Citation: Gang LI, Xin-Yu ZHANG, Feng-Li CHEN, Cheng-Cheng ZHANG, Bo-Hong GAO, Hai-Yan WEI, Xin-Yi WANG. Heterogeneous composites with coexisting spin-crossover and long-range magnetic ordering[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(11): 2197-2208. doi: 10.11862/CJIC.2023.173 shu

Heterogeneous composites with coexisting spin-crossover and long-range magnetic ordering

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
2.
School of Chemistry and Materials Science, Jiangsu Key Laboratory of Biofunctional Materials, Nanjing Normal University, Nanjing 210023, China

Corresponding author: Hai-Yan WEI, weihaiyan@njnu.edu.cn Xin-Yi WANG, wangxy66@nju.edu.cn
Received Date: 24 May 2023
Revised Date: 6 September 2023

Figures(9)

A facile precipitation transformation method at room temperature was employed to efficiently prepare the FeTrz@PB heterostructural composites containing both[Fe(Htrz)₂(trz)](BF₄) (Htrz=1H-1, 2, 4-triazole) and Prussian blue KFe^Ⅲ[Fe^Ⅱ(CN)₆] with the coexistence of spin crossover (SCO) and long-range magnetic ordering (LRMO). The controllable growth process of these heterostructural composites was fully characterized by scanning electron micro-scope, transmission electron microscope, powder X-ray diffraction, FTIR, X-ray photoelectron spectroscopy, energy-dispersion X-ray analysis, thermogravimetric analysis, and magnetic studies. The size of the PB particles and the appearance of FeTrz@PB can be tuned by controlling the reaction time. Increasing the reaction time leads to the increased ratio of the PB phase in the FeTrz@PB composites. Remarkably, magnetic studies on FeTrz@PB revealed the coexistence of SCO above room temperature (362-392 K) and LRMO at low temperatures (ca. 5.6 K). The high spin (HS) fraction and ZFC/FC intensity gradually increased with the growth time, while the heights of the hysteresis loops decreased gradually.
- spin crossover,
- long-range magnetic ordering,
- precipitation transformation,
- multifunctional magnetic materials
1. [1]
  Kumar K S, Ruben M. Emerging trends in spin crossover (SCO) based functional materials and devices[J]. Coord. Chem. Rev., 2017,346:176-205. doi: 10.1016/j.ccr.2017.03.024
2. [2]
  Molnár G, Rat S, Salmon L, Nicolazzi W, Bousseksou A. Spin crossover nanomaterials: From fundamental concepts to devices[J]. Adv. Mater., 2018,30(5)17003862.
3. [3]
  Enriquez-Cabrera A, Rapakousiou A, Bello M P, Molnár G, Salmon L, Bousseksou A. Spin crossover polymer composites, polymers and related soft materials[J]. Coord. Chem. Rev., 2020,419213396. doi: 10.1016/j.ccr.2020.213396
4. [4]
  Coronado E. Molecular magnetism: from chemical design to spin control in molecules, materials and devices[J]. Nat. Rev. Mater., 2020,5(2):87-104.
5. [5]
  Ge J Y, Chen Z Y, Zhang L, Liang X, Su J, Kurmoo M, Zuo J L. A two-dimensional Iron(Ⅱ) coordination polymer with synergetic spin-crossover and luminescent properties[J]. Angew. Chem. Int. Ed., 2019,58(26):1-6.
