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Citation: Li-Xin SU, Xian-Mei WANG, Qing-Yan JIANG, Hui-Min ZHANG, Yi-Wen LU, Qi LIU. A two-dimensional Co-based coordination polymer [KCo(pa)(OH)]n as the electrode material of supercapacitors with higher-capacity[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(8): 1481-1488. doi: 10.11862/CJIC.2023.099 shu

A two-dimensional Co-based coordination polymer [KCo(pa)(OH)]n as the electrode material of supercapacitors with higher-capacity

  • Jiangsu Province Key Laboratory of Fine Petrochemical Engineering, School of Petrochemical Engineering, Changzhou University, Changzhou, Jiangsu 213164, China

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  • A two-dimensional cobalt-based coordination polymer ([KCo(pa)(OH)]n, Co-pa, H2pa=phthalic acid) was synthesized by a simple solvothermal reaction of Co(Ac)2·4H2O and phthalic acid, and characterized by FT-IR spectrum, thermogravimetric analysis, powder X-ray diffraction, X-ray photoelectron spectrum, scanning electron microscope, and N2 adsorption-desorption isotherm. When Co-pa was used as the electrode material for supercapacitors, the Co-pa electrode presented a higher specific capacitance, better rate performance, and cycle stability. At the current densities of 1 and 10 A·g-1, the specific capacitances were 910 and 400 F·g-1, respectively. After 2 000 cycles at 2 A·g-1, the capacitance retention remains 81%. The better pseudo-capacitance performance is attributed to Co-pa nanorods with small size, Co(Ⅱ) ions included in Co-pa, phthalate anions, and their layered structure.
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