Citation: Nian WANG, Meng LI, Ying JI, Ming-Wu XIANG, Yu-Jiao GUO, Hong-Li BAI, Xiao-Fang LIU, Jun-Ming GUO. Synthesis and electrochemical properties of truncated octahedral LiZn_0.08Al_0.01Mn_1.91O₄ cathode material by solid-state combustion method[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(6): 1042-1052. doi: 10.11862/CJIC.2023.085 shu

Synthesis and electrochemical properties of truncated octahedral LiZn_0.08Al_0.01Mn_1.91O₄ cathode material by solid-state combustion method

Nian WANG ¹ ,
Meng LI ¹ ,
Ying JI ¹ ,
Ming-Wu XIANG ¹ ,
Yu-Jiao GUO ^{1, 2,,} ,
Hong-Li BAI ¹ ,
Xiao-Fang LIU ¹ ,
Jun-Ming GUO ^1,,

1.
Key Laboratory of Green-Chemistry Materials in University of Yunnan Province, School of Chemistry and Environment, Yunnan Minzu University, Kunming 650500, China
2.
Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China

Corresponding author: Yu-Jiao GUO, guoyujiao1988@163.com Jun-Ming GUO, guojunming@tsinghua.org.cn
Received Date: 25 December 2022
Revised Date: 9 May 2023

Figures(9)