6. [6]
  Nieto-Castro D, Garcés-Pineda F A, Moneo-Corcuera A, Sánchez-Molina I, Galán-Mascarós J R. Mechanochemical processing of highly conducting organic/inorganic composites exhibiting spin crossover-induced memory effect in their transport properties[J]. Adv. Funct. Mater., 2021,31(33)2102469. doi: 10.1002/adfm.202102469
7. [7]
  Kühne I A, Ozarowski A, Sultan A, Esien K, Carter A B, Wix P, Casey A, Heerah-Booluck M, Keene T D, Müller-Bunz H, Felton S, Hill S, Morgan G G. Homochiral Mn³⁺ spin-crossover complexes: A structural and spectroscopic study[J]. Inorg. Chem., 2022,61(8):3458-3471. doi: 10.1021/acs.inorgchem.1c03379
8. [8]
  Wen W, Liu Q, Zhang S H, Yao N T, Oshio R O, Meng Y S, Liu T. Spin-crossover tuned rotation of pyrazolyl rings in a 2D Iron(Ⅱ) complex towards synergetic magnetic and dielectric transitions[J]. Angew. Chem. Int. Ed., 2022,61(34)e202208886. doi: 10.1002/anie.202208886
9. [9]
  Tissot A, Kesse X, Giannopoulou S, Stenger I, Binet L, Rivière E, Serre C. A spin crossover porous hybrid architecture for potential sensing applications[J]. Chem. Commun., 2019,55(2):194-197. doi: 10.1039/C8CC07573E
10. [10]
  Zappe L, Schönfeld S, Hörner G, Zenere K A, Leong C F, Kepert C J, D'Alessandro D M, Weber B, Neville S M. Spin crossover modulation in a coordination polymer with the redox-active bis-pyridyltetrathiafulvalene (py₂TTF) ligand[J]. Chem. Commun., 2020,56(72):10469-10472. doi: 10.1039/D0CC03788E
11. [11]
  Peng H, Wang D, Ma D S, Zhou Y, Zhang J H, Kang Y J, Yue Q. Multifunctional yolk-shell structured magnetic mesoporous polydopamine/carbon microspheres for photothermal therapy and heterogenous catalysis[J]. ACS Appl. Mater. Interfaces, 2022,14(20):23888-23895. doi: 10.1021/acsami.2c04689
12. [12]
  Dey B, Chandrasekhar V. Fe^Ⅱ spin crossover complexes containing N₄O₂ donor ligands[J]. Dalton Trans., 2022,51(37):13995-14021. doi: 10.1039/D2DT01967A
13. [13]
  Javed M K, Sulaiman A, Yamashita M, Li Z Y. Shedding light on bifunctional luminescent spin crossover materials[J]. Coord. Chem. Rev., 2022,467214625. doi: 10.1016/j.ccr.2022.214625
14. [14]
  Üngör Ö, Choi E S, Shatruk M. Optimization of crystal packing in semiconducting spin-crossover materials with fractionally charged TCNQ^δ^- anions (0 < δ < 1)[J]. Chem. Sci., 2021,12(32):10765-10779. doi: 10.1039/D1SC02843J
15. [15]
  Dugay J, Aarts M, Giménez-Marqués M, Kozlova T, Zandbergen H W, Coronado E, van der Zantt H S J. Phase transitions in spin-crossover thin films probed by graphene transport measurements[J]. Nano Lett., 2017,17(1):186-193. doi: 10.1021/acs.nanolett.6b03780
16. [16]
  Chen Y C, Meng Y, Ni Z P, Tong M L. Synergistic electrical bistability in a conductive spin crossover heterostructure[J]. J. Mater. Chem. C, 2015,3(5):945-949. doi: 10.1039/C4TC02580F
