Citation: Xuan WANG, Ji-Jiang WANG, Long TANG, Lao-Bang WANG, Er-Lin YUE, Chao BAI, Xiao WANG, Yu-Qi ZHANG. A stable Zinc(Ⅱ)metal-organic framework in water for the detection of tetracycline[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(6): 1151-1158. doi: 10.11862/CJIC.2023.069 shu

A stable Zinc(Ⅱ)metal-organic framework in water for the detection of tetracycline

Yan′an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan′an University, Yan′an, Shaanxi 716000, China

Corresponding author: Ji-Jiang WANG, yadxwjj@126.com Long TANG, ydtanglong@163.com
Received Date: 24 December 2022
Revised Date: 18 March 2023

Figures(9)

A Zinc(Ⅱ) metal-organic framework (Zn-MOF), namely [Zn(H₂L)(4, 4′-bpy)]_n (1), where H₄L=1, 1′-ethylbi- phenyl-3, 3′, 5, 5′-tetracarboxylic acid, 4, 4′-bpy=4, 4′-bipyridine, was successfully synthesized under solvothermal conditions. The structure was characterized by single-crystal X-ray diffraction, elemental analysis, and thermogravi- metric analysis. The single crystal structure analysis shows that 1 belongs to the monoclinic C2/c space group and H ₂L^2- ligands adopt monodentate coordination mode, connecting with Zn(Ⅱ)to form 1D chains. Finally, the 1D chains are connected by 4, 4′-bpy to form a 2D wavelike network. 1 shows good stability in water, and can be used as a highly sensitive and selective fluorescent probe to detect tetracycline (TET) with a detection limit of 0.17 μmol· L^-1. 1 can be successfully used for the determination of tetracycline in Yanhe River water. In addition, the possible fluorescence quenching mechanisms of 1 were also studied. CCDC: 2212375, 1.
- metal-organic framework,
- crystal structure,
- tetracycline,
- fluorescent sensor
1. [1]
  Bai Y H, Su J F, Wen Q, Li G Q, Xue L, Huang T L. . Removal of tetracycline by denitrifying Mn - oxidizing bacterium Pseudomonas sp. H117 and biomaterials (BMO and MBMO): Efficiency and mechanisms[J]. Bioresour. Technol, 2020,312123565. doi: 10.1016/j.biortech.2020.123565
2. [2]
  Yaghi O M, O′Keeffe M, Ockwig N W, Ch ae, H K, Eddaoudi M, Kim J. Reticular synthesis and the design of new materials[J]. Nature, 2003,423:705-714. doi: 10.1038/nature01650
3. [3]
  Butova V V, Soldatov M A, Guda A A, Lomachenko K A, Lamberti C. Metal-organic frameworks: Structure, properties, methods of synthesis and characterization[J]. Russ. Chem. Rev, 2016,85:280-307. doi: 10.1070/RCR4554
4. [4]
  Liang Q N, Chen J M, Wang F L, Li Y W. Transition metal - based metal-organic frameworks for oxygen evolution reaction[J]. Coord. Chem. Rev, 2020,424213488. doi: 10.1016/j.ccr.2020.213488
5. [5]
  Sakamoto N, Nishimura Y F, Nonaka T, Ohashi M, Ishida N, Kitazumi K, Kato Y, Sekizawa K, Morikawa T, Arai T. Self-assembled cuprous coordination polymer as a catalyst for CO₂ electrochemical reduction into C₂ products[J]. ACS Catal, 2020,10(18):10412-10419. doi: 10.1021/acscatal.0c01593
6. [6]
  Woldu A R, Huang Z L, Zhao P X, Hu L S, Astruc D. Electrochemical CO₂ reduction (CO₂RR) to multi- carbon products over copper - based catalysts[J]. Chem. Rev, 2022,454214340.
7. [7]
  Zhou Y T, Abazari R, Chen J, Tahir M, Kumar A, Ikreedeegh R R, Rani E, Singh H, Kirillov A M. Bimetallic metal-organic frameworks and MOF-derived composites: Recent progress on electro and photoelectrocatalytic applications[J]. Coord. Chem. Rev, 2022,451214264. doi: 10.1016/j.ccr.2021.214264
8. [8]
