Citation: Ce WANG, Nai-Jian SONG, Jing-Yi LI. Synthesis and fluorescence properties of single-phase Mn-based white light metal-organic framework[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(9): 1751-1756. doi: 10.11862/CJIC.2023.137 shu

Synthesis and fluorescence properties of single-phase Mn-based white light metal-organic framework

College of Chemistry and Material, Weinan Normal University, Weinan, Shaanxi 714099, China

Corresponding author: Ce WANG, wangce1214@163.com
Received Date: 29 December 2022
Revised Date: 12 June 2023

Figures(6)

A novel white light metal-organic framework (Me₄N)₃[Mn₃(btc)₂(Hbtc)(CH₃COO)]·7CH₃OH (1) was prepared by a solvothermal method using 1,3,5-benzenetricarboxylic acid (H₃btc) and MnCl₂·4H₂O. The compound was characterized by single-crystal X-ray diffraction and infrared spectrum, and its thermal stability and white fluorescence properties were studied. The results show that compound 1 emitted red light, white light, and blue light at 287, 355, and 375 nm, respectively. The emissions of the organic ligands H₃btc (390 nm) may be ascribed to the π→π^* or π^*→n transitions. Compound 1 showed dual-modal emission at 455 and 675 nm (λ_ex=355 nm) and showed a red shift compared to H₃btc, which may be the result of ligand-to-metal charge transfer (LMCT). The CIE chromaticity coordinates were used to visualize the emission spectrum, and the white chromaticity coordinates were (0.286, 0.256).
- metal-organic framework,
- fluorescent property,
- single-phase,
- white light
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