Citation: Liang WEI, Jian-Kai WANG, Kai-Ge LIU, Qing-Yun ZHOU, Hao-Xin PAN, Shan FAN, Yong ZHANG. Nanocellulose/reduced graphene oxide composites for high performance supercapacitors[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(3): 456-464. doi: 10.11862/CJIC.2022.287 shu

Nanocellulose/reduced graphene oxide composites for high performance supercapacitors

Liang WEI ^{1, 2} ,
Jian-Kai WANG ³ ,
Kai-Ge LIU ^{1, 2} ,
Qing-Yun ZHOU ^{1, 2} ,
Hao-Xin PAN ^{1, 2} ,
Shan FAN ^{1, 2,,} ,
Yong ZHANG ^{1, 2,,}

1.
School of Materials Science and Engineering, Qiqihar University, Qiqihar, Heilongjiang 161006, China
2.
Heilongjiang Province Key Laboratory of Polymeric Composition Material, Qiqihar, Heilongjiang 161006, China
3.
School of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar, Heilongjiang 161006, China

Corresponding author: Shan FAN, leon1981@163.com Yong ZHANG, 15804528735@163.com
Received Date: 23 August 2022
Revised Date: 2 November 2022

Figures(7)

Nanocellulose/reduced graphene oxide (NC/rGO) composites were prepared by a simple one-step hydrothermal method using high-concentration graphene oxide (GO) solution as the reaction precursor and nanocellulose (NC) as the physical spacer and electrolyte reservoirs. Subsequently, we explored the potential of NC/rGO as electrode materials for supercapacitors. Due to its dense porous structure and large oxygen-containing functional group content, NC/rGO-1 prepared with 1 mL NC exhibited the best electrochemical performance. The binder-free symmetric supercapacitor based on NC/rGO-1 showed high gravimetric and volumetric specific capacitance of 269.33 F·g^-1 and 350.13 F·cm^-3 at a current density of 0.3 A·g^-1. These values can still reach 215.88 F·g^-1 and 280.62 F·cm^-3 at 10.0 A·g^-1 (80.15% of its initial value). The assembled device also displayed high gravimetric and volumetric energy densities (9.3 Wh·kg^-1 and 12.13 Wh·L^-1) and excellent cycling performance (the initial specific capacitance decreased by only 6.02% after 10 000 cycles at 10 A·g^-1).
- graphene,
- nanocellulose,
- supercapacitor
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