Citation: Shuai XIAO, Kai-Wen CHEN, Ming-Hui ZHANG, Kai CHEN, Wei-Wei GE. Synthesis and fluorescence sensing properties of cucurbit[5]uril-based supramolecular self-assemblies incorporating naphthalene-2, 7-disulphonate as the structure-directing agent[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(4): 585-595. doi: 10.11862/CJIC.2023.037 shu

Synthesis and fluorescence sensing properties of cucurbit[5]uril-based supramolecular self-assemblies incorporating naphthalene-2, 7-disulphonate as the structure-directing agent

Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Nanjing University of Information Science & Technology, Nanjing 210044, China

Corresponding author: Kai CHEN, kaichen85@nuist.edu.cn
Received Date: 19 November 2022
Revised Date: 14 February 2023

Figures(12)

Four new cucurbit[5]uril-based (Q[5]) supramolecular self-assemblies (Q[5]-SA), namely{[M (H₂O)₄(Q[5])]·(NDA)}·xH₂O (M=Co (1), Ni (2), Zn (3)) and{[Cd₂Cl₂(H₂O)₄(Q[5])]·(NDA)}·13H₂O (4), were synthesized by employing naphthalene-2, 7-disulphonate anion (2, 7-NDA^2-) as the structure-directing agent to react with Q[5]and transition metal cations (Co²⁺, Ni²⁺, Zn²⁺, Cd²⁺) under hydrothermal conditions.Single-crystal X-ray diffraction (SC-XRD) results reveal that self-assemblies 1-3 are isostructural and the metal cations (Co²⁺, Ni²⁺, Zn²⁺) merely coordinate with the carbonyl groups from one portal of Q[5]to form simple coordination compounds, while the Cd²⁺ cation in selfassembly 4 is bound to both of the two portals of Q[5]to generate 1D coordination chains.In particular, the 2, 7NDA^2- ligands in all self-assemblies are deprotonated to form organic anions 2, 7-NDA^2-, which balanced the system charge.However, 2, 7-NDA^2- fails to coordinate with the metal ions coordinated with Q[5], and these Q[5]-based coordination compounds are assembled into 3D supramolecular architectures through outer surface interactions of Q[5].Furthermore, the fluorescence sensing properties of 1 and 4 were investigated and the results indicated that they could both function as ratiometric fluorescence sensors for norfloxacin (NFX).
- cucurbit[5]uril,
- outer-surface interactions,
- supramolecular self-assembly,
- fluorescence sensor
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