Citation: Zi-Wei XIAO, Ze-Yu XU, Jian-Ming WANG. Solution-phase synthesis of bimetallic (Sn/Ni) doped porous silicon microspheres with electrochemical lithium storage[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(6): 1031-1041. doi: 10.11862/CJIC.2023.060 shu

Solution-phase synthesis of bimetallic (Sn/Ni) doped porous silicon microspheres with electrochemical lithium storage

Department of Chemistry, Zhejiang University, Hangzhou 310027, China

Corresponding author: Jian-Ming WANG, wjm@zju.edu.cn
Received Date: 1 January 2023
Revised Date: 7 March 2023

Figures(9)

Novel bimetallic (Sn/Ni) doped porous silicon microspheres (pSi@SnNi) were prepared by a simple chemical deposition method, using an inexpensive silicon-aluminum alloy precursor. The three-dimensional porous structure of pSi@SnNi composites can buffer the huge volume expansion of silicon in the lithiation process and increase lithium storage active sites. The deposition and doping of bimetallic (Sn/Ni) may improve the electronic conductivity of Si as well as enhance the structural stability of pSi. Profiting from the unique composition and microstructure, the pSi@SnNi composite with moderate Sn/Ni content showed large reversible lithium storage capacity (2 651.7 mAh·g^-1 at 0.1 A·g^-1), high electrochemical cycling stability (1 139 mAh·g^-1 after 400 cycles at 1 A·g^-1), and excellent rate capability (1 235.8 mAh·g^-1 at 2.5 A·g^-1).
- lithium-ion batteries,
- silicon-based anode,
- porous structure,
- bimetallic doping,
- chemical replacement
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