Citation: Li-Hua HU, Xiao WANG, Kai-Ran HU, Chen CHEN, Zhi-Hao XU, Wei XU. Direct synthesis of dimethyl carbonate from CO₂ and methanol over ZIF-67/CeO₂[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(7): 1315-1324. doi: 10.11862/CJIC.2023.091 shu

Direct synthesis of dimethyl carbonate from CO₂ and methanol over ZIF-67/CeO₂

Li-Hua HU ^{1, 2,,} ,
Xiao WANG ¹ ,
Kai-Ran HU ¹ ,
Chen CHEN ¹ ,
Zhi-Hao XU ¹ ,
Wei XU ^{1, 3,,}

1.
School of Environmental Engineering, Nanjing Institute of Technology, Nanjing 211167, China
2.
Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University, Nanning 530004, China
3.
Energy Research Institute, Nanjing Institute of Technology, Nanjing 211167, China

Corresponding author: Li-Hua HU, hulihua@njit.edu.cn Wei XU, xuwei@njit.edu.cn
Received Date: 24 October 2022
Revised Date: 8 May 2023

Figures(7)

An efficient heterogeneous catalyst ZIF-67/CeO₂ composites were synthesized by a precipitation method, and developed for the direct synthesis of dimethyl carbonate (DMC) from CO₂ and methanol. The physicochemical properties of the ZIF-67/CeO₂ catalysts were investigated by X-ray diffraction, N₂ adsorption - desorption, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. The results demonstrated that the introduction of ZIF-67 causes more oxygen vacancies to be generated onto CeO₂. Among the ZIF-67/CeO₂ catalysts, 0.3-ZIF-67/CeO₂ (0.3 was the molar ratio of Co and Ce) showed the best catalytic performance due to its high specific surface area, mesoporous structure, and high CO₂ adsorption capacity. Yield of 3.79 mmol_DMC·g_cat-1 was achieved at a temperature of 140 ℃ and a pressure of 4.5 MPa for 4 h.
- CeO₂,
- ZIFs,
- CO₂,
- dimethyl carbonate,
- heterogeneous catalyst
1. [1]
  Zhang M, Xu Y H, Williams B L, Xiao M, Wang S J, Han D M, Sun L Y, Meng Y Z. Catalytic materials for direct synthesis of dimethyl carbonate (DMC) from CO₂[J]. J. Cleaner Prod., 2021,279123344. doi: 10.1016/j.jclepro.2020.123344
2. [2]
  Kumar P, Srivastava V C, Štangar U L, Mušič B, Mishra I M, Meng Y. Recent progress in dimethyl carbonate synthesis using different feedstock and techniques in the presence of heterogeneous catalysts[J]. Catal. Rev., 2019,63(3):363-421.