17. [17]
  Wang Y X, Qiu D, Xi S F, Ding Z D, Li Z J, Li Y X, Ren X H, Gu Z G. Iron(Ⅱ)-triazole core-shell nanocomposites: Toward multistep spin crossover materials[J]. Chem. Commun., 2016,52(51):8034-8037. doi: 10.1039/C6CC02334G
18. [18]
  Kosaka W, Nomura K, Hashimoto K, Ohkoshi S I. Observation of an Fe(Ⅱ) spin-crossover in a cesium iron hexacyanochromate[J]. J. Am. Chem. Soc., 2005,127(24):8590-8591. doi: 10.1021/ja050118l
19. [19]
  Arai M, Kosaka W, Matsuda T, Ohkoshi S I. Observation of an iron(Ⅱ) spin-crossover in an iron octacyanoniobate-based magnet[J]. Angew. Chem. Int. Ed., 2008,47(36):6885-6887. doi: 10.1002/anie.200802266
20. [20]
  Clemente-León M, Coronado E, López-Jordà M, Desplanches C, Asthana S, Wang H F, Létard J F. A hybrid magnet with coexistence of ferromagnetism and photoinduced Fe? spin-crossover[J]. Chem. Sci., 2011,2(6):1121-1127. doi: 10.1039/c1sc00015b
21. [21]
  Roubeau O, Evangelistia M, Natividad E. A spin crossover ferrous complex with ordered magnetic ferric anions[J]. Chem. Commun., 2012,48(61):7604-7606. doi: 10.1039/c2cc33709f
22. [22]
  Abhervé A, Grancha T, Ferrando-Soria J, Clemente-León M, Coronado E, Waerenborgh J C, Lloreta F, Pardo E. Spin-crossover complex encapsulation within a magnetic metal-organic framework[J]. Chem. Commun., 2016,52(46):7360-7363. doi: 10.1039/C6CC03667H
23. [23]
  Okubo M, Li C H, Talham D R. High rate sodium ion insertion into core-shell nanoparticles of Prussian blue analogues[J]. Chem. Commun., 2014,50(11):1353-1355. doi: 10.1039/C3CC47607C
24. [24]
  Gros C R, Peprah M K, Hosterman B D, Brinzari T V, Quintero P A, Sendova M, Meisel M W, Talham D R. Light-induced magnetization changes in a coordination polymer heterostructure of a Prussian blue analogue and a Hofmann-like Fe(Ⅱ) spin crossover compound[J]. J. Am. Chem. Soc., 2014,136(28):9846-9849. doi: 10.1021/ja504289p
25. [25]
  Gros C R, Peprah M K, Felts A C, Brinzari T V, Risset O N, Cain J M, Ferreira C F, Meisel M W, Talham D R. Synergistic photomagnetic effects in coordination polymer heterostructure particles of Hofmann-like Fe(4-phenylpyridine)₂[Ni(CN)₄]·0.5H₂O and K_0.4Ni[Cr(CN)₆]_0.8·nH₂O[J]. Dalton Trans., 2016,45(42):16624-16634. doi: 10.1039/C6DT02353C
26. [26]
  Herren F, Fisher P, Ludi A, Halg W. Neutron diffraction study of Prussian blue, Fe₄[Fe(CN)₆]₃·xH₂O[J]. Inorg. Chem., 1980,19(4):956-959. doi: 10.1021/ic50206a032
27. [27]
  Hu Y, Zhu T S, Guo Z P, Popli H, Malissa H, Huang Y L, An L, Li Z, Armstrong J N, Boehme C, Vardeny Z V, N'Diaye A T, Zhou C, Wuttig M, Grossman J C, Ren S Q. Printing air-stable high-T_c molecular magnet with tunable magnetic interaction[J]. Nano Lett., 2022,22(2):545-553.
