Citation: Su ZHANG, Qiu-Hong YANG, Qi-Di LI. Dielectric properties of low-temperature sintered NaBi(WO₄)₂ ceramics[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(10): 1923-1930. doi: 10.11862/CJIC.2023.149 shu

Dielectric properties of low-temperature sintered NaBi(WO₄)₂ ceramics

Su ZHANG ^{1, 2} ,
Qiu-Hong YANG ^1,, ,
Qi-Di LI ²

1.
School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China
2.
Suzhou Semitel Electronics Co., Ltd., Suzhou, Jiangsu 215163, China

Corresponding author: Qiu-Hong YANG, yangqiuhong@shu.edu.cn
Received Date: 3 March 2023
Revised Date: 22 August 2023

Figures(12)

A novel NaBi(WO₄)₂ (NBW) ceramic prepared by solid-phase synthesis, the phase structure, morphology, sintering properties, and microwave dielectric properties of NBW ceramic were investigated. NBW is a chemical properties stable compound and was used without special packaging. The NBW ceramic can be sintered densification at temperatures from 625 to 800 ℃ for 1-4 h. The X-ray diffraction showed that the NBW ceramic sintered at temperatures from 625 to 800 ℃ for 2 h is a tetragonal crystal scheelite structure single-phase ceramic. With the increase of sintered temperature, the permittivity and quality factor (Qf value) first increased then decreased, while the temperature coefficient of resonant frequency gradually decreased. The dielectric properties of NBW ceramic sintered at 650 ℃ for 2 h were permittivity of 14.36, Qf of 16 503 GHz, and temperature coefficient of resonant frequency of -1.055 ×10^-5 ℃^-1. When NBW was co-fired with Ag, it reacted with Ag to form Ag₂W₂O₇, but NBW had chemical compatibility with Au and Al.
- low-temperature co-fired ceramic,
- NaBi(WO₄)₂ ceramic,
- dielectric property,
- microwave dielectric ceramic
1. [1]
  Sebastian M T, Jantunen H. Low loss dielectric materials for LTCC applications: A review[J]. Int. Mater. Rev., 2013,53(2):57-90.
2. [2]
  Yu H T, Liu J S, Zhang W L, Zhang S R. Ultra-low sintering temperature ceramics for LTCC applications: A review[J]. J. Mater. Sci-Mater. Electron., 2015,26(12):9414-9423. doi: 10.1007/s10854-015-3282-y
3. [3]
  Sebastian M T, Wang H, Jantunen H. Low temperature co-fired ceramics with ultra-low sintering temperature: A review[J]. Curr. Opin. Solid State Mater. Sci., 2016,20(3):151-170. doi: 10.1016/j.cossms.2016.02.004
4. [4]
  Imanaka Y. Multilayered low temperature cofired ceramics (LTCC) technology. New York: Springer Science & Business Media, 2005:1-98
5. [5]
  Yu H T, Ju K, Wang K M. A novel glass-ceramic with ultra-low sintering temperature for LTCC Application[J]. J. Am. Ceram. Soc., 2014,97(3):704-707. doi: 10.1111/jace.12854
6. [6]
  Xi J, Cheng G H, Liu F, Shang F, Xu J, Zhou C R, Yuan C G, Yuan C L. Synthesis, microstructure and characterization of ultra-low permittivity CuO-ZnO-B₂O₃-Li₂O glass/Al₂O₃ composites for ULTCC application[J]. Ceram. Int., 2017,18(45):24431-24436.
7. [7]
  Pullar R C, Farrah S, Alford N M. MgWO₄, ZnWO₄, NiWO₄ and CoWO₄ microwave dielectric ceramics[J]. J. Eur. Ceram. Soc., 2007,27(2/3):1059-1063.
8. [8]
  Wang X Y, Lv J Q, Xu Y, Zhang L C, Shen Y, Zhou H F, Di Z, Song K X, Guo H, Shi F. Dielectric responses and structure-property relationships of Ca_1-xBa_xWO₄ composite microwave dielectric ceramics[J]. J. Alloy. Compd., 2022,925166669. doi: 10.1016/j.jallcom.2022.166669
9. [9]
  Zhang Q, Xu L L, Tang X L, Zhang H W, Zhou Y T, Jing Y L, Li Y N, Su H. Structural characteristics and microwave dielectric properties of Zn_1-xBi_xV_xW_1-xO₄-based ceramics for LTCC applications[J]. J. Eur. Ceram. Soc., 2022,42(13):5691-5697. doi: 10.1016/j.jeurceramsoc.2022.06.033
10. [10]
  Zhou D, Wang H, Pang L X, Randall C A, Yao X. Bi₂O₃-MoO₃ binary system: An alternative ultralow sintering temperature microwave dielectric[J]. J. Am. Ceram. Soc., 2009,92(10):2242-2246. doi: 10.1111/j.1551-2916.2009.03185.x
11. [11]
  Valant M, Suvorov D. Chemical compatibility between silver electrodes and low-firing binary-oxide compounds conceptual study[J]. J. Am. Ceram. Soc., 2000,83(11):2721-2729.
12. [12]
  Valant M, Suvorov D. Glass-free low-temperature cofired ceramics: Calcium germanates, silicates and tellurates[J]. J. Eur. Ceram. Soc., 2004,24(6):1715-1719. doi: 10.1016/S0955-2219(03)00483-7
13. [13]
  Ohashi M, Ogawa H, Kan A, Tanaka E. Microwave dielectric properties of low-temperature sintered Li₃AlB₂O₆ ceramic[J]. J. Eur. Ceram. Soc., 2005,25(12):2877-2881. doi: 10.1016/j.jeurceramsoc.2005.03.158
14. [14]
