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Citation: Hua-Li CUI, Xin-Yue XU, Wen LIU, Xiao-Li CHEN, Hua YANG, Lin LIU, Ji-Jiang WANG. Multifunctional Zn(Ⅱ) metal-organic framework fluorescent sensor to detect C6H5CHO, tetracycline, 2, 4, 6-trinitrophenol, fluazinam, Cr2O72- and Fe3+[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(7): 1389-1406. doi: 10.11862/CJIC.2023.109 shu

Multifunctional Zn(Ⅱ) metal-organic framework fluorescent sensor to detect C6H5CHO, tetracycline, 2, 4, 6-trinitrophenol, fluazinam, Cr2O72- and Fe3+

  • School of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Laboratory of New Energy & New Function Materials, Yan′an University, Yan′an, Shaanxi 716000, China

  • Corresponding author: Hua-Li CUI, cuihuali07@163.com
  • Received Date: 16 November 2022
    Revised Date: 22 May 2023

Figures(18)

  • A novel Zn(Ⅱ) metal-organic framework (MOF) [Zn2(Hdepa)(dya)2]n (1) (H5depa=2, 2′, 3, 4′, 5-diphenyl ether pentacarboxylic, dya=2, 2′-dipyridyl amine) was successfully prepared. Single-crystal X-ray diffraction analysis indicates that MOF 1 is composed of two Zn2+ ions joining one Hdepa4- ion and two dya molecules, forming a 3D framework through hydrogen bonding. The phase purity of the MOF 1 was demonstrated by powder X-ray diffraction and IR. Interestingly, 1 has excellent fluorescence properties and thermal stability. Notably, due to its excellent fluorescence performance, the high sensitivity and selectivity of 1 enable it to be used as a fluorescence sensor to detect C6H5CHO (BZH), tetracycline (TC), 2, 4, 6-trinitrophenol (TNP), fluazinam (Flu), Cr2O72-, and Fe3+. In addition, the quenching process of Fe3+, TC, and BZH to MOF 1 was analyzed by fluorescence lifetime, and the fluorescence quenching mechanism of Fe3+, Cr2O72-, TNP, TC, BZH, and Flu was studied by energy transfer.
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