Citation: Kai-Min WANG, Xiong ZHAO, Xu-Ling BAI, Yan-Qiu DONG, Rui-Feng FAN, Hong-Mei YU, Huai-Jun TANG, Yu-Lu MA. A fluorescence sensor based on Cd(Ⅱ) coordination polymer for recognition of nitrofurantoin[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(8): 1587-1596. doi: 10.11862/CJIC.2023.125 shu

A fluorescence sensor based on Cd(Ⅱ) coordination polymer for recognition of nitrofurantoin

1.
School of Chemistry & Environment, Yunnan Minzu University, Kunming 650504, China
2.
School of Pharmaceutical Sciences and Yunnan Key Laboratory of Pharmacology for Natural Products, Kunming Medical University, Kunming 650500, China

Corresponding author: Kai-Min WANG, kmwang041684@163.com Rui-Feng FAN, 171951246@qq.com Yu-Lu MA, yuluma163@163.com
Received Date: 13 February 2023
Revised Date: 24 May 2023

Figures(6)

A new 2D coordination polymer (CP) [Cd₂(L)(dbpy)₂(HCOO)(H₂O)]•3H₂O (1), where H₃L=5-((4-carboxybenzyl)amino)isophthalic acid and dbpy=5, 5′-dimethyl-2, 2′-bipyridine, was successfully synthesized by solvothermal method. The structure of CP 1 was characterized by single-crystal X-ray diffraction, powder X-ray diffraction, elemental analysis, IR, thermogravimetric analysis, and solid fluorescence spectroscopy. The structure of CP 1 can be simplified into a 3-connected 2D hcb layer with the point symbol of (6³). More importantly, CP 1 could selectively and sensitively recognize antibiotic nitrofurantoin in an aqueous medium by fluorescence quenching effect and had a low detection limit (LOD=0.19 μmol•L^-1). In addition, the fluorescence quenching mechanism may be caused by the fluorescence resonance energy transfer.
- Cd(Ⅱ),
- coordination polymer,
- fluorescence sensor,
- nitrofurantoin,
- antibiotic residue
1. [1]
  Lei M Y, Ge F Y, Ren S S, Gao X J, Zheng H G. A water-stable Cd-MOF and corresponding MOF@melamine foam composite for detection and removal of antibiotics, explosives, and anions[J]. Sep. Purif. Technol., 2022,286120433. doi: 10.1016/j.seppur.2021.120433
2. [2]
  Gao X T, Chen N N, Cao M L, Shi Y, Zhang Q F. A water-stable 3D Eu(Ⅲ)-organic framework as a Bi-functional ratiometric luminescent sensor for fast, sensitive and selective detection of ODZ and Hg²⁺ in aqueous media[J]. Chin. J. Struct. Chem., 2022,412211110.
3. [3]
  Zhang Q Q, Ying G G, Pan C G, Liu Y S, Zhao J L. Comprehensive evaluation of antibiotics emission and fate in the river basins of China: Source analysis, multimedia modeling, and linkage to bacterial resistance[J]. Environ. Sci. Technol., 2015,49(11):6772-6782. doi: 10.1021/acs.est.5b00729
4. [4]
  Kanzariya D B, Goswami R, Muthukumar D, Pillai R S, Pal T K. Highly luminescent MOF and its in situ fabricated sustainable corn starch gel composite as a fluoro-switchable reversible sensor triggered by antibiotics and oxo-anions[J]. ACS Appl. Mater. Interfaces, 2022,14(43):48658-48674. doi: 10.1021/acsami.2c13571
5. [5]
  Batt A L, Aga D S. Simultaneous analysis of multiple classes of antibiotics by ion trap LC/MS/MS for assessing surface water and groundwater contamination[J]. Anal. Chem., 2005,77(9):2940-2947. doi: 10.1021/ac048512+
6. [6]
  Bai Y, Zhang M L, Wang B T, Ren Y X, Zhao Y C, Yang H, Yang X G. Four MOFs with isomeric ligands as fluorescent probes for highly selective, sensitive and stable detection of antibiotics in water[J]. CrystEngComm, 2022,24:169-181. doi: 10.1039/D1CE01261D
7. [7]
  Tian C, Ren X, He M, Chen B B, Hu B. Core-shell magnetic porous organic polymer for magnetic solid-phase extraction of fluoroquinolone antibiotics in honey samples followed by high-performance liquid chromatography with fluorescence detection[J]. J. Sep. Sci., 2022,45(4):874-882. doi: 10.1002/jssc.202100678