  Lin J B, Zhang J P, Chen X M. Nonclassical active site for enhanced gas sorption in porous coordination polymer[J]. J. Am. Chem. Soc, 2010,132:6654-6656. doi: 10.1021/ja1009635
9. [9]
  Duan J G, Jin W Q, Kitagawa S. Water-resistant porous coordination polymers for gas separation[J]. Coord. Chem. Rev, 2017,332:48-74. doi: 10.1016/j.ccr.2016.11.004
10. [10]
  Duan J G, Higuchi M, Krishna R, Kiyonaga T, Tsutsumi Y, Sato Y, Kubota Y, Takata M, Kitagawa S. High CO₂/N₂/O₂ /CO separation in a chemically robust porous coordination polymer with low binding energy[J]. Chem. Sci, 2014,5(2):660-666. doi: 10.1039/C3SC52177J
11. [11]
  Imaz I, Rubio-Martinez M, Garcia-Fernandez L, Garcia F, Ruiz-Moli-na D, Hernando J, Puntes V, Maspoch D. Coordination polymer particles as potential drug delivery systems[J]. Chem. Commun, 2010,46:4737-4739. doi: 10.1039/c003084h
12. [12]
  Dutta B, Hazra A, Dey A, Sinha C, Ray P P, Banerjee P, Mir M H. Construction of a succinate - bridged Cd - based two - dimensional coordination polymer for efficient optoelectronic device fabrication and explosive sensing application[J]. Cryst. Growth Des, 2020,20(2):765-776. doi: 10.1021/acs.cgd.9b01181
13. [13]
  Wen T, Zhang D X, Liu J, Lin R, Zhang J. A multifunctional helical Cu coordination polymer with mechanochromic, sensing and photocatalytic properties[J]. Chem. Commun, 2013,49:5660-5662. doi: 10.1039/c3cc42241k
14. [14]
  Luo X Z, Abazari R, Tahir M, Fan W K, Kumar A, Kalhorizadeh T, Kirillov A M, Amani- Ghadim A R, Chen J, Zhou Y T. Trimetallic metal - organic frameworks and derived materials for environmental remediation and electrochemical energy storage and conversion[J]. Coord. Chem. Rev, 2022,461214505. doi: 10.1016/j.ccr.2022.214505
15. [15]
  Horike S, Umeyama D, Kitagawa S. Ion conductivity and transport by porous coordination polymers and metal-organic frameworks[J]. Acc.Chem. Re, 2013,46(11):2376-2384. doi: 10.1021/ar300291s
16. [16]
  CHEN X L, LIU L, SHANG L, CAI M, CUI H L, YANG H, WANG J J. A highly sensitive and multi-responsive Zn-MOF fluorescent sensor for detection of Fe³⁺, 2, 4, 6 - trinitrophenol, and ornidazole[J]. Chinese J. Inorg. Chem, 2022,38(4):735-744.
17. [17]
  ZHANG L W, LIU S Q, ZHANG P P, NI A Y, ZHANG J J. Synthe- sis, crystal structure, and detection of acidic amino acids of a Cd metal-organic framework based on 5-((naphthalen-1-ylmethyl) ami- no) isophthalic acid[J]. Chinese J. Inorg. Chem, 2022,38(9):1871-1877.
18. [18]
  XU H, PAN Z R, QI Z P, SUN J. Three luminescent Zn-MOFs based on V-shaped ligands for fluorescence sensing of 2, 4, 6-trinitrophenol and Fe³⁺ in aqueous solution[J]. Chinese J. Inorg. Chem, 2022,38(12):2479-2490.
19. [19]
  Wang S Q, Wang L, Zhu Y M, Song Y H. Fluorescent detection of S^2- based on ZnMOF-74 and CuMOF-74. Spectroc[J]. Acta Pt. A-Molec. Biomolec. Spectr, 2020,236118327. doi: 10.1016/j.saa.2020.118327
20. [20]
  Farahani Y D, Safarifard V. Highly selective detection of Fe³⁺, Cd²⁺ and CH₂Cl₂ based on a fluorescent Zn- MOF with azine- decorated pores[J]. J.Solid State Chem, 2019,275:131-140. doi: 10.1016/j.jssc.2019.04.018
21. [21]
  Chandrasekhar P, Mukhopadhyay A, Savitha G, Moorthy J N. Remarkably selective and enantiodifferentiating sensing of histidine by a fluorescent homochiral Zn - MOF based on pyrene- tetralactic acid[J]. Chem Sc, 2016,7:3085-3091. doi: 10.1039/C5SC03839A
22. [22]