28. [28]
  Boström H L B, Cairns A B, Liu L, Lazorc P, Collings I E. Spin crossover in the Prussian blue analogue FePt(CN)₆ induced by pressure or X-ray irradiation[J]. Dalton Trans., 2020,49(37):12940-12944. doi: 10.1039/D0DT02036B
29. [29]
  Glatz J, Jiménez J R, Godeffroy L, von Bardeleben H J, Fillaud L, Maisonhaute E, Li Y L, Chamoreau L M, Lescouëzec R. Enlightening the alkali ion role in the photomagnetic effect of FeCo Prussian blue analogues[J]. J. Am. Chem. Soc., 2022,144(24):10888-10901. doi: 10.1021/jacs.2c03421
30. [30]
  Egan L, Kamenev K, Papanikolaou D, Takabayashi Y, Margadonna S. Pressure-induced sequential magnetic pole inversion and antiferromagnetic-ferromagnetic crossover in a trimetallic Prussian blue analogue[J]. J. Am. Chem. Soc., 2006,128(18):6034-6035. doi: 10.1021/ja061514m
31. [31]
  Wang W L, Gang Y, Hu Z, Yan Z C, Li W J, Li Y C, Gu Q F, Wang Z X, Chou S L, Liu H K, Dou S X. Reversible structural evolution of sodium-rich rhombohedral Prussian blue for sodium-ion batteries[J]. Nat. Commun., 2020,11(1)980. doi: 10.1038/s41467-020-14444-4
32. [32]
  Zhang M, Zhou J, Yu J L, Shi L D, Ji M W, Liu H C, Li D Z, Zhu C Z, Xu J. Mixed analogous heterostructure based on MXene and Prussian blue analog derivative for high-performance flexible energy storage[J]. Chem. Eng. J., 2020,387123170. doi: 10.1016/j.cej.2019.123170
33. [33]
  Vega-Moreno J, Lemus-Santana A A, Reguera E, Andrio A, Compañ A. High proton conductivity at low and moderate temperature in a simple family of Prussian blue analogs, divalent transition metal hexacyanocobaltates[J]. Electrochim. Acta, 2020,360136959. doi: 10.1016/j.electacta.2020.136959
34. [34]
  Boudjema L, Long J, Salles F, Larionova J, Guari Y, Trens P. A switch in the hydrophobic/hydrophilic gas-adsorption character of Prussian blue analogues: An affinity control for smart gas sorption[J]. Chem.-Eur. J., 2019,25(2):479-484. doi: 10.1002/chem.201804730
35. [35]
  Lin X J, Cao S F, Chen H Y, Chen X D, Wang Z J, Zhou S N, Xu H, Liu S Y, Wei S X, Lu X Q. Boosting oxygen evolution reaction of hierarchical spongy NiFe-PBA/Ni₃C(B) electrocatalyst: Interfacial engineering with matchable structure[J]. Chem. Eng. J., 2022,433133524. doi: 10.1016/j.cej.2021.133524
36. [36]
  Guari Y, Cahu M, Felix G, Sene S, Long J, Chopineau J, Devoisselle J M, Larionova J. Nanoheterostructures based on nanosized Prussian blue and its analogues: Design, properties and applications[J]. Coord. Chem. Rev., 2022,461214497. doi: 10.1016/j.ccr.2022.214497
37. [37]
  Wu X Y, Ru Y, Bai Y, Zhang G X, Shi Y X, Pang H. PBA composites and their derivatives in energy and environmental applications[J]. Coord. Chem. Rev., 2022,451214260. doi: 10.1016/j.ccr.2021.214260
38. [38]
  Qin Z G, Li Y, Gu N. Progress in applications of Prussian blue nanoparticles in biomedicine[J]. Adv. Healthc. Mater., 2018,7(20)1800347. doi: 10.1002/adhm.201800347
39. [39]
  He W H, Cain J M, Meisel M W, Talham D R. Interplay between core and shell in a RbCoFe@RbNiCo Prussian blue analogue spin transition heterostructure[J]. J. Mater. Chem. C, 2021,9(33):10830-10840. doi: 10.1039/D1TC01514A
40. [40]
  Sanchis-Gual R, Otero T F, Coronado-Puchau M, Coronado E. Enhancing the electrocatalytic activity and stability of Prussian blue analogues by increasing their electroactive sites through the introduction of Au nanoparticles[J]. Nanoscale, 2021,13(29):12676-12686. doi: 10.1039/D1NR02928B
41. [41]