8. [8]
  Viñas P, Balsalobre N, López-Erroz C, Hernández-Córdoba M. Liquid chromatography with ultraviolet absorbance detection for the analysis of tetracycline residues in honey[J]. J. Chromatogr. A, 2004,1022:125-129. doi: 10.1016/j.chroma.2003.09.066
9. [9]
  Paul P, Reynaert J, Griend C S D, Adams E, Schepdael A V. Development and validation of a CE method for the determination of tetracyclines with capacitively coupled contactless conductivity detection[J]. Chromatographia, 2019,82:1395-1403. doi: 10.1007/s10337-019-03755-4
10. [10]
  Wu X Y, Xu Z Q, Huang Z, Shao C Y. Large volume sample stacking of cationic tetracycline antibiotics toward 10 ppb level analysis by capillary electrophoresis with UV detection[J]. Electrophoresis, 2016,37(22):2963-2969. doi: 10.1002/elps.201600189
11. [11]
  Yu C X, Jiang W, Wang K Z, Liang A P, Song J G, Zhou Y L, Sun X Q, Liu L L. Luminescent two-dimensional metal-organic framework nanosheets with large π-conjugated system: Design, synthesis, and detection of anti-inflammatory drugs and pesticides[J]. Inorg. Chem., 2022,61(2):982-991. doi: 10.1021/acs.inorgchem.1c03040
12. [12]
  Li X, Zhang S, Zhang L, Yang Y, Zhang K, Cai Y C, Xu Y, Gai Y L, Xiong K C. Viologen-based cationic metal-organic framework for antibiotics detection and MnO₄^- removal in water[J]. Cryst. Growth Des., 2022,22(7):3991-3997. doi: 10.1021/acs.cgd.2c00170
13. [13]
  Zhao Y, Jing J, Yan N, Han M L, Yang G P, Ma L F. Different benzendicarboxylate-directed structural variations and properties of four new porous Cd(Ⅱ)-pyridyl-triazole coordination polymers[J]. Front. Chem., 2020,8616468. doi: 10.3389/fchem.2020.616468
14. [14]
  Su P C, Zhang A R, Yu L, Ge H W, Wang N, Huang S Y, Ai Y J, Wang X K, Wang S H. Dual-functional UiO-type metal-organic frameworks for the sensitive sensing and effective removal of nitrofurans from water[J]. Sens. Actuator B-Chem., 2022,350130865. doi: 10.1016/j.snb.2021.130865
15. [15]
  Benzaqui M, Wahiduzzaman M, Zhao H, Hasan M R, Steenhaut T, Saad A, Marrot J, Normand P, Greneche J M, Heymans N, Weireld G D, Tissot A, Shepard W, Filinchuk Y, Hermans S, Carn F, Manlankowska M, Tellez C, Coronas J, Maurin G, Steunou N, Serre C. A robust eco-compatible microporous iron coordination polymer for CO₂ capture[J]. J. Mater. Chem. A, 2022,10:8535-8545. doi: 10.1039/D1TA10385G
16. [16]
  Chen X, Qiao Z W, Hou B, Jiang H, Gong W, Dong J Q, Li H Y, Cui Y, Liu Y. Chiral metal-organic frameworks with tunable catalytic selectivity in asymmetric transfer hydrogenation reactions[J]. Nano Res., 2021,14:466-472. doi: 10.1007/s12274-020-2905-7
17. [17]
  SHI M F, LI L F, YANG L Z, YU H M, XIAO M, TANG H J, WANG K M. Synthesis and photocatalytic study of two semi-conductive Co(Ⅱ) coordination polymers[J]. Acta Scientiarum Naturalium Universitatis Sunyatseni, 2022,61(6):74-80.
18. [18]
  Zhao J J, Liu P Y, Dong Z P, Liu Z L, Wang Y Q. Eu(Ⅲ)-organic framework as a multi-responsive photoluminescence sensor for efficient detection of 1-naphthol, Fe³⁺ and MnO₄^- in water[J]. Inorg. Chim. Acta, 2020,511119843. doi: 10.1016/j.ica.2020.119843
19. [19]
  Liang J Y, Zulkifli M Y B, Choy S, Li Y, Gao M, Kong B, Yun J, Liang K. Metal-organic framework-plant nano biohybrids as living sensors for on-site environmental pollutant detection[J]. Environ. Sci. Technol., 2020,54(18):11356-11364. doi: 10.1021/acs.est.0c04688
20. [20]
  WANG K M, GUO J R, ZHANG Q, TANG H J, WANG Y N, MA Y L. Synthesis, structure and fluorescence properties of pyridonium amphoteric Cd(Ⅱ) complexes containing charge separation centers[J]. Journal of Yunnan University (Natural Sciences Edition), 2022,44(3):576-584.
