Citation: Xiao HAN, Lin-Yu WANG, Fu-Jiang GENG, Gai-Qing XI. Adsorption of rhodamine B by benzimidazole-based metal-organic framework/graphene oxide composites[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(6): 1159-1168. doi: 10.11862/CJIC.2023.061 shu

Adsorption of rhodamine B by benzimidazole-based metal-organic framework/graphene oxide composites

Hebei Key Laboratory of Heterocyclic Compounds, Hebei Center for New Inorganic Optoelectronic Nanomaterial Research, College of Chemical Engineering & Material, Handan University, Handan, Hebei 056005, China

Corresponding author: Xiao HAN, hanxiao2007510806@126.com Gai-Qing XI, xigq2005@163.com
Received Date: 12 December 2022
Revised Date: 12 April 2023

Figures(8)

In this work, two different morphologies of composites with Cd (Ⅱ) benzimidazole-derived metal-organic framework (MOF) and graphene oxide (GO) were successfully synthesized by adjusting the alkali environments in the one-pot solvothermal process. The structures and properties of these composites were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV-visible absorption spectra (UV-Vis), and FT-IR. The adsorption performance of these composites for rhodamine B (RhB) in water was studied. The results showed that GO and Cd-MOF were successfully combined, and the addition of GO enhanced the stability of Cd-MOF in water and improved its adsorption capacity. When the pH value of the solution was 3.5 and the adsorption time was 60 min, the adsorption rate could reach ca. 95%.
- composite,
- adsorption,
- rhodamine B
1. [1]
  Liu X T, Chen S S, Li S M, Nie H X, Fen Y Q, Fan Y N, Yu M H, Chang Z, Bu X H. Structural tuning of Zn(Ⅱ)-MOFs based on pyrazole functionalized carboxylic acid ligands for organic dye adsorption[J]. CrystEngComm, 2020,22(36):5941-5945. doi: 10.1039/D0CE00798F
2. [2]
  Zhang H, Geng W Y, Luo Y H, Ding Z J, Wang Z X, Xie A D, Zhang D E. Reticular synthesis of two anionic Zn(Ⅱ)-MOFs for organic dye adsorption/separation and lanthanide ion sensitization[J]. CrystEngComm, 2021,23(18):3319-3325. doi: 10.1039/D1CE00112D
3. [3]
  Qasem N A A, Mohammed R H, Lawal D U. Removal of heavy metal ions from wastewater: A comprehensive and critical review[J]. npj Clean Water, 2021,4(1)36. doi: 10.1038/s41545-021-00127-0
4. [4]
  Zhang S, Rong F L, Guo C P, Duan F H, He L H, Wang M H, Zhang Z H, Kang M M, Du M. Metal-organic frameworks (MOFs) based electrochemical biosensors for early cancer diagnosis in vitro[J]. Coord. Chem. Rev., 2021,439213948. doi: 10.1016/j.ccr.2021.213948
5. [5]
  Kumar P, Vejerano E, Khan A, Lisak G, Ahn J H, Kim K H. Metal organic frameworks (MOFs): Current trends and challenges in control and management of air quality[J]. Korean J. Chem. Eng., 2019,36(11):1839-1853. doi: 10.1007/s11814-019-0378-8
6. [6]
  Okoro H K, Ayika S O, Ngila J C, Tella A C. Rising profile on the use of metal-organic frameworks (MOFs) for the removal of heavy metals from the environment: An overview[J]. Appl. Water Sci., 2018,8(6)169. doi: 10.1007/s13201-018-0818-3
7. [7]
  Jayaramulu K, Geyer F, Schneemann A, Kment Š, Otyepka M, Zboril R, Vollmer D, Fischer R A. Hydrophobic metal-organic frameworks[J]. Adv. Mater., 2019,31(32)1900820.
