Citation: Tao LI, Li WANG, You-Fu XIA, Li-Li WANG, Yue SHEN. Two-dimensional covalent organic frameworks based on Ni-Salphen: Preparation and capacitive performance[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(9): 1691-1698. doi: 10.11862/CJIC.2023.123 shu

Two-dimensional covalent organic frameworks based on Ni-Salphen: Preparation and capacitive performance

Traditional Chinese Medicine College, Bozhou University, Bozhou, Anhui 236800, China

Corresponding author: Tao LI, 2012020003@bzuu.edu.cn
Received Date: 22 March 2023
Revised Date: 8 June 2023

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To develop covalent organic frameworks supercapacitors electrode materials, functional designs is important practical significance to enhance electrochemical performance. Two-dimensional covalent organic frameworks (COFs) based on Ni-Salphen (Ni-Salphen-COF) has been constructed by the reaction of 2, 3, 6, 7, 10, 11-hexaaminotri-phenylene (HATP) and 4, 6-dihydroxy-5-methyl-1, 3-diformyl benzene (DMDB). Structures, morphology, and electro-chemical properties of the Ni-Salphen-COF were characterized via a series of methods. The three-electrode test results suggest that Ni-Salphen-COF showed excellent specific capacitance of 531 F·g^-1 and good cycle stability (capacity retention of 89% after 10 000 cycles) at the current density of 1 A·g^-1. Meanwhile, Ni-Salphen-COF//AC (AC: activated carbon) in the two-electrode system displayed the specific capacitance of 176 F·g^-1 at 1 A·g^-1, and the highest energy density was up to 55 Wh·kg^-1 at a power density of 900 W·kg^-1. Compared to Salphen-COF with-out Ni, Ni-Salphen-COF showed a high specific capacitance. The electrochemical performance could be attributed to Ni-Salphen units, increasing in electrical conductivity, redox-active, and charge transfer activity.
- covalent organic frameworks,
- supercapacitors,
- Ni-Salphen,
- two-dimension
1. [1]
  Song Y P, Sun Q, Aguila B, Aguila B, Ma S Q. Covalent organic frameworks: Opportunities of covalent organic frameworks for advanced applications[J]. Adv. Sci., 2019,6(2)1970011. doi: 10.1002/advs.201970011
2. [2]
  Alahakoon S B, Diwakara S D, Thompson C M, Smaldone R A. Supra-molecular design in 2D covalent organic frameworks[J]. Chem. Soc. Rev., 2020,49:1344-1356. doi: 10.1039/C9CS00884E
3. [3]
  Li B J, Wang Z T, Gao Z Z, Suo J Q, Xue M, Yan Y S, Valtchev V, Qiu S L, Fang Q R. Self-standing covalent organic framework membranes for H₂/CO₂ separation[J]. Adv. Funct. Mater., 2023,33(16)2300219. doi: 10.1002/adfm.202300219
4. [4]
  Zheng L, Song Q, Tan P, Wang S T, Liu X Q, Sun L B. Endowing covalent organic frameworks with photoresponsive active sites for controllable propylene adsorption[J]. Small, 2023,19(15)2207291. doi: 10.1002/smll.202207291
5. [5]
  Chen B H, Xie H L, Shen L G, Xu Y C, Zhang M J, Zhou M Z, Li B S, Li R J, Lin H J. Covalent organic frameworks: The rising-star platforms for the design of CO₂ separation membranes[J]. Small, 2023,192207313. doi: 10.1002/smll.202207313
6. [6]
  An S H, Li X W, Shang S S, Xu T, Yang S, Cui C X, Peng C J, Liu H L, Xu Q, Jiang Z, Hu J. One-dimensional covalent organic frameworks for the 2e^- oxygen reduction reaction[J]. Angew. Chem. Int. Ed., 2023,62(14)e202218742. doi: 10.1002/anie.202218742
7. [7]
  Li S X, Ma R, Xu S Q, Zheng T Y, Wang H P, Fu G G, Yang H Y, Hou Y, Liao Z Q, Wu B Z, Feng X L, Wu L Z, Li X B, Zhang T. Two-dimensional benzobisthiazole-vinylene-linked covalent organic frameworks outperform one-dimensional counterparts in photocatalysis[J]. ACS Catal., 2023,13(2):1089-1096. doi: 10.1021/acscatal.2c05023
8. [8]
  Zou W W, Jiang G X, Zhang W F, Zhang L H, Cui Z M, Song H Y, Liang Z X, Du L. Hierarchically macro-microporous covalent organic frameworks for efficient proton conduction[J]. Adv. Funct. Mater., 2023,33(18)2213642. doi: 10.1002/adfm.202213642
9. [9]
  Skorjanc T, Shetty D, Valant M. Covalent organic polymers and frameworks for fluorescence-based sensors[J]. ACS Sens., 2021,6(4):1461-1481. doi: 10.1021/acssensors.1c00183
10. [10]
  Chen S F, Liang L J, Li Y Y, Wang D Y, Lu J G, Zhan X L, Hou Y, Zhang Q H, Lu J. Brain capillary-inspired self-assembled covalent organic framework membrane for sodium-sulfur battery separator[J]. Energy Mater., 2023,13(11)2204334. doi: 10.1002/aenm.202204334
11. [11]
