Citation: Yan XU, Xuan WANG, Zhao-Wen LIU, Xiao-Yang WANG, Wen-Kang GAO, Lei CUI. Pyridinium/imidazolium-triggered modulation of structure and properties of cobalt naphthalene-diphosphates[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(2): 193-201. doi: 10.11862/CJIC.2022.291 shu

Pyridinium/imidazolium-triggered modulation of structure and properties of cobalt naphthalene-diphosphates

Department of Materials Science and Engineering, Suqian University, Suqian, Jiangsu 223800, China

Corresponding author: Yan XU, xuyan0511@126.com Lei CUI, 16077@squ.edu.cn
Received Date: 28 September 2022
Revised Date: 12 December 2022

Figures(6)

By the introduction of protonated 1, 3-di(4-pyridyl)propane (1, 3-dppH₂²⁺) and protonated bis(imidazol-1- ylmethyl)benzene (1, 4-bixH₂²⁺) as a cationic template, three new cobalt naphthalene-diphosphate coordination poly- mers based on 1, 4-naphthalenediphosphonic acid (1, 4-ndpaH₄), namely (1, 3-dppH₂)₂[Co₄(1, 4-ndpa)(1, 4-ndpaH)₂(1, 4-ndpaH₂)]·6H₂O (1), (1, 4-bixH₂)_0.5[Co(1, 4-ndpaH)] (2), and (1, 4-bixH₂)_0.5[Co₂(1, 4-ndpaH)(1, 4-ndpaH₂)(H₂O)₂] (3), have been hydrothermally synthesized. Complexes 1-3 were characterized by elemental analysis, infrared spectros- copy, single crystal X -ray diffraction, powder X -ray diffraction, and thermogravimetric analysis, respectively. In complexes 1 and 2, inorganic chains of corner-sharing {CoO₄} and {PO₃C} tetrahedron are cross-linked by naphtha- lene ligands into 3D open-framework structures. The protonated di-pyridinium/imidazolium moieties, 1, 3-dppH₂²⁺ for 2 and 1, 4-bixH₂²⁺ for 2, lie inside the skeletal voids of the crystal structure, respectively. Interestingly, complex 3 with similar chemical composition to 2 except for an additional 1, 4-ndpaH₂^2- ligand and two coordinated water mole- cules shows a 2D undulating layer structure, where the chains of corner-sharing {CoO₅} trigonal bipyramid, {CoO6} octahedron, and {PO₃C} tetrahedron are cross - linked by naphthalene groups. Adjacent layers are packed in AB stacking into the supramolecular structure, in which 1, 4-bixH₂²⁺ ions fill and balance the charge of 3. Magnetic stud- ies reveal that dominant antiferromagnetic interactions between the magnetic centers are propagated in complexes 1 and 2.
- coordination polymers,
- naphthalene-diphosphate ligand,
- template,
- crystal structure,
- magnetism
1. [1]
  Clearfield A, Demadis K. Metal phosphonate chemistry: From synthesis to applications. Cambridge: Royal Society of Chemistry, 2012.
2. [2]
  Bao S S, Zheng L M. Magnetic materials based on 3d metal phosphonates[J]. Coord. Chem. Rev., 2016,319:63-85. doi: 10.1016/j.ccr.2016.05.002
3. [3]
  Yücesan G, Zorlu Y, Stricker M, Beckmann J. Metal - organic solids derived from arylphosphonic acids[J]. Coord. Chem. Rev., 2018,369105122.
4. [4]
  Goura J, Chandrasekhar V. Molecular metal phosphonates[J]. Chem. Rev., 2015,115:6854-6965. doi: 10.1021/acs.chemrev.5b00107
5. [5]
  Mao J G. Structures and luminescent properties of lanthanide phosphonates[J]. Coord. Chem. Rev., 2007,251:1493-1520. doi: 10.1016/j.ccr.2007.02.008
6. [6]
  Firmino A D G, Figueira F, Tome J P C, Paz F A A, Rocha J. Metalorganic frameworks assembled from tetraphosphonic ligands and lanthanides[J]. Coord. Chem. Rev., 2018,355:133-149. doi: 10.1016/j.ccr.2017.08.001
7. [7]
  Jia J G, Zheng L M. Metal-organic nanotubes: Designs, structures and functions[J]. Coord. Chem. Rev., 2020,403213083. doi: 10.1016/j.ccr.2019.213083
8. [8]
  Weng G G, Zheng L M. Chiral metal phosphonates: Assembly, structures and functions[J]. Sci. China Chem., 2020,63(5):619-636. doi: 10.1007/s11426-020-9707-4
9. [9]
  Liu B, Liu J C, Shen Y, Feng J S, Bao S S, Zheng L M. Polymorphic layered copper phosphonates: Exfoliation and proton conductivity studies[J]. Dalton Trans., 2019,48:6539-6545. doi: 10.1039/C9DT00970A
10. [10]