8. [8]
  Zhang X D, Lv X T, Shi X Y, Yang Y Q. Enhanced hydrophobic UiO-66(University of Oslo 66) metal-organic framework with high capacity and selectivity for toluene capture from high humid air[J]. J. Colloid Interface Sci., 2019,539:152-160. doi: 10.1016/j.jcis.2018.12.056
9. [9]
  Schoenecker P M, Carson C G, Jasuja H, Flemming C J J, Walton K S. Effect of water adsorption on retention of structure and surface area of metalorganic frameworks[J]. Ind. Eng. Chem. Res., 2012,51(18):6513-6519. doi: 10.1021/ie202325p
10. [10]
  Li Y J, Miao J P, Sun X J, Xiao J, Li Y W, Wang H H, Xia Q B, Li Z. Mechanochemical synthesis of Cu-BTC@GO with enhanced water stability and toluene adsorption capacity[J]. Chem. Eng. J., 2016,298:191-197. doi: 10.1016/j.cej.2016.03.141
11. [11]
  Zhou Y, Zhou L, Zhang X H, Chen Y L. Preparation of zeolitic imidazolate framework-8/graphene oxide composites with enhanced VOCs adsorption capacity[J]. Microporous Mesoporous Mat., 2016,225:488-493. doi: 10.1016/j.micromeso.2016.01.047
12. [12]
  Ying Y P, Liu D H, Zhang W X, Ma J, Huang H L, Yang Q Y, Zhong C L. High-flux graphene oxide membranes intercalated by metalorganic framework with highly selective separation of aqueous organic solution[J]. ACS Appl. Mater. Interfaces, 2017,9(2):1710-1718. doi: 10.1021/acsami.6b14371
13. [13]
  Zheng Y, Chu F C, Zhang B, Yan J, Chen Y L. Ultrahigh adsorption capacities of carbon tetrachloride on MIL-101 and MIL-101/graphene oxide composites[J]. Microporous Mesoporous Mat., 2018,263:71-76. doi: 10.1016/j.micromeso.2017.12.007
14. [14]
  Dai Y X, Li M, Liu F, Xue M, Wang Y Q, Zhao C C. Graphene oxide wrapped copperbenzene-1, 3, 5-tricarbxylate metal organic framework as efficient absorbent for gaseous toluene under ambient conditions[J]. Environ. Sci. Pollut. Res., 2019,26(3):2477-2491. doi: 10.1007/s11356-018-3657-8
15. [15]
  Zheng Y, Zheng S S, Xue H G, Pang H. Metal-organic frameworks/graphene-based materials: Preparations and applications[J]. Adv. Funct. Mater., 2018,28(47)1804950. doi: 10.1002/adfm.201804950
16. [16]
  Muschi M, Serre C. Progress and challenges of graphene oxide/metalorganic composites[J]. Coord. Chem. Rev., 2019,387:262-272. doi: 10.1016/j.ccr.2019.02.017
17. [17]
  Zhao Y N, Han X, Yu F H, Wei D H, Cheng Q, Meng X R, Ding J, Hou H W. Direct conversion of benzothiadiazole to benzimidazole: New benzimidazole-derived metal-organic frameworks with adjustable honeycomb-like cavities[J]. Chem. -Eur. J., 2019,25(20):5246-5250. doi: 10.1002/chem.201805697
18. [18]
  Huang H Y, Wang Y, Zhang Y B, Niu Z Y, Li X L. Amino-functionalized graphene oxide for Cr(Ⅵ), Cu(Ⅱ), Pb(Ⅱ) and Cd(Ⅱ) removal from industrial wastewater[J]. Open Chem., 2020,18(1):97-107. doi: 10.1515/chem-2020-0009
19. [19]
  Kim D, Kim D W, Hong W G, Coskun A. Graphene/ZIF-8 composites with tunable hierarchical porosity and electrical conductivity[J]. J. Mater. Chem. A, 2016,4:7710-7717. doi: 10.1039/C6TA01899H
20. [20]
  Liu L, Zhang B, Zhang Y R, He Y J, Huang L H, Tan S Z, Cai X. Simultaneous removal of cationic and anionic dyes from environmental water using montmorillonite-pillared graphene oxide[J]. J. Chem. Eng. Data, 2015,60:1270-1278. doi: 10.1021/je5009312
21. [21]
  Karimzadeh Z, Javanbakht S, Namazi H. Carboxymethylcellulose/MOF-5/graphene oxide bio-nanocomposite as antibacterial drug nanocarrier agent[J]. Bioimpacts, 2018,9:5-13. doi: 10.15171/bi.2019.02
22. [22]
  Kumar G, Masram D T. Sustainable synthesis of MOF-5@GO nanocomposites for efficient removal of rhodamine B from Water[J]. ACS Omega, 2021,6:9587-9599. doi: 10.1021/acsomega.1c00143