  Maurin-Pasturel G, Long J, Guari Y, Godiard F, Willinger M G, Guerin C, Larionova J. Nanosized heterostructures of Au@Prussian blue analogues: Towards multifunctionality at the nanoscale[J]. Angew. Chem. Int. Ed., 2014,53(15):3872-3876. doi: 10.1002/anie.201310443
42. [42]
  Cabrera-Garcia A, Checa-Chavarria E, Pacheco-Torres J, Bernabeu-Sanz A, Vidal-Moya A, Rivero-Buceta E, Sastre G, Fernández E, Botella P. Engineered contrast agents in a single structure for T₁-T₂ dual magnetic resonance imaging[J]. Nanoscale, 2018,10(14):6349-6360. doi: 10.1039/C7NR07948F
43. [43]
  Kahn O, Martinez C J. Spin-transition polymers: From molecular materials toward memory devices[J]. Science, 1998,279(5347):44-48. doi: 10.1126/science.279.5347.44
44. [44]
  Piedrahita-Bello M, Angulo-Cervera J E, Courson R, Molnár G, Malaquin L, Thibault C, Tondu B, Salmon L, Bousseksou A. 4D printing with spin-crossover polymer composites[J]. J. Mater. Chem. C, 2020,8(18):6001-6005. doi: 10.1039/D0TC01532F
45. [45]
  Torres-Cavanillas R, Morant-Giner M, Escorcia-Ariza G, Dugay J, Canet-Ferrer J, Tatay S, Cardona-Serra S, Gimenez-Marques M, Galbiati M, Forment-Aliaga A, Coronado E. Spin-crossover nanoparticles anchored on MoS₂ layers for heterostructures with tunable strain driven by thermal or light-induced spin switching[J]. Nat. Chem., 2021,13(11):1101-1109. doi: 10.1038/s41557-021-00795-y
46. [46]
  Roubeau O. Triazole-based one-dimensional spin-crossover coordination polymers[J]. Chem.-Eur. J., 2012,18(48):15230-15244. doi: 10.1002/chem.201201647
47. [47]
  Tanaka D, Aketa N, Tanaka H, Horike S, Fukumori M, Tamaki T, Inose T, Akai T, Toyama H, Sakata O, Tajiri H, Ogawa T. Facile preparation of hybrid thin films composed of spin-crossover nanoparticles and carbon nanotubes for electrical memory devices[J]. Dalton Trans., 2019,48(21):7074-7079. doi: 10.1039/C8DT02923G
48. [48]
  Li Z H, Wang Y X, Han W K, Zhu W, Li T, Li Z J, Ren X H, Gu Z G. Integrating spin-crossover nanoparticles with silver nanowires: Toward magnetic and conductive bifunctional nanomaterials[J]. New J. Chem., 2017,41(18):10062-10068. doi: 10.1039/C7NJ02089A
49. [49]
  Palluel M, Tran N M, Daro N, Buffière S, Mornet S, Freysz E, Chastanet G. The interplay between surface plasmon resonance and switching properties in gold@spin crossover nanocomposites[J]. Adv. Funct. Mater., 2020,30(17)2000447. doi: 10.1002/adfm.202000447
50. [50]
  Piedrahita-Bello M, Martin B, Salmon L, Molnár G, Demont P, Bousseksou A. Mechano-electric coupling in P(VDF-TrFE)/spin crossover composites[J]. J. Mater. Chem. C, 2020,8(18):6042-6051. doi: 10.1039/D0TC00780C
51. [51]
  Gural'skiy I A, Quintero C M, Costa J S, Demont P, Molnár G, Salmon L, Shepherd , H J, Bousseksou A. Spin crossover composite materials for electrothermomechanical actuators[J]. J. Mater. Chem. C, 2014,2(16):2949-2955. doi: 10.1039/C4TC00267A
52. [52]
  Manrique-Juárez M D, Mathieu F, Laborde A, Rat S, Shalabaeva V, Demont P, Thomas O, Salmon L, Leichle T, Nicu L, Molnár G, Bousseksou A. Micromachining-compatible, facile fabrication of polymer nanocomposite spin crossover actuators[J]. Adv. Funct. Mater., 2018,28(29)1801970. doi: 10.1002/adfm.201801970
53. [53]
  Rat S, Piedrahita-Bello M, Salmon L, Molnár G, Demont P, Bousseksou A. Coupling mechanical and electrical properties in spin crossover polymer composites[J]. Adv. Mater., 2018,30(8)1705275. doi: 10.1002/adma.201705275
54. [54]
  Titos-Padilla S, Herrera J M, Chen X W, Delgado J J, Colacio E. Bifunctional hybrid SiO₂ nanoparticles showing synergy between core spin crossover and shell luminescence properties[J]. Adv. Mater., 2018,50(14):3290-3293.