  Gogia A, Mandal S K. A rational design and green synthesis of 3D metal organic frameworks containing a rigid heterocyclic nitrogen - rich dicarboxylate: Structural diversity, CO₂ sorption and selective sensing of 2, 4, 6-TNP in water[J]. Dalton Trans, 2019,48:2388-2398. doi: 10.1039/C8DT04474K
23. [23]
  Liu T Y, Qu X L, Zhang Y, Yan B. A stable Cd -based metal-organic framework: Synthesis, structure, and its Eu³⁺ functionalization for ratiometric sensing on the biomarker 2-(2 - methoxyethoxy) acetic acid[J]. Inorg. Chem, 2021,60(12):8613-8620. doi: 10.1021/acs.inorgchem.1c00589
24. [24]
  Wang L B, Wang J J, Yue Er L, Li J F, Tang L, Bai Ch, Wang X, Hou X Y, Zhang Y Q. Information encryption, highly sensitive detection of nitrobenzene, tetracycline based on a stable luminescent Cd - MOF. Spectroc[J]. Acta Pt. A - Molec. Biomolec. Spect, 2022,269120752. doi: 10.1016/j.saa.2021.120752
25. [25]
  Dang S, Ma E, Sun Z M, Zhang H J. A layer-structured Eu-MOF as a highly selective fluorescent probe for Fe³⁺ detection through a cationexchange approach[J]. J. Mater. Chem., 2012,22:16920-16926. doi: 10.1039/c2jm32661b
26. [26]
  Chen Z, Sun Y W, Zhang L L, Sun D, Liu F L, Meng Q G, Wang R M, Sun D F. . A tubular europium-organic framework exhibiting selective sensing of Fe³⁺ and Al³⁺ over mixed metal ions[J]. Chem.Commu, 2013,49:11557-11559. doi: 10.1039/c3cc46613b
27. [27]
  Zhao X L, Tian D, Gao Q, Sun H W, Xu J, Bu X H. A chiral lantha- nide metal - organic framework for selective sensing of Fe ions[J]. Dalton Tran, 2016,45:1040-1046. doi: 10.1039/C5DT03283K
28. [28]
  Nagarkar S S, Joarder B, Chaudhari A K, Mukherjee S, Ghosh S K. Highly selective detection of nitro explosives by a luminescent metalorganic framework[J]. Angew. Chem. Int. Ed, 2013,52(10):2881-2885. doi: 10.1002/anie.201208885
29. [29]
  Pramanik S, Zheng C, Zhang X, Emge T J, Li J. New microporous metal- organic framework demonstrating unique selectivity for detection of high explosives and aromatic compounds[J]. J. Am. Chem. Soc, 2011,133(12):4153-4155. doi: 10.1021/ja106851d
30. [30]
  Liu Z P, He W J, Guo Z J. Metal coordination in photoluminescent sensing[J]. Chem. Soc. Rev, 2013,42:1568-1600. doi: 10.1039/c2cs35363f
31. [31]
  He T S, Lan Y L, Li Z Y, Zhu L N, Li X Z. Chiral coordination polymers from a new 2 - deoxy - D - ribose derivative linker: Syntheses, structures, and Fe³⁺ fluorescent probe functions[J]. Cryst. Growth Des, 2021,21(4):2233-2242. doi: 10.1021/acs.cgd.0c01661
32. [32]
  Huang Y, Qin Y, Ge Y, Cui Y F, Zhang X M, Li Y H, Yao J L. Ratio- nally assembled nonanuclear lanthanide clusters: Dy₉ displays slow relaxation of magnetization and Tb₉ serves as luminescent sensor for Fe³⁺, CrO₄^2- and Cr₂O₇^2-[J]. New J. Chem, 2019,43:19344-19354. doi: 10.1039/C9NJ04893F
33. [33]
  Smith J A, Singh-Wilmot M A, Carter K P, Cahill C L, Ridenour J A. Lanthanide-2, 3, 5, 6- tetrabromoterephthalic acid metal-organic frame- works: Evolution of halogen…halogen interactions across the lantha- nide series and their potential as selective bifunctional sensors for the detection of Fe³⁺, Cu²⁺, and nitroaromatics[J]. Cryst. Growth Des, 2019,19(1):305-319. doi: 10.1021/acs.cgd.8b01426
34. [34]
  Chen S, Yu Y L, Wang J H. Inner filter effect-based fluorescent sens- ing systems: A review[J]. Anal. Chim. Act, 2018,999:13-26. doi: 10.1016/j.aca.2017.10.026
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