23. [23]
  He Y, Fishman Z S, Yang K R, Ortiz B, Liu C, Goldsamt J, Batista V S, Pfefferle L D. Hydrophobic CuO nanosheets functionalized with organic adsorbates[J]. J. Am. Chem. Soc., 2018,140(5):1824-1833. doi: 10.1021/jacs.7b11654
24. [24]
  Shao H Y, Zhuang Q, Gao H D, Wang Y, Ji L, Wang X, Zhang T T, Duan L M, Bai J, Niu Z Q, Liu J H. Nitrogen and oxygen tailoring of a solid carbon active site for two-electron selectivity electrocatalysis[J]. Inorg. Chem. Front., 2021,8(1):173-181. doi: 10.1039/D0QI01089H
25. [25]
  Liu H C, Gu Y R, Dai Y X, Wang K, Zhang S T, Chen G, Zou B, Yang B. Pressure-induced blue-shifted and enhanced emission: A cooperative effect between aggregation-induced emission and energytransfer suppression[J]. J. Am. Chem. Soc., 2020,142:1153-1158. doi: 10.1021/jacs.9b11080
26. [26]
  Aboutalebi S H, Chidembo A T, Salari M, Konstantinov K, Wexler D, Liu H K, Dou S X. Comparison of GO, GO/MWCNTs composite and MWCNTs as potential electrode materials for supercapacitors[J]. Energy Environ. Sci., 2011,4:1855-1865. doi: 10.1039/c1ee01039e
27. [27]
  Tissera N D, Wijesena R N, Perera J R, de Silva K M N, Amaratunge G A J. Hydrophobic cotton textile surfaces using an amphiphilic graphene oxide (GO) coating[J]. Appl. Surf. Sci., 2015,324:455-463. doi: 10.1016/j.apsusc.2014.10.148
28. [28]
  Yao Z Y, Yang L, Cai Y C, Yan C C, Zhang M, Cai N, Dong X D, Wang P. Rigidifying the π-linker to enhance light absorption of organic dye-sensitized solar cells and influences on charge transfer dynamics[J]. J. Phys. Chem. C, 2014,118(6):2977-2986. doi: 10.1021/jp412070p
29. [29]
  Liu X, Xu Z, Cole J M. Molecular design of UV-vis absorption and emission properties in organic fluorophores: Toward larger bathochromic shifts, enhanced molar extinction coefficients, and greater stokes shifts[J]. J. Phys. Chem. C, 2013,117(32):16584-16595. doi: 10.1021/jp404170w
30. [30]
  Yang C, Wu S C, Cheng J H, Chen Y C. Indium-based metalorganic framework/graphite oxide composite as an efficient adsorbent in the adsorption of rhodamine B from aqueous solution[J]. J. Alloy. Compd., 2016,687:804-812. doi: 10.1016/j.jallcom.2016.06.173
1. [1]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
2. [2]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
3. [3]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
4. [4]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
5. [5]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
6. [6]
  Cunjun Li , Wencong Liu , Xianlei Chen , Liang Li , Shenyu Lan , Mingshan Zhu . Adsorption and activation of peroxymonosulfate on BiOCl for carbamazepine degradation: The role of piezoelectric effect. Chinese Chemical Letters, 2024, 35(10): 109652-. doi: 10.1016/j.cclet.2024.109652
7. [7]
  Shuqi Yu , Yu Yang , Keisuke Kuroda , Jian Pu , Rui Guo , Li-An Hou . Selective removal of Cr(Ⅵ) using polyvinylpyrrolidone and polyacrylamide co-modified MoS₂ composites by adsorption combined with reduction. Chinese Chemical Letters, 2024, 35(6): 109130-. doi: 10.1016/j.cclet.2023.109130
8. [8]
  Kexin Yuan , Yulei Liu , Haoran Feng , Yi Liu , Jun Cheng , Beiyang Luo , Qinglian Wu , Xinyu Zhang , Ying Wang , Xian Bao , Wanqian Guo , Jun Ma . Unlocking the potential of thin-film composite reverse osmosis membrane performance: Insights from mass transfer modeling. Chinese Chemical Letters, 2024, 35(5): 109022-. doi: 10.1016/j.cclet.2023.109022
9. [9]
