Citation: Li-Yu LI, Qiu-Feng SHI, Hai-Jie GUO, Cai-E CUI, Ping HUANG, Lei WANG. Preparation and luminescence properties of Eu²⁺ doped MgY₂Al₃Si₂O₁₁N cyan-emitting light phosphor[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(1): 63-70. doi: 10.11862/CJIC.2022.271 shu

Preparation and luminescence properties of Eu²⁺ doped MgY₂Al₃Si₂O₁₁N cyan-emitting light phosphor

School of Physics, Taiyuan University of Technology, Jinzhong, Shanxi 030600, China

Corresponding author: Lei WANG, wanglei_keke@163.com
Received Date: 19 June 2022
Revised Date: 8 October 2022

Figures(6)

A series of Eu²⁺ doped MgY₂Al₃Si₂O₁₁N (MYASON) cyan-emitting phosphors were synthesized by a high-temperature solid-state method. The effects of three preparation methods on the phase structure and luminous intensity of phosphor were discussed in detail. By comparing the XRD patterns and fluorescence intensity of samples, it was proved that H₂/N₂ as a reducing atmosphere was conducive to obtaining pure phase and good luminescence properties. X-ray diffraction refinement and X-ray photoelectron spectroscopy proved that Si⁴⁺-N^3- ion pair was successfully doped into the garnet lattice. The emission spectrum of the sample showed asymmetric broadband emission at 420-750 nm. With the increase of Eu²⁺ doping concentration, the emission intensity of the phosphor was quenched by concentration. The quenching mechanism is electric multipole interaction. In addition, the thermal stability of the sample was studied by variable temperature spectrum, and its activation energy (ΔE) was calculated to be 0.22 eV. The results show that MYASON∶Eu²⁺ phosphor exhibited asymmetric broadband emission in the cyanemitting light region when excited by 365 nm ultraviolet light, and the peak value was 490 nm, which can effectively provide cyan-emitting light components for the white light emitting diode excited by the ultraviolet chip.
- photoluminescence,
- cyan-emitting phosphor,
- white light emitting diode,
- garnet,
- oxynitride
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Preparation and luminescence properties of Eu2+ doped MgY2Al3Si2O11N cyan-emitting light phosphor

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Preparation and luminescence properties of Eu²⁺ doped MgY₂Al₃Si₂O₁₁N cyan-emitting light phosphor