Citation: Hai-Feng YU, Ting FENG, Shao-Juan CHENG, Ya-Hui GAO, Qi XIAO, Fang WANG. Nitrogen-rich doped carbon hollow nanocage structure cooperating with cobalt-nickel sulfide to improve the performance of supercapacitors[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(8): 1597-1609. doi: 10.11862/CJIC.2023.088 shu

Nitrogen-rich doped carbon hollow nanocage structure cooperating with cobalt-nickel sulfide to improve the performance of supercapacitors

Hai-Feng YU ¹ ,
Ting FENG ² ,
Shao-Juan CHENG ^1,, ,
Ya-Hui GAO ¹ ,
Qi XIAO ¹ ,
Fang WANG ^1,,

1.
College of Chemistry and Chemistry, Luoyang Institute of Technology, Luoyang, Henan 471023, China
2.
College of Materials Science and Engineering, Henan University of Science and Technology, Luoyang, Henan 471000, China

Corresponding author: Shao-Juan CHENG, chengshaojuan2004@126.com Fang WANG, wangfang1116@163.com
Received Date: 15 January 2023
Revised Date: 11 April 2023

Figures(9)

A novel nitrogen-rich doped carbon hollow nanocage (NC) supported binary metal sulfide nanoparticle (CoNi_xS_y) composite CoNi_xS_y/NC was successfully prepared by a simple pyrolysis-vulcanization two-step method. In this strategy, dimethylglyoxime nickel was used as the nickel source to increase the active site, and the core-shell structure of the precursor ZIF-8@Ni-ZIF-67 provided the possibility for the construction of hollow carbon nanocages. More importantly, this unique hollow structure loaded with binary metal sulfide nanoparticles made the CoNi_xS_y/NC possess more active sites, high conductivity, and structural stability when used as an electrode material, thereby providing a higher specific capacity (629.2 F·g^-1 at 1 A·g^-1) and excellent cycle stability (93.4% capacity retention after 1 000 cycles at 1 A·g^-1). When further assembled into a symmetrical supercapacitor, a specific capacitance of 207.2 F·g^-1 can be provided at 1 A·g^-1, and the retention rate was 85.36% after 1 000 cycles of stabilization.
- transition metal sulfide,
- metal-organic framework,
- hollow nanocage,
- supercapacitors
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