Citation: Qiao-Li ZHANG, Ya-Ping WANG, Wan-Jie SUN, Qing-Feng YI. Preparation and oxygen reduction electroactivity of metal nanoparticles loaded on sheet-like carbon composites[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(2): 346-356. doi: 10.11862/CJIC.2023.003 shu

Preparation and oxygen reduction electroactivity of metal nanoparticles loaded on sheet-like carbon composites

1.
School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan 411201, China
2.
Key Laboratory of Theoretical Chemistry and Molecular Simulation of Ministry of Education, Xiangtan, Hunan 411201, China

Corresponding author: Qing-Feng YI, yqfyy2001@hnust.edu.cn
Received Date: 4 September 2022
Revised Date: 7 December 2022

Figures(7)

Herein, Co/C-N, Fe/C-N, and Fe-Co/C-N nanocomposites were obtained by the self-template method, and high-temperature pyrolysis of the mixture composed of dicyandiamide, sucrose, and cobalt (ferric) phthalocyanine as nitrogen, carbon, and metal sources respectively. Then a small amount of platinum was deposited on the Co/C-N with better oxygen reduction reaction (ORR) electroactivity by thermal reduction to obtain carbon nanosheet -supported Co-Pt nanoparticles (Co-Pt/C-N). The catalysts were well characterized and tested for ORR. The Co/C-N catalyst displayed the onset potential (E_onset) and half-wave potential (E_1/2) of ORR closed to the Pt/C in an alkaline solution, and it even presented the more positive onset potential and half-wave potential in a neutral solution. For Co-Pt/C-N, its ORR electroactivity in an acidic solution was greatly enhanced compared with the Co/C-N and was comparable to the Pt/C. The excellent ORR electroactivity of the samples is mainly attributed to the 3D structure formed by the carbon nanosheets, uniform distribution of the metal nanoparticles, and abundant pyridine N.
- oxygen reduction reaction,
- cobalt phthalocyanine,
- ferric phthalocyanine,
- fuel cell
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