Citation: Xiao-Qin CUI, Dian-Hui WANG, Xin LI, Yu-Xin WANG, Ting LI, Jing DOND, Huan LI. Competitive coordination in 2-nitro benzoate protected one-dimensional Co(Ⅱ)/Zn(Ⅱ) complexes[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(8): 1579-1586. doi: 10.11862/CJIC.2023.121 shu

Competitive coordination in 2-nitro benzoate protected one-dimensional Co(Ⅱ)/Zn(Ⅱ) complexes

Institute of Crystalline Materials, Shanxi University, Taiyuan 030006, China

Corresponding author: Xiao-Qin CUI, 202012801003@email.sxu.edu.cn Huan LI, 59584340@sxu.edu.cn
Received Date: 17 February 2023
Revised Date: 9 May 2023

Figures(5)

Using tris(acetylacetonato)cobalt(Ⅲ) (Co(acac)₃) and zinc(Ⅱ) acetylacetonate (Zn(acac)₂) as precursors and 2-nitrobenzoic acid (2-nbaH) as ligand, three 1D complexes [Co(H₂O)(2-nba)₂]_n (Co-1), [Co₃(2-nba)₄(acac)₂]_n (Co-2), and [Zn₂(2-nba)₄]_n (Zn-3) were obtained by solvothermal reaction in toluene. The complexes were characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, and UV-Vis diffuse reflectance spectroscopy. In complex Co-1, each Co²⁺ ion is coordinated by two bridged water molecules and four 2-nba^- ions to form an octahedron geometry. When 2-nba^- was not sufficient, the acac^- ligands from the precursor were involved in the bonding with Co²⁺, leading to another 1D complex Co-2 with a different local structure. Most prominent is that two-thirds of the Co²⁺ ions in Co-2 are pentagonal triangular-dipyramid, while the other one-third is similar to that of Co-1. The synthetic method for Co was also successfully applied to Zn(acac)₂ to give a 1D zigzag-shaped Zn-3. In complex Zn-3, the Zn²⁺ ions exhibited the {ZnO₄} tetrahedral geometry protected only by 2-nba^- ions. The results show that the competitive coordination between 2-nba^- and acac^- can significantly affect the coordination environment of Co²⁺ ions.
- one-dimensional complex,
- competitive coordination,
- 2-nitrobenzoic acid,
- cobalt,
- zinc
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