A single-crystal truncated octahedral morphology LiZn_0.08Al_0.01Mn_1.91O₄ cathode material with {111}, {110}, and {100} crystal surfaces was synthesized by a solid-state combustion method. The results show that Zn-Al co-doped promotes the crystal development and the selective growth of crystal surfaces of spinel LiMn₂O₄ materials, while forming single-crystal truncated octahedral grain. The Zn-Al co-doped sample effectively inhibits the JahnTeller effect and reduces Mn dissolution, thus enhancing the crystal structure stability and significantly improving the electrochemical performance. The initial discharge specific capacity of LiZn_0.08Al_0.01Mn_1.91O₄ were 92.6 and 76.5 mAh·g^-1 at 5C and 10C, the corresponding capacity retention remained 70.4% and 74.8% after 2 000 cycles, respectively. Even at a high current density of 15C, the initial discharge capacity was still 64.2 mAh·g^-1, and the capacity retention can reach 82.2% after 800th cycles. Compared with LiZn_0.08Mn_1.92O₄, the LiZn_0.08Al_0.01Mn_1.91O₄ cathode material had a larger Li⁺ diffusion coefficient (1.02×10^-11 cm²·s^-1) and smaller apparent activation energy (25.60kJ mol^-1). The results show that the Zn-Al co-doped and monocrystalline morphology control strategy can reduce the energy barrier of Li⁺ during the de-intercalation process and increase the diffusion rate in electrode materials.
- LiMn₂O₄,
- Zn-Al co-doping,
- cathode material,
- Jahn-Teller effect,
- Mn dissolution,
- truncated octahedron,
- solid-state combustion method
1. [1]
  LIU Q, GUO J M, LIU X F, BAI H L, XIANG M W, BAI W, DUAN K J. Preparation and long cycle electrochemical properties of B-doped spinel LiMn₂O₄ cathode material[J]. Chinese J. Inorg. Chem., 2021,37(2):276-284.
2. [2]
  LIU P S, SONG L J, HUANG C L, HU L, LU X Y, JIANG Q. Effects of manganese sources on the high temperature performance of spinel LiMn₂O₄[J]. Chinese J. Inorg. Chem., 2023,39(1):55-62.
3. [3]
  JI Y, LI M, GUO Y J, GUO J M, XIANG M W, LIU X F. Preparation of two types of truncated octahedral LiMn₂O₄ materials induced by Ni-Cu doping and their electrochemical properties[J]. Transactions of Materials and Heat Treatment, 2023,44(3):28-40.
4. [4]
  Abdollahifar M, Lannelongue P, Liu H W, Chen H, Sheu H S, Lee J F, Liao Y F, Wu N L. Room-temperature synthesis of LiMn₂O₄ by electrochemical ion exchange in an aqueous medium[J]. ACS Sustain. Chem. Eng., 2021,9(41):13717-13725. doi: 10.1021/acssuschemeng.1c03747
5. [5]
  Mao F X, Guo W, Ma J M. Research progress on design strageties, synthesis and performance of LiMn₂O₄-based cathodes[J]. RSC Adv., 2015,5(127):105248-105258. doi: 10.1039/C5RA21777F
6. [6]
  Nitta N, Wu F X, Lee J T, Yushin G. Li-ion battery materials: Present and future[J]. Mater. Today, 2015,18(5):252-264. doi: 10.1016/j.mattod.2014.10.040
7. [7]
  Zuo X X, Chang K, Zhao J, Xie Z Z, Tang H W, Li B, Chang Z R. Lithium-ion batteries: Outlook on present, future, and hybridized technologies[J]. J. Mater. Chem. A, 2016,4(1):51-58. doi: 10.1039/C5TA06869J
8. [8]
  Goncalves R, Sharma P, Ram P, Ferdov S, Silva M M, Costa C M, Singhal R, Sharma R K, Lanceros-Méndez S. Improved electrochemical performance of LiMn_1.5M_0.5O₄(M=Ni, Co, Cu) based cathodes for lithium-ion batteries[J]. J. Alloy. Compd., 2021,853157208. doi: 10.1016/j.jallcom.2020.157208
9. [9]
  Madhu M, Venkateswara Rao A, Mutyala S. La and Ni Co-doping effect in LiMn₂O₄ on structural and electrochemical properties for lithium-ion batteries[J]. J. Electron. Mater., 2021,50(9):5141-5149. doi: 10.1007/s11664-021-09037-w
10. [10]
  XIA B B, QIU G C, SUN H D, FANG G Q, LIU W W, ZHANG R X, WANG H Y, LI D C. Improved electrochemical properties of conducting AZO-coated spinel LiMn₂O₄ at 55℃[J]. Chinese J. Inorg. Chem., 2014,30(4):725-732.
11. [11]
  YANG M, CHEN Y F, LIU H L, XIANG M W, GUO Y J, LIU X F, GUO J M. Preparation and electrochemical properties of truncated octahedral LiFe_0.12Mn_1.88O₄ cathode materials[J]. J. Chin. Ceram Soc., 2022,50(7):1865-1874.
12. [12]
  Marincaş A H, Goga F, Dorneanu S A, Petru I. Review on synthesis methods to obtain LiMn₂O₄ based cathode materials for Li-ion batteries[J]. J. Solid State Electrochem., 2020,24(3):473-497. doi: 10.1007/s10008-019-04467-3