3. [3]
  ZHANG J Y. Study on synthesis of dimethyl carbonate from carbon dioxide and methanol over cerium based catalysts. Tianjin: Tianjin University, 2020: 1-3
4. [4]
  Esan A O, Adeyemi A D, Ganesan S. A review on the recent application of dimethyl carbonate in sustainable biodiesel production[J]. J. Cleaner Prod., 2020,257120561. doi: 10.1016/j.jclepro.2020.120561
5. [5]
  Medrano-García J D, Javaloyes-Antón J, Vázquez D, Ruiz-Femenia R, Caballero J A. Alternative carbon dioxide utilization in dimethyl carbonate synthesis and comparison with current technologies[J]. J. CO2 Util., 2021,45101436. doi: 10.1016/j.jcou.2021.101436
6. [6]
  Tamboli A H, Chaugule A A, Kim H. Catalytic developments in the direct dimethyl carbonate synthesis from carbon dioxide and methanol[J]. Chem. Eng. J., 2017,323:530-544. doi: 10.1016/j.cej.2017.04.112
7. [7]
  Li H G, Zhang G Q, Wang Y, Zhang S J. Transesterification of ethylene carbonate with methanol over Zn-La mixed oxide catalysts[J]. J. Fuel Chem. Technol., 2018,46(8):977-984. doi: 10.1016/S1872-5813(18)30041-0
8. [8]
  Lee K M, Jang J H, Balamurugan M, Kim J E, Jo Y I, Nam K T. Redoxneutral electrochemical conversion of CO₂ to dimethyl carbonate[J]. Nat. Energy, 2021,6(7):733-741. doi: 10.1038/s41560-021-00862-1
9. [9]
  Kabra S K, Turpeinen E, Keiski R L, Yadav G D. Direct synthesis of dimethyl carbonate from methanol and carbon dioxide: A thermodynamic and experimental study[J]. J. Supercrit. Fluids, 2016,117:98-107. doi: 10.1016/j.supflu.2016.05.039
10. [10]
  Marin C M, Li L, Bhalkikar A, Doyle J E, Zeng X C, Cheung C L. Kinetic and mechanistic investigations of the direct synthesis of dimethyl carbonate from carbon dioxide over ceria nanorod catalysts[J]. J. Catal., 2016,340:295-301. doi: 10.1016/j.jcat.2016.06.003
11. [11]
  Shi D C, Heyte S, Capron M, Paul S. Catalytic processes for the direct synthesis of dimethyl carbonate from CO₂ and methanol: A review[J]. Green Chem., 2022,24(3):1067-1089. doi: 10.1039/D1GC04093F
12. [12]
  Zhao T X, Hu X B, Wu D S, Li R, Yang G Q, Wu Y T. Direct synthesis of dimethyl carbonate from carbon dioxide and methanol at room temperature using imidazolium hydrogen carbonate ionic liquid as a recyclable catalyst and dehydrant[J]. ChemSusChem, 2017,10(9):2046-2052. doi: 10.1002/cssc.201700128
13. [13]
  Lu B, Wang X, Li Y, Sun J, Zhao J X, Cai Q H. Electrochemical conversion of CO₂ into dimethyl carbonate in a functionalized ionic liquid[J]. J. CO2 Util., 2013,3-4:98-101. doi: 10.1016/j.jcou.2013.10.001
14. [14]
  Sun J, Lu B, Wang X, Li X, Zhao J X, Cai Q H. A functionalized basic ionic liquid for synthesis of dimethyl carbonate from methanol and CO₂[J]. Fuel Process. Technol., 2013,115:233-237. doi: 10.1016/j.fuproc.2013.06.009
15. [15]
  Choi J C, He L N, Yasuda H, Sakakura T. Selective and high yield synthesis of dimethyl carbonate directly from carbon dioxide and methanol[J]. Green Chem., 2002,4(3):230-234. doi: 10.1039/b200623p
16. [16]
  Truong C C, Mishra D K. Recent advances in the catalytic fixation of carbon dioxide to value - added chemicals over alkali metal salts[J]. J. CO2 Util., 2020,41101252. doi: 10.1016/j.jcou.2020.101252
17. [17]
  Akune T, Morita Y, Shirakawa S, Katagiri K, Inumaru K. ZrO₂ nanocrystals as catalyst for synthesis of dimethyl carbonate from methanol and carbon dioxide: Catalytic activity and elucidation of active sites[J]. Langmuir, 2018,34(1):23-29. doi: 10.1021/acs.langmuir.7b01294
18. [18]
  Xu S Y, Cao Y X, Liu Z M. Dimethyl carbonate synthesis from CO₂ and methanol over CeO₂ -ZrO₂ catalyst[J]. Catal. Commun., 2022,162106397. doi: 10.1016/j.catcom.2022.106397
19. [19]
  WANG X H, ZHAO J X, PEI Y L, REN J. Research progress in dimethyl carbonate synthesis from carbon dioxide and methanol catalyzed by metal oxides[J]. Chemical Industry and Engineering Progress, 2019,38(11):4956-4964.
