technology, College of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
2.
Analytical and Testing Center, Huazhong University of Science and Technology, Wuhan 430074, China
3.
Wuhan Maritime Communication Research Institute, Wuhan 430205, China

Corresponding author: Wu-Lin SONG, wulins@126.com
Received Date: 17 February 2023
Revised Date: 4 October 2023

Figures(10)

An erythrocyte-like copper sulfide material with twins was synthesized by a solvothermal method. It was found that the different precursor proportions and reaction times play key roles in the formation of erythrocyte-like CuS. The formation mechanism of twin erythrocyte-like CuS was systematically elaborated. The Fenton-like system composed of CuS and H₂O₂ showed excellent degradation performance under visible light irradiation, and the degradation rate of methylene blue reached 95% after 50 min under visible light. The catalytic performance of the erythrocyte-like CuS and the synthetic flower ball-like CuS was compared, and the degradation performance of the erythrocyte-like CuS was better, indicating that the twin crystals accelerate the separation of photogenerated electrons-holes.
- erythrocyte-like CuS,
- twin boundary,
- photo-Fenton,
- pollutant degradation
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