Manganese ion oxidation precipitation method for the recycling and reusing of LiNi0.8Co0.05Mn0.15O2 materials for lithium-ion batteries
- Corresponding author: Ping HE, pinghe@nju.edu.cn
Citation: Zhao-Cheng WANG, Yi-Gang WANG, Chuan-Chao SHENG, Ping HE, Hao-Shen ZHOU. Manganese ion oxidation precipitation method for the recycling and reusing of LiNi0.8Co0.05Mn0.15O2 materials for lithium-ion batteries[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(9): 1661-1672. doi: 10.11862/CJIC.2023.130
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The four influencing factors affecting the leaching process of concentrated hydrochloric acid, except for the variables; Constant conditions: the temperature was 70 ℃, the dosing ratio was 6 mL·g-1, the time was 120 min, and the hydrochloric acid concentration was 5 mol·L-1.
The control group used the method of sequential precipitation of metal ions by adding NaOH, the experimental group used the method of preferential precipitation of leached products by oxidizing Mn2+, with error bars and error ranges marked. It indicates that the fluctuation range of the recovery and purity, taking the recovery of Li in the experimental group as an example, with an error bar of 2.9, the recovery of Li in multiple experiments ranged from 92.1% to 97.9% (Fig. 3a).
(a-c) Li2CO3; (d-f) MnO2; (g-i) Co3O4; (j-l) Ni2O3
The loading of pouch cell was 20.8 mg·cm2, the rate was 1C (99.8 mA), and the current density was 8.32 mA·cm2.