20. [20]
  Aouissi A, Al-Othman Z A, Al-Amro A. Gas-phase synthesis of dimethyl carbonate from methanol and carbon dioxide over Co_1.5PW₁₂O₄₀ Keggin-type heteropolyanion[J]. Int. J. Mol. Sci., 2010,11(4):1343-1351. doi: 10.3390/ijms11041343
21. [21]
  Xuan K, Pu Y F, Li F, Li A X, Luo J, Li L, Wang F, Zhao N, Xiao F K. Direct synthesis of dimethyl carbonate from CO₂ and methanol over trifluoroacetic acid modulated UiO-66[J]. J. CO2 Util., 2018,27:272-282. doi: 10.1016/j.jcou.2018.08.002
22. [22]
  Xuan K, Pu Y F, Li F, Luo J, Zhao N, Xiao F K. Metal-organic frameworks MOF-808-X as highly efficient catalysts for direct synthesis of dimethyl carbonate from CO₂ and methanol[J]. Chin. J. Catal., 2019,40(4):553-566. doi: 10.1016/S1872-2067(19)63291-2
23. [23]
  Xuan K, Chen S K, Pu Y F, Guo Y P, Guo Y D, Li Y, Pu C X, Zhao N, Xiao F K. Encapsulating phosphotungstic acid within metalorganic framework for direct synthesis of dimethyl carbonate from CO₂ and methanol[J]. J. CO₂ Util., 2022,59101960. doi: 10.1016/j.jcou.2022.101960
24. [24]
  Chen Y D, Yang Y, Tian S L, Ye Z B, Tang Q, Ye L, Li G. Highly effective synthesis of dimethyl carbonate over CuNi alloy nanoparticles@porous organic polymers composite[J]. Appl. Catal. A-Gen., 2019,587117275. doi: 10.1016/j.apcata.2019.117275
25. [25]
  Prymak I, Prymak O, Wang J, Kalevaru V N, Martin A, Bentrup U, Wohlrab S. Phosphate functionalization of CeO₂-ZrO₂ solid solutions for the catalytic formation of dimethyl carbonate from methanol and carbon dioxide[J]. ChemCatChem, 2018,10(2):391-394. doi: 10.1002/cctc.201701105
26. [26]
  Faria D J, dos Santos L M, Bernard F L, Pinto I S, Romero I P, Chaban V V, Einloft S. Performance of supported metal catalysts in the dimethyl carbonate production by direct synthesis using CO₂ and methanol[J]. J. CO₂ Util., 2021,53101721. doi: 10.1016/j.jcou.2021.101721
27. [27]
  Chang K, Zhang H C, Cheng M J, Lu Q. Application of ceria in CO₂ conversion catalysis[J]. ACS Catal., 2019,10(1):613-631.
28. [28]
  Jiang J, Marin C M, Both A K, Cheung C L, Li L, Zeng X C. Formation of dimethyl carbonate via direct esterification of CO₂ with methanol on reduced or stoichiometric CeO₂(111) and (110) surfaces[J]. Phys. Chem. Chem. Phys., 2021,23(30):16150-16156. doi: 10.1039/D1CP02152D
29. [29]
  Zhang J Y, Huang S Y, Zhao Y J, Ma X N, Wang S P. CeO₂ hollow nanosphere for catalytic synthesis of dimethyl carbonate from CO₂ and methanol: The effect of cavity effect on catalytic performance[J]. Asia-Pac. J. Chem. Eng., 2020,16(1)e2554.
