Citation: Sheng-Ding XUE, Jun GU, Meng-Fei HAN, Su-Jun ZHU, Tao YU. Preparation of platinum catalysts supported on oxygen-boron co-modification multi-wall carbon nanotubes and their oxygen reducing activity[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(2): 281-290. doi: 10.11862/CJIC.2022.262 shu

Preparation of platinum catalysts supported on oxygen-boron co-modification multi-wall carbon nanotubes and their oxygen reducing activity

Sheng-Ding XUE ¹ ,
Jun GU ^{1, 2, 3,,} ,
Meng-Fei HAN ¹ ,
Su-Jun ZHU ¹ ,
Tao YU ^{1, 4}

1.
School of Physics, Nanjing University, Nanjing 210093, China
2.
Nanjing Doinpower Technology Co., Ltd., Nanjing 211100, China
3.
National Laboratory of Solid State Microstructures, Nanjing 210093, China
4.
Nantong Institute of Materials Engineering Nanjing University, Nantong, Jiangsu 226019, China

Corresponding author: Jun GU, junguca@nju.edu.cn
Received Date: 22 July 2022
Revised Date: 21 October 2022

Figures(7)

We synthesized an oxygen-boron co-decorated multi-walled carbon nanotube material by a simple method. After that, it was used as a carrier to prepare platinum-based catalysts and carried out a variety of characterizations. The results indicated that the platinum particles supported on this carrier showed smaller particle size, higher electrochemical surface area (40 m²·g_Pt^-1), and higher oxygen reduction activity (0.3 A·mg_Pt^-1). Predictably, boron and oxygen play an important role in improving the dispersion of carbon nanotubes, controlling the uniformity and size of platinum particles, and promoting oxygen adsorption/dissociation in the oxygen reduction reaction.
- catalyst,
- carbon nanotubes,
- platinum,
- boron,
- oxygen-reducing activity
1. [1]
  Tomas M, Gholami F, Gholami Z, Sedlacek J. Catalysts for oxygen reduction reaction in the polymer electrolyte membrane fuel cells: A brief review[J]. Electrochem, 2021,2(4):590-603. doi: 10.3390/electrochem2040037
2. [2]
  GAO W T, LEI Y J, ZHANG X, HU X B, SONG P P, ZHAO Q, WANG C, MAO Z Q. An overview of proton exchange membrane fuel cell[J]. Chem. Ind. Eng. Prog., 2022,41(3):1539-1555.
3. [3]
  LUO Y, FENG J Z, FENG J, JIANG Y G, LI L J. Research progress on advanced carbon materials as Pt support for proton exchange membrane fuel cells[J]. J. Inorg. Mater., 2020,35(4):407-415.
4. [4]
  Pollet B G S S. Support materials for PEMFC and DMFC electrocatalysts-A review[J]. J. Power Sources, 2012,208:96-119. doi: 10.1016/j.jpowsour.2012.02.011
5. [5]
  XU C, TANG H L, MU S C, PAN M, YUAN R Z. Progress on synthesis of Pt/CNTs electro-catalyst for proton exchange membrane fuel cell[J]. Chinese Journal of Power Sources, 2004,28(10):652-655.
6. [6]
  WU Z P, ZHANG W B, YIN Y H, LI Y S, CHEN Y S, YANG J G, LIU Y, XU Q F. Preparation of highly dispersed and ultrafine Pt particles on carbon nanotubes used as an effective electrochemical catalyst[J]. Rare Metal Mater. Eng., 2015,44(6):1351-1356.
7. [7]
  Jung N, Chung D Y, Ryu J, Yoo S J, Sung Y E. Pt-based nanoarchitecture and catalyst design for fuel cell applications[J]. Nano Today, 2014,9(4):433-456. doi: 10.1016/j.nantod.2014.06.006