13. [13]
  Liang Q M, Wang Z L, Bai W, GUO J M, Xiang M W, Liu X F, Bai H L. Stimulative formation of truncated octahedral LiMn₂O₄ by Cr and Al co-doping for use in durable cycling Li-ion batteries[J]. Dalton Trans., 2021,50(46):17052-17061. doi: 10.1039/D1DT03221F
14. [14]
  Arumugam D, Kalaignan G P, Vediappan K, Lee C W. Synthesis and electrochemical characterizations of nano-scaled Zn doped LiMn₂O₄ cathode materials for rechargeable lithium batteries[J]. Electrochim. Acta, 2010,55(28):8439-8444. doi: 10.1016/j.electacta.2010.07.033
15. [15]
  Zhao H Y, Gao X Y, Li Y F, Ran Q W, Fu C G, Feng Y P, Liu J T, Liu X Q, Su J X. Synergistic effects of zinc-doping and nano-rod morphology on enhancing the electrochemical properties of spinel Li-Mn-O material[J]. Ceram. Int., 2019,45(14):17591-17597. doi: 10.1016/j.ceramint.2019.05.324
16. [16]
  Jiang J B, Liang L W, Li D, Xiao J, Peng Z D, Du K, Cao Y B, Hu G R, Jiang F. Synthesis of High-performance cycling LiNi_xMn_2-xO₄(x ≤ 0.10) as cathode material for lithium batteries[J]. J. Nanosci. Nanotechnol., 2017,17(12):9182-9185. doi: 10.1166/jnn.2017.13919
17. [17]
  Jiang J B, Li W, Deng H J, Gong G, Li N. Research on improving the electrochemical performance of LiMn₂O₄ via Cr-doping[J]. J. Nanosci. Nanotechnol., 2019,19(1):125-129. doi: 10.1166/jnn.2019.16386
18. [18]
  Yuan A B, Tian L, Xu W M, Wang Y Q. Al-doped spinel LiAl_0.1Mn_1.9O₄ with improved high-rate cyclability in aqueous electrolyte[J]. J. Power Sources, 2010,195(15):5032-5038. doi: 10.1016/j.jpowsour.2010.01.074
19. [19]
  Tao Y, Liu Q, Guo Y J, Xiang M W, Liu X F, Bai W, Guo J M, Chou S L. Regulation of morphology evolution and Mn dissolution for ultralong cycled spinel LiMn₂O₄ cathode materials by B-doping[J]. J. Power Sources, 2022,524231073. doi: 10.1016/j.jpowsour.2022.231073
20. [20]
  Lee J, Kang Y, Han S, Hwang C S, Choi J H. Ab initio study on the structural characteristics of amorphous Zn₂SnO₄[J]. Appl. Phys. Lett., 2013,103(25)252102. doi: 10.1063/1.4850895
21. [21]
  Li B Z, Xu W G, Qiu S L, Pang W Q, Xu R R. Simulated calculation of aluminophosphate molecular sieves structure and stability. 2. Bond lengths, bond angles and distribution of framework structure[J]. Chem. Res. Chin. Univ., 1997,18(7):1000-1006.
22. [22]
  Suzuki K, Oumi S, Takami S, Kubo M, Miyamoto A, Kikuchi M, Yamazaki N, Mita M. Structural properties of Li_xMn₂O₄ as investigated by molecular dynamics and density functional theory[J]. Jpn. J. Appl. Phys., 2000,39(7):4318-4322.
23. [23]
  Xu W Q, Li Q L, Guo J M, Bai H L, Su C W, Ruan R S, Peng J H. Electrochemical evaluation of LiZn_xMn₂O₄(x ≤ 0.10) cathode material synthesized by solution combustion method[J]. Ceram. Int., 2016,42(5):5693-5698. doi: 10.1016/j.ceramint.2015.12.098
24. [24]
  Cai Z F, Ma Y Z, Huang X N, Yan X H, Yu Z X, Zhang S H, Song G S, Xu Y L, Wen C E, Yang W D. High electrochemical stability Al-doped spinel LiMn₂O₄ cathode material for Li-ion batteries[J]. J. Energy Storage, 2020,27101036. doi: 10.1016/j.est.2019.101036
25. [25]
  Xu W Q, Zheng Y H, Cheng Y, Qi R J, Peng H, Lin H C, Huang R. Understanding the effect of Al doping on the electrochemical performance improvement of the LiMn₂O₄ cathode material[J]. ACS Appl. Mater. Interfaces, 2021,13(38):45446-45454. doi: 10.1021/acsami.1c11315
26. [26]
  LIANG L Q, GUO J M, YANG L Y, SU C W, DUAN K J, XIANG M W, BAI W. Synthesis of LiNi_0.10Zn_xMn_1.90-xO₄(x ≤ 0.15) cathode materials synthesized by solid state combustion and its electrochemical properties[J]. Journal of Yunnan University (Natural Sciences Edition), 2020,42(1):119-126.
27. [27]
  Tao Y, Lu Y, Guo Y J, Guo J M, Xiang M W, Bai W, Liu X F, Bai H L. Facile synthesis and electrochemical properties of truncated octahedral Al, Ni dual doped LiMn₂O₄ cathode materials[J]. J. Alloy. Compd., 2022,904164027. doi: 10.1016/j.jallcom.2022.164027
28. [28]
  Thirunakaran R, Kim T, Yoon W S. Zinc and aluminium: Glutamic acid assisted dual-doped LiMn₂O₄ spinels via sol-gel method as cathode material for use in lithium rechargeable batteries[J]. J. Sol-Gel Sci. Technol., 2015,73(1):62-71. doi: 10.1007/s10971-014-3495-1