30. [30]
  Tamboli A H, Chaugule A A, Gosavi S W, Kim H. CeZr_1-xO₂ solid solutions for catalytic synthesis of dimethyl carbonate from CO₂: Reaction mechanism and the effect of catalyst morphology on catalytic activity[J]. Fuel, 2018,216:245-254. doi: 10.1016/j.fuel.2017.12.008
31. [31]
  Wang S P, Zhao L F, Wang W, Zhao Y J, Zhang G L, Ma X B, Gong J L. Morphology control of ceria nanocrystals for catalytic conversion of CO₂ with methanol[J]. Nanoscale, 2013,5(12):5582-5588. doi: 10.1039/c3nr00831b
32. [32]
  Fu Z W, Zhong Y Y, Yu Y H, Long L Z, Xiao M, Han D M, Wang S J, Meng Y Z. TiO₂-doped CeO₂ nanorod catalyst for direct conversion of CO₂ and CH₃OH to dimethyl carbonate: Catalytic performance and kinetic study[J]. ACS Omega, 2018,3(1):198-207. doi: 10.1021/acsomega.7b01475
33. [33]
  Liu B, Li C M, Zhang G Q, Yao X S, Chuang S S C, Li Z. Oxygen vacancy promoting dimethyl carbonate synthesis from CO₂ and methanol over Zr-doped CeO₂ nanorods[J]. ACS Catal., 2018,8(11):10446-10456. doi: 10.1021/acscatal.8b00415
34. [34]
  Liu B, Li C M, Zhang G Q, Yan L F, Li Z. Direct synthesis of dimethyl carbonate from CO₂ and methanol over CaO-CeO₂ catalysts: The role of acid - base properties and surface oxygen vacancies[J]. New J. Chem., 2017,41(20):12231-12240. doi: 10.1039/C7NJ02606D
35. [35]
  YAN Y Y, LI Y, DENG J, ZHAO X, TA N, CHEN Y D. Direct synthesis of dimethyl carbonate from CO₂ and methanol by Mg - doped ceria monolithic catalyst[J]. Chinese J. Inorg. Chem., 2022,38(7):1402-1410.
36. [36]
  SUN Y C. Study on the reaction and mechanism of CO2 synthesis of dimethyl carbonate with lattice oxygen and oxygen vacancies on the surface of cerium ⁃ based catalyst. Taiyuan: Taiyuan University of Technology, 2020: 54-65
37. [37]
  ZHANG G Q, SUN Y C, SHI Y B, ZHENG H Y, LI Z, SHANGGUAN J, LIU S J, SHI P Z. Surface properties of Ce_1-x Mn_xO₂ catalyst on the catalytic activities for direct synthesis of DMC from CO₂ and methanol[J]. Chem. J. Chinese Universities, 2020,41(9):2061-2069.
38. [38]
  Marciniak A A, Alves O C, Appel L G, Mota C J A. Synthesis of dimethyl carbonate from CO₂ and methanol over CeO₂: Role of copper as dopant and the use of methyl trichloroacetate as dehydrating agent[J]. J. Catal., 2019,371:88-95. doi: 10.1016/j.jcat.2019.01.035
39. [39]
  Kuan W F, Yu W Y, Tu F Y, Chung C H, Chang Y C, Lin M M, Yu T H, Chen L J. Facile reflux preparation of defective mesoporous ceria nanorod with superior catalytic activity for direct carbon dioxide conversion into dimethyl carbonate[J]. Chem. Eng. J., 2022,430132941. doi: 10.1016/j.cej.2021.132941
40. [40]
  Cravillon J, Munzer S, Lohmeier S J, Feldhoff A, Huber K, Wiebcke M. Rapid room - temperature synthesis and characterization of nanocrystals of a prototypical zeolitic imidazolate framework[J]. Chem. Mater., 2009,21(8):1410-1412. doi: 10.1021/cm900166h
41. [41]
  SHI Y B, ZHANG G Q, SUN Y C, ZHENG H Y, LI Z, SHANGGUAN J, MI J, LIU S J, SHI P Z. KIT-6 supported CeO₂ for catalytic synthesis of dimethyl carbonate from CO₂ and methanol[J]. Chinese J. Inorg. Chem., 2021,37(6):1004-1016.