  Huang J, Ding H M, Xu Y, Zeng D, Zhu H, Zang D M, Bao S S, Ma Y Q, Zheng L M. Chiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers[J]. Nat. Commun., 2017,82131. doi: 10.1038/s41467-017-02260-2
11. [11]
  Huang X D, Wen G H, Bao S S, Jia J G, Zheng L M. Thermo- and light-triggered reversible interconversion of dysprosium- anthracene complexes and their responsive optical, magnetic and dielectric properties[J]. Chem. Sci., 2021,12:929-937. doi: 10.1039/D0SC04851H
12. [12]
  Liu S B, Bao S S, Zheng L M. Polar layered coordination polymers incorporating triazacyclononane - triphosphonate metalloligands[J]. Dalton Trans., 2020,49:3758-3765. doi: 10.1039/C9DT03858B
13. [13]
  Wen G H, Chen X M, Xu K, Xu X J, Bao S S, Zheng L M. Uranyl phosphonates: Crystalline materials and nanosheets for temperature sensing[J]. Dalton Trans., 2021,50:17129-17139. doi: 10.1039/D1DT02977K
14. [14]
  Feng J S, Bao S S, Ren M, Cai Z S, Zheng L M. Chirality- and pHcontrolled supramolecular isomerism in cobalt phosphonates and its impact on the magnetic behavior[J]. Chem. - Eur. J., 2015,2117336. doi: 10.1002/chem.201502335
15. [15]
  Tang S F, Li L J, Wang C, Zhao X B. Investigation of the structure variation of metal diphosphonates with the changing of N-donor auxiliary ligands and their properties[J]. CrystEngComm, 2014,169104. doi: 10.1039/C4CE01266F
16. [16]
  Rom T, Kumar N, Sharma M, Gaur A, Paul A K. Colossal dielectric responses from the wide band gap 2D - semiconducting amine templated hybrid framework materials[J]. Inorg. Chem., 2020,59(14)94659470.
17. [17]
  Fu R B, Hu S M, Wu X T. New layered metal phosphonates based on functionalized phosphonic acids[J]. Cryst. Growth Des., 2015,15(6):3004-3014. doi: 10.1021/acs.cgd.5b00423
18. [18]
  Rom T, Biswas R, Haldar K K, Sarkar S, Saha U, Paul A K. Charge separated one-dimensional hybrid cobalt/nickel phosphonate frameworks: A facile approach to design bifunctional electrocatalyst for oxygen evolution and hydrogen evolution reactions[J]. Inorg. Chem., 2021,60:15106-15111. doi: 10.1021/acs.inorgchem.1c02320
19. [19]
  Paul A K, Kanagaraj R, Jana A K, Maji P K. Novel amine templated three-dimensional zinc-organophosphonates with variable poreopenings[J]. CrystEngComm, 2017,19:6425-6435. doi: 10.1039/C7CE00994A
20. [20]
  Ma Y J, Hu J X, Han S D, Pan J, Li J H, Wang G M. Manipulating on/off single-molecule magnet behavior in a Dy(Ⅲ)-based photochromic complex[J]. J. Am. Chem. Soc., 2020,142:2682-2689. doi: 10.1021/jacs.9b13461
21. [21]
  Liu H H, Ma Y J, Han S D, Li J H, Wang G M. Zinc diphosphonates with extended dipyridine units: Synthesis, structures, in situ reactions, and photochromism[J]. Dalton Trans., 2019,48:3955-3961. doi: 10.1039/C9DT00081J
22. [22]
  Bulut A, Zorlu Y, Wörle M, Çetinkaya A C, Kurt H, Tam B, Yazaydın A, Beckmann J, Yücesan G. Short naphthalene organophosphonate linkers to microporous frameworks[J]. ChemistrySelect, 2017,27050. doi: 10.1002/slct.201701411
23. [23]
  Kahn O. Molecular magnetism. New York: Wiley-VCH, 1993.
24. [24]
  Zou Q, Bao S S, Huang X D, Wen G H, Jia J G, Wu L Q, Zheng L M. Cobalt(Ⅱ)-dianthracene frameworks: Assembly, exfoliation and properties[J]. Chem.-Asian J., 2021,16:1-11. doi: 10.1002/asia.202001239
25. [25]
  Zheng T, Bao S S, Ren M, Zheng L M. Cobalt phosphonates based on 4-(ethoxycarbonyl)-naphthalen-1-yl)phosphonic acid[J]. Dalton Trans., 2013,42:16396-16402. doi: 10.1039/c3dt52125g
26. [26]
  Pan J, Ma Y J, Han S D, Xue Z Z, Wang G M. Switching the zincdiphosphonates from 1D chain to 2D layer and 3D framework by the modulation of a flexible organic amine[J]. Cryst. Growth Des., 2019,19:2919-2926. doi: 10.1021/acs.cgd.9b00139
27. [27]
  Paul A K, Kanagaraj R, Pant N, Naveen K. Rare examples of aminetemplated organophosphonate open - framework compounds: Combined role of metal and amine for structure building[J]. Cryst. Growth Des., 2017,17:5620-5624. doi: 10.1021/acs.cgd.7b01110
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