55. [55]
  Suleimanov I, Kraieva O, Costa J S, Fritsky I O, Molnár G, Salmon L, Bousseksou A. Electronic communication between fluorescent pyrene excimers and spin crossover complexes in nanocomposite particles[J]. J. Mater. Chem. C, 2015,3(19):5026-5032. doi: 10.1039/C5TC00667H
56. [56]
  Suleimanov I, Kraieva O, Molnár G, Salmon L, Bousseksou A. Enhanced luminescence stability with a Tb-spin crossover nanocomposite for spin state monitoring[J]. Chem. Commun., 2015,51(82):15098-15101. doi: 10.1039/C5CC06426K
57. [57]
  Díaz-Ortega I F, Fernández-Barbosa E L, Titos-Padilla S, Pope S J A, Jiménez J R, Colacio E, Herrera J M. Monitoring spin-crossover phenomena via Re(Ⅰ) luminescence in hybrid Fe(Ⅱ) silica coated nanoparticles[J]. Dalton Trans., 2021,50(44):16176-16184. doi: 10.1039/D1DT03334D
58. [58]
  Jia Y, Ji Y G, Xue Q, Li F M, Zhao G T, Jin P J, Li S N, Chen Y. Efficient nitrate-to-ammonia electroreduction at cobalt phosphide nanoshuttles[J]. ACS Appl. Mater. Interfaces, 2021,13(38):45521-45527. doi: 10.1021/acsami.1c12512
59. [59]
  Xiao X, Zhang G X, Xu Y X, Zhang H L, Guo X T, Liu Y, Pang H. A new strategy for the controllable growth of MOF@PBA architectures[J]. J. Mater. Chem. A, 2019,7(29):17266-17271. doi: 10.1039/C9TA05409J
60. [60]
  Samain L, Grandjean F, Long G J, Martinetto P, Bordet P, Strivay D. Relationship between the synthesis of Prussian blue pigments, their color, physical properties, and their behavior in paint layers[J]. J. Phys. Chem. C, 2013,117(19):9693-9712. doi: 10.1021/jp3111327
61. [61]
  Siddiqui S A, Domanov O, Schafler E, Vejpravova J, Shiozawa H. Synthesis and size-dependent spin crossover of coordination polymer [Fe(Htrz)₂(trz)](BF₄)[J]. J. Mater. Chem. C, 2021,9(3):1077-1084. doi: 10.1039/D0TC03878D
62. [62]
  Palluel M, El Khoury L, Daro N, Buffière S, Josse M, Marchivie M, Chastanet G. Rational direct synthesis of [Fe(Htrz)₂(trz)](BF₄) polymorphs: Temperature and concentration effects[J]. Inorg. Chem. Front., 2021,8(15):3697-3706. doi: 10.1039/D1QI00482D
63. [63]
  Mamontova E, Daurat M, Long J, Godefroy A, Salles F, Guari Y, Gary-Bobo M, Larionova J. Fashioning Prussian blue nanoparticles by adsorption of luminophores: Synthesis, properties, and in vitro imaging[J]. Inorg. Chem., 2020,59(7):4567-4575. doi: 10.1021/acs.inorgchem.9b03699
64. [64]
  Zhao Z X, Xu S W, Du Z J, Jiang C, Huang X Z. Metal-organic framework-based PB@MoS₂ core-shell microcubes with high efficiency and broad bandwidth for microwave absorption performance[J]. ACS Sustainable Chem. Eng., 2019,7(7):7183-7192. doi: 10.1021/acssuschemeng.9b00191
65. [65]
  Wu X Y, Qiu S, Xu Y K, Ma L, Bi X X, Yuan Y F, Wu T P, Shahbazian-Yassar R, Lu J, Ji X L. Hydrous nickel-iron Turnbull's blue as a high-rate and low temperature proton electrode[J]. ACS Appl. Mater. Interfaces, 2020,12(8):9201-9208. doi: 10.1021/acsami.9b20320
66. [66]
  Zhou P H, Xue D S. Finite-size effect on magnetic properties in Prussian blue nanowire arrays[J]. J. Appl. Phys., 2004,96(1):610-614. doi: 10.1063/1.1737044
67. [67]
  Uemura T, Kitagawa S. Prussian blue nanoparticles protected by poly(vinylpyrrolidone)[J]. J. Am. Chem. Soc., 2003,125(26):7814-7815. doi: 10.1021/ja0356582
68. [68]
  Kumar B, Paul A, Mondal D J, Paliwal P, Konar S. Spin-state modulation in Fe^Ⅱ-based Hofmann-type coordination polymers: From molecules to materials[J]. Chem. Rec., 2022,22(11)e2022001.
