Citation: Qing-Tang ZHANG, Zong-Qiang XU, Qi-Qi SHU, Fei LIAN. Preparation and lithium storage properties of nitrogen, sulfur heteroatom hard carbon by pyrolysis of conjugated microporous polymers[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(1): 45-54. doi: 10.11862/CJIC.2022.263 shu

Preparation and lithium storage properties of nitrogen, sulfur heteroatom hard carbon by pyrolysis of conjugated microporous polymers

School of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou 730050, China

Corresponding author: Qing-Tang ZHANG, zhqt137@163.com Zong-Qiang XU, 1967685817@qq.com
Received Date: 30 May 2022
Revised Date: 6 October 2022

Figures(9)

A bottom-up approach was employed to build a thiazole-containing conjugated microporous polymer (NSCMP) by choosing bromo-thiazole and triacetylene benzene as monomers. The pyrolyzation and KOH-assisted pyrolyzation of NSCMP were performed to obtain the N, S heteroatom hard carbon (NSHC) and KOH-activated NSHC (KNSHC). NSHC and KNSHC were further characterized by scanning electronic microscope, energy-dispersive spectra (EDS), nitrogen adsorption-desorption, galvanostatic charge-discharging test, etc. The EDS revealed that the N and S mass fractions of KNSHC were 10.42% and 2.23%, respectively. The specific surface area of KNSHC was as high as 2 140 m²·g^-1, which was distinctly higher than that of NSHC (657 m²·g^-1). The specific capacity of KNSHC after 500 cycles at 0.2 A·g^-1 was as high as 946.2 mAh·g^-1, while that of NSHC was only 493.7 mAh·g^-1. The excellent electrochemical performance of KNSHC may be due to the synergistic effect of N and S heteroatoms as well as the unique porous structure.
- conjugated microporous polymer,
- hard carbon,
- anode material,
- lithium ion battery
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