Citation: Yu-Xing TAN, Yong-Lan FENG, Fu-Xing ZHANG, Jiang-Xi YU, Wu-Jiu JIANG, Dai-Zhi KUANG. Synthesis, crystal structure, and herbicidal activity of two tetranuclear di(n-butyl)tin aryloyacetates complexes with Sn₄O₈ cluster[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(4): 649-658. doi: 10.11862/CJIC.2023.031 shu

Synthesis, crystal structure, and herbicidal activity of two tetranuclear di(n-butyl)tin aryloyacetates complexes with Sn₄O₈ cluster

Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Organometallic New Materials, College of Hunan Province, Hunan Provincial Engineering Research Center for Monitoring and Treatment of Heavy Metals Pollution in the Upper Reaches of Xiangjiang River, School of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008, China

Corresponding author: Dai-Zhi KUANG, hnkcq@qq.com
Received Date: 23 September 2022
Revised Date: 3 January 2023

Figures(6)

Two tetranuclear di(n‐butyl)tin aryloyacetates [(o‐R—C₆H₄—OCH₂COOSn(n‐Bu)₂)₂O]₂ (R=H (C1), Cl (C2)) have been synthesized by the reaction of phenoxyacetic acid or o‐chlorophenoxyacetic acid with dibutyltin oxide, respectively. The structures were characterized by elemental analysis, IR, ¹H, ¹³C NMR, and X‐ray crystal diffraction. There is a ladder structure formed by a four‐membered central endocyclic Sn₂O₂ unit in the independent molecules of complexes C1 and C2, two carboxyl oxygen atoms and an Sn—O—Sn unit constituted the six‐membered ring on both sides of the ladder, which constitutes the Sn₄O₈ configuration. Thermogravimetric analysis shows that the complexes possess good thermal stability in the air atmosphere. Herbicidal activity results show that complex C1 has good regulative effects on the growth of Cassia tora Linn., and complex C2 has better inhibitory activity against the root and stalk of Amaranthus spinosus at the concentration of 50 mol·L^-1.
- di(n-butyl)tin aryloyacetates,
- synthesis,
- crystal structure,
- thermal stability,
- herbicidal activity
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Synthesis, crystal structure, and herbicidal activity of two tetranuclear di(n-butyl)tin aryloyacetates complexes with Sn4O8 cluster

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通讯作者: 陈斌, bchen63@163.com

Synthesis, crystal structure, and herbicidal activity of two tetranuclear di(n-butyl)tin aryloyacetates complexes with Sn₄O₈ cluster