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Citation: Sheng-Yang HAO, Yu-Ting ZHANG, Xiao-Qing WANG. Preparation and supercapacitor performance of Mo-doped NiMnSe2[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(6): 1091-1102. doi: 10.11862/CJIC.2023.072 shu

Preparation and supercapacitor performance of Mo-doped NiMnSe2

  • College of Chemical Engineering and Technology, Tiangong University, Tianjin 300387, China

  • Corresponding author: Xiao-Qing WANG, Xiaoqingwang2012@126.com
  • Received Date: 15 November 2022
    Revised Date: 20 April 2023

Figures(9)

  • In this work, we applied a simple hydrothermal method to grow a Mo-doped NiMnSe2 without binding reagent on the foam nickel (noted as Ni0.8Mo0.2MnSe2). Small amount of Mo substitution for Ni can provide rich reactive sites and therefore greatly enhances the electrochemical performance of NiMnSe2. The specific capacity of Ni0.8Mo0.2MnSe2 at 1 A·g-1 reached 1 404.0 F·g-1. Mo substitution can also decrease the charge transfer resistance and diffusion resistance as well as improve the stability of the material structure. The Ni0.8Mo0.2MnSe2//AC (activated carbon) hybrid supercapacitor (HSC) delivered capacity of 81.6 F·g-1 and exhibited excellent rate performance. After 10 000 cycles at 2 A·g-1, the Ni0.8Mo0.2MnSe2//AC HSC maintained 95.8% of the capacity, indicating a high cycling stability. Under the power density of 376.6 W·kg-1, the Ni0.8Mo0.2MnSe2//AC HSC showed an energy density of 25.5 Wh·kg-1, higher than those of other similar supercapacitor, implying a high energy storage ability.
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