42. [42]
  Zhu M Q, Venna S R, Jasinski J B, Carreon M A. Room-temperature synthesis of ZIF-8: The coexistence of ZnO nanoneedles[J]. Chem. Mater., 2011,23(16):3590-3592. doi: 10.1021/cm201701f
43. [43]
  Hu Y, Kazemian H, Rohani S, Huang Y H, Song Y. In situ high pressure study of ZIF-8 by FTIR spectroscopy[J]. Chem. Commun., 2011,47(47):12694-12696. doi: 10.1039/c1cc15525c
44. [44]
  Tuan D D, Lin K Y A. Ruthenium supported on ZIF - 67 as an enhanced catalyst for hydrogen generation from hydrolysis of sodium borohydride[J]. Chem. Eng. J., 2018,351:48-55. doi: 10.1016/j.cej.2018.06.082
45. [45]
  Zhao S Z, Kang D J, Liu Y P, Wen Y F, Xie X Z, Yi H H, Tang X L. Spontaneous formation of asymmetric oxygen vacancies in transitionmetal-doped CeO₂ nanorods with improved activity for carbonyl sulfide hydrolysis[J]. ACS Catal., 2020,10(20):11739-11750. doi: 10.1021/acscatal.0c02832
46. [46]
  Hahn K R, Iannuzzi M, Seitsonen A P, Hutter J. Coverage effect of the CO₂ adsorption mechanisms on CeO₂(111) by first principles analysis[J]. J. Phys. Chem. C, 2013,117(4):1701-1711. doi: 10.1021/jp309565u
47. [47]
  Zhao S Y, Wang S P, Zhao Y J, Ma X B. An in situ infrared study of dimethyl carbonate synthesis from carbon dioxide and methanol over well-shaped CeO₂[J]. Chin. Chem. Lett., 2017,28(1):65-69. doi: 10.1016/j.cclet.2016.06.003
48. [48]
  Chizallet C, Lazare S, Bazer-Bachi D, Bonnier F, Lecocq V, Soyer E, Quoineaud A A, Bats N. Catalysis of transesterification by a nonfunctionalized metal - organic framework: Acido - basicity at the external surface of ZIF - 8 probed by FTIR and ab initio calculations[J]. J. Am. Chem. Soc., 2010,132:2365-12377.
49. [49]
  Liu H, Zou W J, Xu X L, Zhang X L, Yang Y Q, Yue H J, Yu Y, Tian G, Feng S H. The proportion of Ce4+ in surface of CexZr_1-x O₂ catalysts: The key parameter for direct carboxylation of methanol to dimethyl carbonate[J]. J. CO2 Util., 2017,17:43-49. doi: 10.1016/j.jcou.2016.11.006
50. [50]
  Zheng Q X, Nishimura R, Sato Y, Inomata H, Ota M, Watanabe M, Camy S. Dimethyl carbonate (DMC) synthesis from methanol and carbon dioxide in the presence of ZrO₂ solid solutions and yield improvement by applying a natural convection circulation system[J]. Chem. Eng. J., 2022,429132378. doi: 10.1016/j.cej.2021.132378
51. [51]
  Cai Q H, Lu B, Guo L J, Shan Y K. Studies on synthesis of dimethyl carbonate from methanol and carbon dioxide[J]. Catal. Commun., 2009,10(5):605-609. doi: 10.1016/j.catcom.2008.11.002
52. [52]
  Stoian D, Medina F, Urakawa A. Improving the stability of CeO₂ catalyst by rare earth metal promotion and molecular insights in the dimethyl carbonate synthesis from CO₂ and methanol with 2-cyanopyridine[J]. ACS Catal., 2018,8(4):3181-3193. doi: 10.1021/acscatal.7b04198
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Direct synthesis of dimethyl carbonate from CO2 and methanol over ZIF-67/CeO2

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Direct synthesis of dimethyl carbonate from CO₂ and methanol over ZIF-67/CeO₂