Citation: Xiao-Yan ZHANG, Piao CHEN, Ying-Xin ZHAO, Xiong-Jian LI, Shui-Jin YANG, Yun YANG. Construction and photocatalytic properties of MOF-808/Bi₂MoO₆ composites[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(5): 805-814. doi: 10.11862/CJIC.2023.051 shu

Construction and photocatalytic properties of MOF-808/Bi₂MoO₆ composites

1.
Hubei Key Laboratory of Pollutant Analysis & Reuse Technology, College of Chemistry and Chemical Engineering, Hubei Normal University, Huangshi, Hubei 435002, China
2.
College of Chemistry and Environmental Engineering, Hanjiang Normal University, Shiyan, Hubei 442000, China

Corresponding author: Shui-Jin YANG, yangshuijin@hbnu.edu.cn Yun YANG, yangyunhub@163.com
Received Date: 26 September 2022
Revised Date: 23 March 2023

Figures(11)

Zirconium-based metal-organic framework and bismuth molybdate composite (MOF-808/Bi₂MoO₆) was prepared by a simple two-step hydrothermal method. The phase composition, microstructure, optical properties, and photogenerated charge recombination efficiency of the materials were analyzed by X-ray powder diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, UV visible diffuse reflectance spectroscopy, N₂ adsorption-desorption testing, and electrochemical testing. Compared with pure Bi₂MoO₆ and MOF-808, the 0.5%-MOF-808/Bi₂MoO₆ composite exhibited higher photocatalytic activity, and the degradation rate of the antibiotic ciprofloxacin (CIP) reached 89.7% under visible light irradiation for 120 min. Through radical trapping experiments, it was proved that •O₂^- was the main active species, based on which we proposed a possible photocatalytic degradation mechanism.
- MOF-808,
- Bi₂MoO₆,
- photocatalytic properties,
- ciprofloxacin
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Construction and photocatalytic properties of MOF-808/Bi₂MoO₆ composites