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Citation: Hong-Mei CHAI, Jia-Ling YAN, Xue-Hua SUN, Gang-Qiang ZHANG, Yi-Xia REN, Lou-Jun GAO. Four isostructural lanthanide metal-organic frameworks: Syntheses, structures, and fluorescence sensing of Fe3+ and ciprofloxacin hydrochloride[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(4): 775-784. doi: 10.11862/CJIC.2023.039 shu

Four isostructural lanthanide metal-organic frameworks: Syntheses, structures, and fluorescence sensing of Fe3+ and ciprofloxacin hydrochloride

  • 1.

    Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

  • 2.

    Xinjiang Xuanli Environmental Protection Energy Co., Ltd., Hami, Xinjiang 839000, China

Figures(9)

  • Using nitrogen-containing tetra-carboxylate ligands 3, 5-bis (3', 5'-dicarboxyphenyl)-1H-1, 2, 4-triazole (H4BDT), four isostructural lanthanide metal-organic frameworks (Ln-MOFs): {[La3(BDT)2(HCOO)(H2O)5]·0.5H2O· 3DMF}n(1), {[Ce3(BDT)2(HCOO)(H2O)5]·3DMF}n(2), {[Pr3(BDT)2(HCOO)(H2O)5]·3DMF}n(3), and{[Nd3(BDT)2(HCOO)(H2O)5]·3DMF}n(4), have been synthesized by solvothermal method and characterized by single-crystal Xray diffraction, powder X-ray diffraction, elemental analysis, thermogravimetric analysis, FT-IR, adsorption experiment of N2, and luminescence spectra.The results show that all these Ln-MOFs are monoclinic C2/m space group crystals and have 3D mesoporous structures with double cores as inorganic building units.Among them, 2 could selectively fluorescently detect Fe3+ ion and ciprofloxacin hydrochloride drug molecule and the limits of detection were 4.59 and 0.77 μmol·L-1, respectively.
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