  Hu B, Xu J, Fan Z J, Xu C, Han S C, Zhang J X, Ma L B, Ding B, Zhuang Z C, Kang Q, Zhang X G. Covalent organic framework based lithium-sulfur batteries: materials, interfaces, and solid-state electrolytes[J]. Adv. Energy Mater., 2023,13(10)2203540. doi: 10.1002/aenm.202203540
12. [12]
  Dai Y Y, Liu C L, Bai Y, Kong Q Q, Pang H. Framework materials for supercapacitors[J]. Nanotechnol. Rev., 2022,11(1):1005-1046. doi: 10.1515/ntrev-2022-0042
13. [13]
  Yue Y, Li H Y, Chen H Z, Huang N. Piperazine-linked covalent organic frameworks with high electrical conductivity[J]. J. Am. Chem. Soc., 2022,144(7):2873-2878. doi: 10.1021/jacs.1c13012
14. [14]
  Li H, Chang J H, Li S S, Guan X Y, Li D H, Li C Y, Tang L X, Xue M, Yan Y S, Valtchev V, Qiu S L, Fang Q R. Three-dimensional tetrathiafulvalene-based covalent organic frameworks for tunable electrical conductivity[J]. J. Am. Chem. Soc., 2019,141(34):13324-13329. doi: 10.1021/jacs.9b06908
15. [15]
  Halder A, Ghosh M, Khayum M A, Bera S, Addicoat M, Sasmal H S, Karak S, Kurungot S, Banerjee R. Interlayer hydrogen-bonded covalent organic frameworks as high-performance supercapacitors[J]. J. Am. Chem. Soc., 2018,140(35):10941-10945. doi: 10.1021/jacs.8b06460
16. [16]
  Li M, Liu J J, Zhang T, Song X Y, Chen W H, Chen L. 2D redoxactive covalent organic frameworks for supercapacitors: Design, synthesis, and challenges[J]. Small, 2021,17(22)2005073. doi: 10.1002/smll.202005073
17. [17]
  El-Mahdy A F M, Mohamed M G, Mansoure T H, Yu H H, Chen T, Kuo S W. Ultrastable tetraphenyl-p-phenylenediamine-based covalent organic frameworks as platforms for high-performance electrochemical supercapacitors[J]. Chem. Commun., 2019,55:14890-14893. doi: 10.1039/C9CC08107K
18. [18]
  Pakulski D, Montes-García V, Gorczyński A, Czepa W, Chudziak T, Samorì P, Ciesielski A. Thiol-decorated covalent organic frameworks as multifunctional materials for high-performance supercapacitors and heterogeneous catalysis[J]. J. Mater. Chem. A, 2022,10:16685-16696. doi: 10.1039/D2TA03867F
19. [19]
  An N, Guo Z, Xin J, He Y Y, Xie K F, Sun D M, Dong X Y, Hu Z G. Hierarchical porous covalent organic framework/graphene aerogel electrode for high-performance supercapacitors[J]. J. Mater. Chem. A, 2021,9:16824-16833. doi: 10.1039/D1TA04313G
20. [20]
  Xu Z J, Liu Y N, Wu Z T, Wang R T, Wang Q F, Li T, Zhang J H, Cheng J, Yang Z H, Chen S F, Miao M H, Zhang D H. Construction of extensible and flexible supercapacitors from covalent organic framework composite membrane electrode[J]. Chem. Eng. J., 2020,387124071. doi: 10.1016/j.cej.2020.124071
21. [21]
  Karak S, Kandambeth S, Biswal B P, Sasmal H S, Kumar S, Pachfule P, Banerjee R. Constructing ultraporous covalent organic frameworks in seconds via an organic terracotta process[J]. J. Am. Chem. Soc., 2017,139:1856-1862. doi: 10.1021/jacs.6b08815
22. [22]
  Jin J, Zheng Y, Huang S Z, Sun P P, Srikanth N, Kong L B, Yan Q Y, Zhou K. Directly anchoring 2D NiCo metal-organic frameworks on few-layer black phosphorus for advanced lithium-ion batteries[J]. J. Mater. Chem. A, 2019,7:783-790. doi: 10.1039/C8TA09327J
23. [23]
  Cheng Y, Guo X W, Xue Y D, Pang H. Controllable synthesis of a flower-like superstructure of nickel metal-organic phosphate and its derivatives for supercapacitors[J]. Appl. Mater. Today, 2021,23101048. doi: 10.1016/j.apmt.2021.101048
24. [24]
  Zheng S S, Sun Y, Xue H G, Braunstein P, Pang H. Dual-ligand and hard-soft-acid-base strategies to optimize metal-organic framework nanocrystals for stable electrochemical cycling performance[J]. Natl. Sci. Rev., 2022,9(7)nwab197. doi: 10.1093/nsr/nwab197
25. [25]
  Laheäär A, Przygocki P, Abbas Q, Béguin F. Appropriate methods for evaluating the efficiency and capacitive behavior of different types of supercapacitors[J]. Electrochem. Commun., 2015,60:21-25. doi: 10.1016/j.elecom.2015.07.022
26. [26]
  Chandra S, Chowdhury D R, Addicoat M, Heine T, Paul A, Banerjee R. Molecular level control of the capacitance of two-dimensional covalent organic frameworks: Role of hydrogen bonding in energy storage materials[J]. Chem. Mater., 2017,29:2074-2080. doi: 10.1021/acs.chemmater.6b04178
27. [27]
  Khattak A M, Ghazi Z A, Liang B, Khan N A, Iqbal A, Li L S, Tang Z Y. A redox-active 2D covalent organic framework with pyridine moieties capable of faradaic energy storage[J]. J. Mater. Chem. A, 2016,4:16312-16317. doi: 10.1039/C6TA05784E
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