Citation: Miao CAI, Zhu-Yun WANG, Xiao-Li CHEN, Lu LIU, Rui-Kui YAN, Hua-Li CUI, Hua YANG, Ji-Jiang WANG. Synthesis, structure, and fluorescence sensing properties of zinc coordination polymer based on 4-(2, 4-dicarboxylic phenoxyl) phthalic acid ligand[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(7): 1379-1388. doi: 10.11862/CJIC.2023.101 shu

Synthesis, structure, and fluorescence sensing properties of zinc coordination polymer based on 4-(2, 4-dicarboxylic phenoxyl) phthalic acid ligand

Miao CAI ¹ ,
Zhu-Yun WANG ² ,
Xiao-Li CHEN ^1,, ,
Lu LIU ¹ ,
Rui-Kui YAN ¹ ,
Hua-Li CUI ¹ ,
Hua YANG ¹ ,
Ji-Jiang WANG ¹

1.
School of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Laboratory of New Energy & New Function Materials, Yan′an University, Yan′an, Shaanxi 716000, China
2.
Hybrid Rapeseed Research Center of Shaanxi Province, Yangling, Shaanxi 712100, China

Corresponding author: Xiao-Li CHEN, chenxiaoli003@163.com
Received Date: 29 November 2022
Revised Date: 28 March 2023

Figures(6)

A zinc coordination polymer (Zn-CP) based on H₄dpa and bpy ligands (H₄dpa=4-(2, 4-dicarboxylic phenoxyl) phthalic acid, bpy=4, 4′-dipyridine), namely [Zn(H₂dpa)(bpy)_1.5]_n (1), has been hydrothermal synthesized and structurally characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction analysis. 1 shows 1D double chain based on Zn²⁺ ion, H₂dpa^2- and bpy ligand. The adjacent 1D double chains further expand into a 3D supramolecular network through hydrogen bonding. Fluorescence studies show that 1 is a fluorescence sensor with high sensitivity, good selectivity, and multiple responses, which can be used for the detection of pesticides and nitro explosives. Interestingly, 2, 4, 6-trinitrobenzene (TNP), and pyrimethanil (Pth) had an obvious quenching effect on the fluorescence emission of 1, while imazalil (Ima) had an enhancement effect on the fluorescence of 1. In addition, the fluorescence mechanism was investigated by means of UV-Vis absorption spectrum, fluorescence lifetime, and X-ray photoelectron spectroscopy.
- 4-(2, 4-dicarboxylic phenoxyl) phthalic acid,
- crystal structure,
- fluorescence sensing
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