Citation: Long TANG, Lu-Yuan CHEN, Xiang-Yang HOU, Xiao WANG, Ji-Jiang WANG. Two cadmium-based coordination polymers with tripodal carboxylate and imidazolyl ligands: Syntheses, structures, and fluorescent properties[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(1): 168-180. doi: 10.11862/CJIC.2022.273 shu

Two cadmium-based coordination polymers with tripodal carboxylate and imidazolyl ligands: Syntheses, structures, and fluorescent properties

1.
Yan'an University Key Laboratory of New Energy & New Functional Materials, Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China
2.
Shaanxi Jingyi Chemical Co., Ltd., Yulin, Shaanxi 719300, China

Corresponding author: Long TANG, ydtangl@126.com Ji-Jiang WANG, yadxwjj@126.com
Received Date: 14 June 2022
Revised Date: 8 October 2022

Figures(23)

Two cadmium-based coordination polymers [Cd(Htatb) (1,4-bimb)] ·H₂O (1) and [Cd(Htatb) (1,4-bib) (H₂O)]·DMF (2) (H₃tatb=4, 4', 4″-s-triazine-2,4,6-tribenzoic acid, 1,4-bimb=1,4-bis(imidazole-1-ylmethyl) benzene, 1,4-bib=1,4-bis(1-imidazoly) benzene) were synthesized by hydrothermal reactions and characterized by single-crystal X-ray diffraction, thermogravimetric analyses, IR spectroscopy, elemental analysis, etc. 1 displays a 2D layer structure, further these layers are joined by O—H⋯O hydrogen bonding to generate a four-fold interpenetrating 3D architecture. 2 shows a 2D layer structure, further joined through O—H⋯O hydrogen bonding to produce a two-fold interpenetrating 3D architecture. Complexes 1 and 2 had fluorescent properties. 1 was highly selective and sensitive towards nitrobenzene and Fe³⁺ ion through different detection mechanisms, while CP 2 was highly selective and sensitive towards 2,4,6-trinitrophenol and CrO₄^2- ion.
- cadmium(Ⅱ),
- coordination polymers,
- crystal structure,
- fluorescent properties
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