21. [21]
  Gao Y F, Zhang X Q, Sun W, Liu Z L. A robust microporous metal-organic framework as a highly selective and sensitive, instantaneous and colorimetric sensor for Eu³⁺ ions[J]. Dalton Trans., 2015,44(4):1845-1849. doi: 10.1039/C4DT02752C
22. [22]
  Xu X Y, Bing Y. A fluorescent wearable platform for sweat Cl^- analysis and logic smart-device fabrication based on color adjustable lanthanide MOFs[J]. J. Mater. Chem. C, 2018,6(7):1863-1869. doi: 10.1039/C7TC05204A
23. [23]
  Kondo A, Noro S I, Kajiro H, Kanoh H. Structure- and phase-transformable coordination polymers/metal complexes with fluorinated anions[J]. Coord. Chem. Rev., 2022,471214728. doi: 10.1016/j.ccr.2022.214728
24. [24]
  Gurtovyi R I, Gavrish S P, Tsymbal L V, Apostu M O, Cazacu M, Shova S, Lampeka Y D. 2D coordination polymers and ionic complexes of the nickel(Ⅱ) and zinc(Ⅱ) cyclam cations with trigonal carboxylate linkers based on triazine core. Crystal structures, supramolecular catenation and spectral characterization[J]. Polyhedron, 2022,221115870. doi: 10.1016/j.poly.2022.115870
25. [25]
  WANG K M, SHI M F, LI L F, FAN B M, SUN W Q, MA Y L. Construction of water stable Zn(Ⅱ) metal-organic framework iron ion fluorescence probe with mixed ligand[J]. Acta Scientiarum Naturalium Universitatis Sunyatseni, 2023,62(1):142-148. doi: 10.13471/j.cnki.acta.snus.2022c010
26. [26]
  Sun S L, Sun X Y, Sun Q, Gao E Q. Highly efficient fluorescent chemosensor for nitro antibiotic detection based on luminescent coordination polymers with 2, 6-di(4-carboxyphenyl)pyrazine[J]. CrystEngComm, 2021,23(17):3167-3174. doi: 10.1039/D1CE00245G
27. [27]
  WANG K M, LI L F, SHI M F, YE Y Q, WANG Y N, GUO J R, TANG H J, MA Y L. Crystal structure of Eu(Ⅲ) coordination polymer based on zwitterionic ligand and detection of furacilin[J]. Chinese J. Inorg. Chem., 2022,38(9):1843-1852.
28. [28]
  Su Y Q, Fu L S, Cui G H. Two chemically robust Cd(Ⅱ)-frameworks for efficient sensing of levofloxacin, benzaldehyde, and Fe³⁺ ions[J]. Dalton Trans., 2021,50(43):15743-15753. doi: 10.1039/D1DT03205D
29. [29]
  Sheldrick G M. Crystal structure refinement with SHELXL[J]. Acta Crystallogr. Sect. C, 2015,C71:3-8.
30. [30]
  Yu X Y, Dong W W, Han H M, Zhao J, Li D S. A water-stable Zn(Ⅱ) coordination polymer as fluorescent sensor for selective and sensitive detection of antibiotics and Fe³⁺[J]. J. Solid State Chem., 2021,296122032. doi: 10.1016/j.jssc.2021.122032
31. [31]
  Wang K M, Yang L Z, Li L F, Dong X Y, Wang Z L, Tang H J, Sun W Q, Ma Y L. A water-stable zwitterionic Cd(Ⅱ) coordination polymer as fluorescent sensor for the detection of oxo-anions and dimetridazole in milk[J]. Arab. J. Chem., 2022,15(11)104295. doi: 10.1016/j.arabjc.2022.104295
32. [32]
  Zeng N N, Ren L, Cui G H. Ultrasensitive fluorescence detection of norfloxacin in aqueous medium employing a 2D Zn(Ⅱ)-based coordination polymer[J]. CrystEngComm, 2022,24(5):931-935.
