Citation: Heng LU, Xiao-Hong TAN, Shao-Ru WU, Yan-Mei ZHOU, Guo-Bin HUANG, Jun-Ying ZHANG, Qiao-Wen ZHENG, Zhi-Xiong CAI, Fei-Ming LI, Mao-Sheng ZHANG. Preparation of polymethyl methacrylate-coated (CH₃NH₃)PbBr₃ nanocrystalline electrospinning film and fluorescence sensing of ammonia[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(9): 1757-1765. doi: 10.11862/CJIC.2023.135 shu

Preparation of polymethyl methacrylate-coated (CH₃NH₃)PbBr₃ nanocrystalline electrospinning film and fluorescence sensing of ammonia

Heng LU ^{1, 2, #} ,
Xiao-Hong TAN ^{3, #} ,
Shao-Ru WU ^{1, 2} ,
Yan-Mei ZHOU ¹ ,
Guo-Bin HUANG ⁴ ,
Jun-Ying ZHANG ^{1, 2} ,
Qiao-Wen ZHENG ^{1, 2} ,
Zhi-Xiong CAI ^{1, 2} ,
Fei-Ming LI ^{1, 2} ,
Mao-Sheng ZHANG ^{1, 2,,}

1.
College of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou 363000, China
2.
Fujian Province Key Laboratory of Modern Analytical Science and Separation Technology, Minnan Normal University, Zhangzhou, Fujian 363000, China
3.
College of Chemistry, Guangdong University of Petrochemical Technology, Maoming, Guangdong 525000, China
4.
Institute of Food Safety and Environment Monitoring, Fuzhou University, Fuzhou 350108, China

Corresponding author: Mao-Sheng ZHANG, zms0557@mnnu.edu.cn
Received Date: 22 November 2022
Revised Date: 18 May 2023

Figures(7)

In this work, a novel polymethyl methacrylate-coated MAPbBr₃ nanocrystalline (MAPbBr₃@PMMA, MA=methylammonium) electrospinning film was synthesized by in situ growth method, and NH₃ sensor was constructed based on the fluorescence significant quenching of the MAPbBr₃@PMMA electrospinning film after the addition of NH₃ gas. The morphology and structure of MAPbBr₃@PMMA fiber were characterized by scanning electron microscopy, transmission electron microscopy, powder X-ray diffraction, and infrared spectroscopy, and its optical properties were characterized by UV-Vis and fluorescence spectroscopy. The results showed that the prepared NH₃ sensor showed a good linear relationship (r=0.995 9) to NH₃ gas concentration in a range of 8-90 mg·L^-1, low detection limit (3 mg·L^-1), and high reproducibility and selectivity. Finally, the standard recovery and the relative standard deviation (RSD) for NH₃ of actual sample gas were 92.2%-102.1% and 1.8%-3.2%, respectively.
- perovskite,
- (CH₃NH₃)PbBr₃,
- electrospinning,
- fluorescence sensing,
- ammonia
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of polymethyl methacrylate-coated (CH3NH3)PbBr3 nanocrystalline electrospinning film and fluorescence sensing of ammonia

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通讯作者: 陈斌, bchen63@163.com

Preparation of polymethyl methacrylate-coated (CH₃NH₃)PbBr₃ nanocrystalline electrospinning film and fluorescence sensing of ammonia