Citation: Jie LI, Jing SHI, Shuai XIAO, Ming-Hui ZHANG, Wei-Wei GE, Lin HUANG, Kai CHEN. Construction and solvent recognition of cucurbit[5]uril-alkali metal and alkali-earth metal supramolecular self-assembly induced by 2, 7-naphthalene disulfonic acid[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(9): 1711-1720. doi: 10.11862/CJIC.2023.122 shu

Construction and solvent recognition of cucurbit[5]uril-alkali metal and alkali-earth metal supramolecular self-assembly induced by 2, 7-naphthalene disulfonic acid

Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Nanjing University of Information Science & Technology, Nanjing 210044, China

Corresponding author: Lin HUANG, 002650@nuist.edu.cn Kai CHEN, kaichen85@nuist.edu.cn
Received Date: 7 March 2023
Revised Date: 15 May 2023

Figures(11)

By introducing 2, 7-naphthalene disulfonic acid (H₂NDA) as a structure-directed agent, four new Q[5]-based supramolecular self-assemblies, namely[K₂(H₂O)₄(Q[5])](2, 7-NDA)·4H₂O (1), [Rb₂(H₂O)₅(Q[5])](2, 7-NDA)· 3H₂O (2), [Mg(H₂O)₄(Q[5])](2, 7-NDA)·8H₂O (3), and[Ca(H₂O)₄(Q[5])](2, 7-NDA)·10H₂O (4), were prepared under hydrothermal conditions. Single crystal X-ray diffraction results show that the self-assemblies 1 and 2 have the same structure. The coordination of the Q[5] molecule with metal ions forms a "molecular capsule" structure in 1 and 2, while the coordination of Q[5] and Mg²⁺ in 3 forms a 1:1 simple complex structure. In 4, Q[5] and Ca²⁺ can directly coordinate to form a 1D Q[5]-Ca²⁺coordination polymer chain structure. The 2, 7-NDA^2- anions in these structures balance the system charge, and through their outer-surface interactions with Q[5], promote its final construction into a 3D supramolecular structure. In addition, we also studied the fluorescence sensing properties of self-assembly 4, which could be used as quenching fluorescence probes for the organic solvents acetone and DMF.
- cucurbit[5]uril,
- outer-surface interactions,
- supramolecular assembly,
- fluorescence probe,
- solvent recognition
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