69. [69]
  Cain J M, He W H, Maurin I, Meisel M W, Talham D R. Stimulus induced strain in spin transition heterostructures[J]. J. Appl. Phys., 2021,129(16)160903. doi: 10.1063/5.0045939
70. [70]
  Liu S S, Zhou K, Yuan T L, Lei W R, Chen H Y, Wang X Y, Wang W. Imaging the thermal hysteresis of single spin-crossover nanoparticles[J]. J. Am. Chem. Soc., 2020,142(37):15852-1585. doi: 10.1021/jacs.0c05951
1. [1]
  Yinglian LI , Chengcheng ZHANG , Xinyu ZHANG , Xinyi WANG . Spin crossover in [Co(pytpy)₂]²⁺ complexes modified by organosulfonate anions. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1162-1172. doi: 10.11862/CJIC.20240087
2. [2]
  Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411
3. [3]
  Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215
4. [4]
  Shuangying Li , Qingxiang Zhou , Zhi Li , Menghua Liu , Yanhui Li . Sensitive measurement of silver ions in environmental water samples integrating magnetic ion-imprinted solid phase extraction and carbon dot fluorescent sensor. Chinese Chemical Letters, 2024, 35(5): 108693-. doi: 10.1016/j.cclet.2023.108693
5. [5]
  Xianzheng Zhang , Yana Chen , Zhiyong Ye , Huilin Hu , Ling Lei , Feng You , Junlong Yao , Huan Yang , Xueliang Jiang . Magnetic field-assisted microbial corrosion construction iron sulfides incorporated nickel-iron hydroxide towards efficient oxygen evolution. Chinese Journal of Structural Chemistry, 2024, 43(1): 100200-100200. doi: 10.1016/j.cjsc.2023.100200
6. [6]
  Yan Cheng , Hua-Peng Ruan , Yan Peng , Longhe Li , Zhenqiang Xie , Lang Liu , Shiyong Zhang , Hengyun Ye , Zhao-Bo Hu . Magnetic, dielectric and luminescence synergetic switchable effects in molecular material [Et₃NCH₂Cl]₂[MnBr₄]. Chinese Chemical Letters, 2024, 35(4): 108554-. doi: 10.1016/j.cclet.2023.108554
7. [7]
  Ning DING , Siyu WANG , Shihua YU , Pengcheng XU , Dandan HAN , Dexin SHI , Chao ZHANG . Crystalline and amorphous metal sulfide composite electrode materials with long cycle life: Preparation and performance of hybrid capacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1784-1794. doi: 10.11862/CJIC.20240146
8. [8]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
9. [9]
  Lihua HUANG , Jian HUA . Denitration performance of HoCeMn/TiO₂ catalysts prepared by co-precipitation and impregnation methods. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 629-645. doi: 10.11862/CJIC.20230315
10. [10]
  Xian-Fa Jiang , Chongyun Shao , Zhongwen Ouyang , Zhao-Bo Hu , Zhenxing Wang , You Song . Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109011-. doi: 10.1016/j.cclet.2023.109011
11. [11]
  Yudi Cheng , Xiao Wang , Jiao Chen , Zihan Zhang , Jiadong Ou , Mengyao She , Fulin Chen , Jianli Li . A near-infrared fluorescent probe for visualizing transformation pathway of Cys/Hcy and H₂S and its applications in living system. Chinese Chemical Letters, 2024, 35(5): 109156-. doi: 10.1016/j.cclet.2023.109156