29. [29]
  Kim J S, Kim K S, Cho W, Shin W H, Kanno R, Choi J W. A Truncated manganese spinel cathode for excellent power and lifetime in lithium-ion batteries[J]. Nano Lett., 2012,12:6358-6365. doi: 10.1021/nl303619s
30. [30]
  Jiang C H, Tang Z L, Wang S T, Zhang Z T. A truncated octahedral spinel LiMn₂O₄ as high-performance cathode material for ultrafast and long-life lithium-ion batteries[J]. J. Power Sources, 2017,357:144-148. doi: 10.1016/j.jpowsour.2017.04.079
31. [31]
  Fu Y, Jiang H, Hu Y J, Dai Y H, Zhang L, Li C Z. Synergistic enhancement effect of Al doping and highly active facets of LiMn₂O₄ cathode materials for lithium-ion batteries[J]. Ind. Eng. Chem. Res., 2015,54(15):3800-3805.
32. [32]
  Xiao B, Wu G, Wang T D, Wei Z G, Sui Y W, Shen B L, Qi J Q, Wei F X, Meng Q K, Ren Y J, Xue X L, Zheng J C, Mao J, Dai K H. High entropy oxides (FeNiCrMnX)₃O₄(X=Zn, Mg) as anode materials for lithium ion batteries[J]. Ceram. Int., 2021,47(24):33972-33977.
33. [33]
  Cai Y J, Huang Y D, Wang X C, Jia D Z, Pang W K, Guo Z P, Du Y P, Tang X C. Facile synthesis of LiMn₂O₄ octahedral nanoparticles as cathode materials for high capacity lithium ion batteries with long cycle life[J]. J. Power Sources, 2015,278:574-581.
34. [34]
  Xu J T, Chou S L, Gu Q F, Liu H K, Dou S X. The effect of different binders on electrochemical properties of LiNi_1/3Mn_1/3Co_1/3O₂ cathode material in lithium ion batteries[J]. J. Power Sources, 2013,225:172-178.
1. [1]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
2. [2]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
3. [3]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
4. [4]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
5. [5]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
6. [6]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
7. [7]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
8. [8]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
9. [9]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
10. [10]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
11. [11]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
12. [12]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
13. [13]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
14. [14]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
15. [15]
  Simin Wei , Yaqing Yang , Junjie Li , Jialin Wang , Jinlu Tang , Ningning Wang , Zhaohui Li . The Mn/Yb/Er triple-doped CeO₂ nanozyme with enhanced oxidase-like activity for highly sensitive ratiometric detection of nitrite. Chinese Chemical Letters, 2024, 35(6): 109114-. doi: 10.1016/j.cclet.2023.109114
16. [16]
  Le Ye , Wei-Xiong Zhang . Structural phase transition in a new organic-inorganic hybrid post-perovskite: (N,N-dimethylpyrrolidinium)[Mn(N(CN)2)3]. Chinese Journal of Structural Chemistry, 2024, 43(6): 100257-100257. doi: 10.1016/j.cjsc.2024.100257
17. [17]
  Jing Cao , Dezheng Zhang , Bianqing Ren , Ping Song , Weilin Xu . Mn incorporated RuO₂ nanocrystals as an efficient and stable bifunctional electrocatalyst for oxygen evolution reaction and hydrogen evolution reaction in acid and alkaline. Chinese Chemical Letters, 2024, 35(10): 109863-. doi: 10.1016/j.cclet.2024.109863
18. [18]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
19. [19]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
20. [20]
  Guihuang Fang , Wei Chen , Hongwei Yang , Haisheng Fang , Chuang Yu , Maoxiang Wu . Improved performance of LiMn_0.8Fe_0.2PO₄ by addition of fluoroethylene carbonate electrolyte additive. Chinese Chemical Letters, 2024, 35(6): 108799-. doi: 10.1016/j.cclet.2023.108799

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1015)
HTML views(84)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and electrochemical properties of truncated octahedral LiZn0.08Al0.01Mn1.91O4 cathode material by solid-state combustion method

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis and electrochemical properties of truncated octahedral LiZn_0.08Al_0.01Mn_1.91O₄ cathode material by solid-state combustion method