Citation: Jing-Ya LI, Wen-Ru HUANG, Feng WANG, Yan-Yan ZHOU. Highly sensitive detection of small molecular weight amines based on an amino alcohol modified β-diketonate europium complex[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(1): 71-79. doi: 10.11862/CJIC.2022.265 shu

Highly sensitive detection of small molecular weight amines based on an amino alcohol modified β-diketonate europium complex

1.
Baotou Research Institute of Rare Earths, State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization, Baotou, Inner Mongolia 014030, China
2.
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China

Corresponding author: Yan-Yan ZHOU, zhouyanyan@hlju.edu.cn
Received Date: 7 June 2022
Revised Date: 5 October 2022

Figures(10)

As a kind of volatile toxic amines, organic small-molecule amines do great harm to human health. Therefore, the detection of organic small-molecule amines has attracted extensive attention. Lanthanide luminescence sensors stand out among all kinds of fluorescent sensors because of their easy synthesis, high biocompatibility, and high sensitivity. However, the large ion radius and unstable coordination configuration of lanthanide ions make it a challenge to achieve high-sensitivity luminescence detection of organic small-molecule amines in the solid state. The mononuclear lanthanide complex [Eu(L)₃(H₂O)₂] (HL=(2Z)-1-(4-(bis(2-hydroxyethyl)amino)phenyl)-4, 4, 4-trifluoro-3-hydroxybut-2-en-1-one) with intraligand charge transfer (ILCT) properties was successfully constructed by the coordination of the mono-β-diketone ligand with the lanthanide ion europium by introducing the amine alcohol recognition group. The sensing study of the complex showed that [Eu(L)₃(H₂O)₂] exhibited obvious luminescence enhancement response to small organic amines such as tripropylamine under weak nucleophilic action.
- lanthanide complex,
- luminous sensor,
- organic small-molecule amines,
- detection
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