12. [12]
  Jianqiu Li , Yi Zhang , Songen Liu , Jie Niu , Rong Zhang , Yong Chen , Yu Liu . Cucurbit[8]uril-based non-covalent heterodimer realized NIR cell imaging through topological transformation from nanowire to nanorod. Chinese Chemical Letters, 2024, 35(10): 109645-. doi: 10.1016/j.cclet.2024.109645
13. [13]
  Shuangliang Xie , Yuyue Chen , Qing He , Liang Chen , Jikun Yang , Shiqing Deng , Yimei Zhu , He Qi . Relaxor antiferroelectric-relaxor ferroelectric crossover in NaNbO₃-based lead-free ceramics for high-efficiency large-capacitive energy storage. Chinese Chemical Letters, 2024, 35(7): 108871-. doi: 10.1016/j.cclet.2023.108871
14. [14]
  Zikang Hu , Hengjie Zhang , Zhengqiu Li , Tianbao Zhao , Zhipeng Gu , Qijuan Yuan , Baoshu Chen . Multifunctional photothermal hydrogels: Design principles, various functions, and promising biological applications. Chinese Chemical Letters, 2024, 35(10): 109527-. doi: 10.1016/j.cclet.2024.109527
15. [15]
  Fengyun Li , Zerong Pei , Shuting Chen , Gen li , Mengyang Liu , Liqin Ding , Jingbo Liu , Feng Qiu . Multifunctional nano-herb based on tumor microenvironment for enhanced tumor therapy of gambogic acid. Chinese Chemical Letters, 2024, 35(5): 108752-. doi: 10.1016/j.cclet.2023.108752
16. [16]
  Yu Qin , Mingyang Huang , Chenlu Huang , Hannah L. Perry , Linhua Zhang , Dunwan Zhu . O₂-generating multifunctional polymeric micelles for highly efficient and selective photodynamic-photothermal therapy in melanoma. Chinese Chemical Letters, 2024, 35(7): 109171-. doi: 10.1016/j.cclet.2023.109171
17. [17]
  Kangmin Wang , Liqiu Wan , Jingyu Wang , Chunlin Zhou , Ke Yang , Liang Zhou , Bijin Li . Multifunctional 2-(2′-hydroxyphenyl)benzoxazoles: Ready synthesis, mechanochromism, fluorescence imaging, and OLEDs. Chinese Chemical Letters, 2024, 35(10): 109554-. doi: 10.1016/j.cclet.2024.109554
18. [18]
  Shaohua Zhang , Liyao Liu , Yingqiao Ma , Chong-an Di . Advances in theoretical calculations of organic thermoelectric materials. Chinese Chemical Letters, 2024, 35(8): 109749-. doi: 10.1016/j.cclet.2024.109749
19. [19]
  Junjie Wang , Yan Wang , Zhengdong Li , Changqiang Xie , Musammir Khan , Xingzhou Peng , Fabiao Yu . Triphenylamine-AIEgens photoactive materials for cancer theranostics. Chinese Chemical Letters, 2024, 35(6): 108934-. doi: 10.1016/j.cclet.2023.108934
20. [20]
  Hui Liu , Xiangyang Tang , Zhuang Cheng , Yin Hu , Yan Yan , Yangze Xu , Zihan Su , Futong Liu , Ping Lu . Constructing multifunctional deep-blue emitters with weak charge transfer excited state for high-performance non-doped blue OLEDs and single-emissive-layer hybrid white OLEDs. Chinese Chemical Letters, 2024, 35(10): 109809-. doi: 10.1016/j.cclet.2024.109809

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(431)
HTML views(30)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142