33. [33]
  Yang Y X, Guo Y W, Xia S Y, Ma X N, Wu X X. Metal-organic framework sensors based on triazole carboxylic acid ligands for ion sensing and dye adsorption[J]. J. Solid State Chem., 2022,331123113.
34. [34]
  Wang K M, Yang L Z, Li L F, Ma Y L, Guo J R, Wang Z L, Tang H J, Wang Y N, Zhou J. Highly sensitive and rapid fluorescence detection of chlortetracycline in milk using a water- and pH-stable Zn(Ⅱ) coordination polymer derived from zwitterionic and N-donor ligands[J]. J. Solid State Chem., 2022,316123606.
35. [35]
  Wang X M, Liu C, Wang M, Zhou X H, YouY J, Xiao H P. A selective fluorescence turn-on sensing coordination polymer for antibiotic aztreonam[J]. Chem. Commun., 2022,58(29):4667-4670.
36. [36]
  Ye Y, Ge B D, Meng X Y, Liu Y H, Wang S, Song X W, Liang Z Q. An yttrium-organic framework based on a hexagonal prism second building unit for luminescent sensing of antibiotics and highly effective CO₂ fixation[J]. Inorg. Chem. Front., 2022,9(2):391-400.
37. [37]
  Zhu G S, Cheng S L, Zhou Z D, Du B, Shen Y Y, Yu B Y. Bisligand-coordinated cadmium organic frameworks as fluorescent sensors to detect ions, antibiotics and pesticides in aqueous solutions[J]. Polyhedron, 2022,217115759.
38. [38]
  Wang K M, Li L F, Yang L Z, Guo J R, Wang Z L, Tang H J, Ma Y L. A water-stable zwitterionic Zn(Ⅱ) coordination polymer as a luminescent sensor for the nitrofurazone antibiotic in milk[J]. Polyhedron, 2022,226116092.
39. [39]
  Niu M Y, Yang X P, Ma Y N, Wang C R, Hao W X, Shi D L, Schipper D. Construction of an octanuclear Zn(Ⅱ)-Yb(Ⅲ) Schiff base complex for the NIR luminescent sensing of Nitrofuran antibiotics[J]. Chin. J. Chem., 2021,39(8):2083-2087.
40. [40]
  Xu S, Shi J J, Ding B, Liu Z Y, Wang X G, Zhao X J, Yang E C. A heterometallic sodium(Ⅰ)-europium(Ⅲ)-organic layer exhibiting dual-responsive luminescent sensing for nitrofuran antibiotics, Cr₂O₇^2- and MnO₄^- anions[J]. Dalton Trans., 2019,48(5):1823-1834.
41. [41]
  Ma Y N, Yang X P, Shi D L, Niu M Y, Schipper D. Construction of a 18-Metal neodymium(Ⅲ) nanoring with NIR luminescent sensing to antibiotics[J]. Inorg. Chem., 2020,59(23):17608-17613.
42. [42]
  Zhang Y J, Yang J D, Zhao D S, Liu Z J, Li D C, Fan L M, Hu T P. Two cadmium(Ⅱ) coordination polymers as luminescent sensors for the detection of nitrofuran/nitroimidazole antibiotics[J]. CrystEngComm, 2019,21(41):6130-6135.
43. [43]
  Yang H W, Xu P, Ding B, Liu Z Y, Zhao X J, Yang E C. A highly stable luminescent Eu-MOF exhibiting efficient response to nitrofuran antibiotics through the inner filter effect and photoinduced electron transfer[J]. Eur. J. Inorg. Chem., 2019(48):5077-5084.
44. [44]
  Xu N, Zhang Q H, Zhang G A. A carbazole-functionalized metal-organic framework for efficient detection of antibiotics, pesticides and nitroaromatic compounds[J]. Dalton Trans., 2019,48(8):2683-2691.
45. [45]
  Wang Y, Xu J, Wang R Z, Liu H, Yu S S, Xing L B. Supramolecular polymers based on host-guest interactions for the construction of artificial light-harvesting systems[J]. Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 2022,279(15)121402.
46. [46]
  Zhang L Q, Wang X W, Gu L, Yu Y H, Gao J S. Three pairs of luminescent coordination polymers based on Co^Ⅱ and Cd^Ⅱ clusters for the detection of antibiotics, pesticides and chiral nitro aromatic compounds[J]. RSC Adv., 2020,10(16):9476-9485.
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