  Qianqian Song , Yunting Zhang , Jianli Liang , Si Liu , Jian Zhu , Xingbin Yan . Boron nitride nanofibers enhanced composite PEO-based solid-state polymer electrolytes for lithium metal batteries. Chinese Chemical Letters, 2024, 35(6): 108797-. doi: 10.1016/j.cclet.2023.108797
10. [10]
  Minying Wu , Xueliang Fan , Wenbiao Zhang , Bin Chen , Tong Ye , Qian Zhang , Yuanyuan Fang , Yajun Wang , Yi Tang . Highly dispersed Ru nanospecies on N-doped carbon/MXene composite for highly efficient alkaline hydrogen evolution. Chinese Chemical Letters, 2024, 35(4): 109258-. doi: 10.1016/j.cclet.2023.109258
11. [11]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
12. [12]
  Miaomiao Li , Mengwei Yuan , Xingzi Zheng , Kunyu Han , Genban Sun , Fujun Li , Huifeng Li . Highly polar CoP/Co₂P heterojunction composite as efficient cathode electrocatalyst for Li-air battery. Chinese Chemical Letters, 2024, 35(9): 109265-. doi: 10.1016/j.cclet.2023.109265
13. [13]
  Ning DING , Siyu WANG , Shihua YU , Pengcheng XU , Dandan HAN , Dexin SHI , Chao ZHANG . Crystalline and amorphous metal sulfide composite electrode materials with long cycle life: Preparation and performance of hybrid capacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1784-1794. doi: 10.11862/CJIC.20240146
14. [14]
  Zixuan Zhu , Xianjin Shi , Yongfang Rao , Yu Huang . Recent progress of MgO-based materials in CO₂ adsorption and conversion: Modification methods, reaction condition, and CO₂ hydrogenation. Chinese Chemical Letters, 2024, 35(5): 108954-. doi: 10.1016/j.cclet.2023.108954
15. [15]
  Xiao Li , Wanqiang Yu , Yujie Wang , Ruiying Liu , Qingquan Yu , Riming Hu , Xuchuan Jiang , Qingsheng Gao , Hong Liu , Jiayuan Yu , Weijia Zhou . Metal-encapsulated nitrogen-doped carbon nanotube arrays electrode for enhancing sulfion oxidation reaction and hydrogen evolution reaction by regulating of intermediate adsorption. Chinese Chemical Letters, 2024, 35(8): 109166-. doi: 10.1016/j.cclet.2023.109166
16. [16]
  Xue Zhao , Mengshan Chen , Dan Wang , Haoran Zhang , Guangzhi Hu , Yingtang Zhou . Ultrafine nano-copper derived from dopamine polymerization & synchronous adsorption achieve electrochemical purification of nitrate to ammonia in complex water environments. Chinese Chemical Letters, 2024, 35(8): 109327-. doi: 10.1016/j.cclet.2023.109327
17. [17]
  Yu-Hang Li , Shuai Gao , Lu Zhang , Hanchun Chen , Chong-Chen Wang , Haodong Ji . Insights on selective Pb adsorption via O 2p orbit in UiO-66 containing rich-zirconium vacancies. Chinese Chemical Letters, 2024, 35(8): 109894-. doi: 10.1016/j.cclet.2024.109894
18. [18]
  Yan Wang , Huixin Chen , Fuda Yu , Shanyue Wei , Jinhui Song , Qianfeng He , Yiming Xie , Miaoliang Huang , Canzhong Lu . Oxygen self-doping pyrolyzed polyacrylic acid as sulfur host with physical/chemical adsorption dual function for lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(7): 109001-. doi: 10.1016/j.cclet.2023.109001
19. [19]
  Linhui Liu , Wuwan Xiong , Mingli Fu , Junliang Wu , Zhenguo Li , Daiqi Ye , Peirong Chen . Efficient NO_x abatement by passive adsorption over a Pd-SAPO-34 catalyst prepared by solid-state ion exchange. Chinese Chemical Letters, 2024, 35(4): 108870-. doi: 10.1016/j.cclet.2023.108870
20. [20]
  Yifan LIU , Zhan ZHANG , Rongmei ZHU , Ziming QIU , Huan PANG . A three-dimensional flower-like Cu-based composite and its low-temperature calcination derivatives for efficient oxygen evolution reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 979-990. doi: 10.11862/CJIC.20240008

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(1058)
HTML views(99)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142