  Yoon S H, Kim D W, Cho S Y, Hong K S. Investigation of the relations between structure and microwave dielectric properties of divalent metal tungstate compounds[J]. J. Eur. Ceram. Soc., 2006,26(10/11):2051-2054.
15. [15]
  Fang L, Wei Z, Guo H H, Sun Y H, Tang Y, Li C C. Phase composition and microwave dielectric properties of low-firing Li₂A₂W₃O₁₂ (A=Mg, Zn) ceramics[J]. J. Mater. Sci-Mater. Electro., 2015,26(8):5892-5895. doi: 10.1007/s10854-015-3158-1
16. [16]
  Bian J J, Wu J Y. Designing of glass-free LTCC microwave ceramic Ca_1-x(Li_0.5)_xWO₄ by crystal chemistry[J]. J. Am. Ceram. Soc., 2012,95(1):318-323. doi: 10.1111/j.1551-2916.2011.04790.x
17. [17]
  Zhang S, Su H, Zhang H, Jing Y L, Tang X L. Microwave dielectric properties of CaWO₄-Li₂TiO₃ ceramics added with LBSCA glass for LTCC applications[J]. Ceram. Int., 2016,42(14):15242-15246. doi: 10.1016/j.ceramint.2016.06.161
18. [18]
  Huang B, Chen G, Xia T, Shang F. Microwave dielectric properties of Li₂WO₄-added SrWO₄ ceramics for LTCC applications[J]. J. Mater. Sci-Mater. Electro., 2022,33(27):21925-21934. doi: 10.1007/s10854-022-08980-6
19. [19]
  Zhou D, Randall C A, Pang L X, Wang H, Guo J, Zhang G Q, Wu X G, Shui L, Yao X. Microwave dielectric properties of Li₂WO₄ ceramic with ultra-low sintering temperature[J]. J. Am. Ceram. Soc., 2011,94(2):348-350. doi: 10.1111/j.1551-2916.2010.04312.x
20. [20]
  Dong H L, Hu C X, Wang W J, Bao H P, Liu W J, Yang B. Novel low-permittivity, low-sintering-temperature Na₂WO₄ microwave dielectric ceramics for LTCC applications[J]. J. Ceram. Sci. Technol., 2018,9(4):471-476.
21. [21]
  Hao J, Guo J, Zhao E, Si M M, Yuan X F, Yao F Z, Wang H. Grain size effect on microwave dielectric properties of Na₂WO₄ ceramics prepared by cold sintering process[J]. Ceram. Int., 2020,46(17):27193-27198. doi: 10.1016/j.ceramint.2020.07.200
22. [22]
  Hanuza J, Benzar A, Haznar A, Maczka M, Pietraszko A, Maas van der J H. Structure and vibrational dynamics of tetragonal NaBi(WO₄)₂ scheelite crystal[J]. Vib. Spectrosc., 1996,12(1996):25-36.
23. [23]
  LIU J H, YILI C R, SUN J, WANG Y W, LI J L, ZHANG L, YU Y Q. Growth of Nd doped NaBi(WO₄)₂ crystal[J]. Journal of the Chinese Ceramic Society, 2003,31(2):165-168.
24. [24]
  LI J L, XU B, LIU J H, LI Y H, LI L, ZHANG L, ZHAO Y. Study on crystal growth parameters for NaBi(WO₄)₂ single crystal[J]. Journal of Synthetic Crystals, 2001,30(3):250-255.
25. [25]
  Shannon R D. Dielectric polarizabilities of ions in oxides and fluorides[J]. J. Appl. Phys., 1993,73(1):348-366. doi: 10.1063/1.353856
26. [26]
  Zhang G Q, Wang H, Guo J, He L, Wei D D, Yuan Q B. Ultra-low sintering temperature microwave dielectric ceramics based on Na₂O-MoO₃ binary system[J]. J. Am. Ceram. Soc., 2015,98(2):528-533. doi: 10.1111/jace.13297
27. [27]
  Feteira A, Sinclair D C. Microwave dielectric properties of low firing temperature Bi₂W₂O₉ ceramics[J]. J. Am. Ceram. Soc., 2008,91(4):1338-1341.
28. [28]
  Guo B, Liu P, Yang T, Zhang H W. Thermal stable microwave dielectric properties of CdWO₄ ceramics prepared by high energy ball milling method[J]. J. Alloy. Compd., 2015,650:777-782.
1. [1]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
2. [2]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
3. [3]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
4. [4]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
5. [5]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
6. [6]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
7. [7]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
8. [8]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
9. [9]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
10. [10]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
11. [11]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
12. [12]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
13. [13]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
14. [14]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
15. [15]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
16. [16]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
17. [17]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
18. [18]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
19. [19]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
20. [20]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(388)
HTML views(71)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Dielectric properties of low-temperature sintered NaBi(WO4)2 ceramics

Metrics

通讯作者: 陈斌, bchen63@163.com

Dielectric properties of low-temperature sintered NaBi(WO₄)₂ ceramics