Citation: Zhi-Hu MA, Yi-Xia REN, Zhi-Xiang WANG, Mei-Li ZHANG, Ji-Jiang WANG. Preparation and characterization of 2D nickel coordination polymer (Ni-CP) and Ag@Ni-CP Schottky junctions for photocatalytic degradation of cationic dyes[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(10): 2009-2019. doi: 10.11862/CJIC.2023.148 shu

Preparation and characterization of 2D nickel coordination polymer (Ni-CP) and Ag@Ni-CP Schottky junctions for photocatalytic degradation of cationic dyes

Shaanxi Key Laboratory of Chemical Reaction Engineering, Laboratory of New Energy and New Function Materials, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

Corresponding author: Yi-Xia REN, renyixia1@163.com
Received Date: 1 March 2023
Revised Date: 10 June 2023

Figures(6)

A new 2D nickel (Ⅱ) coordination polymer (Ni - CP) has been synthesized hydrothermally, named as [Ni(DDB)_0.5(2, 2'-bipy)(H₂O)]·H₂O (H₄DDB=1, 4-di(3, 5-dicarboylphenoxy) benzene, 2, 2'-bipy=2, 2'-bipyridine), and characterized by element analysis, thermogravimetric analysis, powder X-ray diffraction, scanning electron microscopy, and X-ray photoelectron spectroscopy. Single-crystal structural analysis shows that the coordination polymer possesses a 2D waved network through DDB^4- ligand in μ₄ fashion. Ag-loaded products (Ag@Ni-CP) with Schottky junction were prepared by the photoreduction method. Photocatalytic degradation performance of Ni-CP and Ag@ Ni-CP were investigated, and the latter exhibited excellent degradation effect, especially for rhodamine B and methylene blue with a high degradation rate of 99% rapidly in 60 min. Ag@Ni-CP exhibited higher and faster degradation performance than the reported MOF catalyst materials. The photocatalytic mechanism was investigated by free radical trapping experiments.
- nickel(Ⅱ) coordination polymer,
- Ag@Ni-CP,
- crystal structure,
- photocatalytic degradation,
- cationic dye
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