8. [8]
  Shahgaldi S, Hamelin J. Improved carbon nanostructures as a novel catalyst support in the cathode side of PEMFC: A critical review[J]. Carbon, 2015,94:705-728. doi: 10.1016/j.carbon.2015.07.055
9. [9]
  Kim J, Lee S W, Carlton C, Shao-Horn Y. Pt-covered multiwall carbon nanotubes for oxygen reduction in fuel cell applications[J]. J. Phys. Chem. Lett., 2011,2(11):1332-1336. doi: 10.1021/jz200531z
10. [10]
  Li L Y, Liu H Q, Wang L, Yue S Y, Tong X, Zaliznyak T, Taylor G T, Wong S S. Chemical strategies for enhancing activity and charge transfer in ultrathin pt nanowires immobilized onto nanotube supports for the oxygen reduction reaction[J]. ACS Appl. Mater. Interfaces, 2016,8(50):34280-34294. doi: 10.1021/acsami.6b07870
11. [11]
  FU X B, YU H, PENG F, WANG H J, LÜ P. Preparation and characterization of highly dispersed platinum nanoparticles supported on carbon nanotubes[J]. Chinese J. Inorg. Chem., 2006,22(6):1148-1154. doi: 10.3321/j.issn:1001-4861.2006.06.034
12. [12]
  Wang Q Q, Dai N N, Zheng J S, Zheng J P. Preparation and catalytic performance of Pt supported on Nafion^® functionalized carbon nanotubes[J]. J. Electroanal. Chem., 2019,854113508. doi: 10.1016/j.jelechem.2019.113508
13. [13]
  Xiao F, Meng Y, Lin Z P, Lei Y, Chen X H, Zhang J K, Lu H Y, Tong Y P, Liu G C, Xu J T. Highly boron-doped holey graphene for lithium oxygen batteries with enhanced electrochemical performance[J]. Carbon, 2022,189:404-412. doi: 10.1016/j.carbon.2021.12.061
14. [14]
  Lei Z D, Chen H B, Yang M, Yang D G, Li H M. Boron and oxygencodoped porous carbon as efficient oxygen reduction catalysts[J]. Appl. Surf. Sci., 2017,426:294-300. doi: 10.1016/j.apsusc.2017.07.183
15. [15]
  Rani P, Jindal V K. Designing band gap of graphene by B and N dopant atoms[J]. RSC Adv., 2013,3(3):802-812. doi: 10.1039/C2RA22664B
16. [16]
  Van Khai T, Na H G, Kwak D S, Kwon Y J, Ham H, Shim K B, Kim H W. Comparison study of structural and optical properties of borondoped and undoped graphene oxide films[J]. Chem. Eng. J., 2012,211:369-377.
17. [17]
  Vinayan B P, Jafri R I, Nagar R, Rajalakshmi N, Sethupathi K, Ramaprabhu S. Catalytic activity of platinum-cobalt alloy nanoparticles decorated functionalized multiwalled carbon nanotubes for oxygen reduction reaction in PEMFC[J]. Int. J. Hydrog. Energy, 2012,37(1):412-421. doi: 10.1016/j.ijhydene.2011.09.069
18. [18]
  Ma Z H, Tian H, Meng G, Peng L X, Chen Y F, Chen C, Chang Z W, Cui X Z, Wang L J, Jiang W, Shi J L. Size effects of platinum particles@CNT on HER and ORR performance[J]. Sci. China Mater., 2020,63(12):2517-2529. doi: 10.1007/s40843-020-1449-2
19. [19]
  YAO Y L, ZHANG D, XIA X H. Study on deposition mechanism of Pt nanoparticles on carbon nanotube[J]. Chinese J. Inorg. Chem., 2004,20(5):531-535.
20. [20]
  Gan J, Zhang J K, Zhang B Y, Chen W Y, Niu D F, Qin Y, Duan X Z, Zhou X G. Active sites engineering of Pt/CNT oxygen reduction catalysts by atomic layer deposition[J]. J. Energy Chem., 2020,45:59-66. doi: 10.1016/j.jechem.2019.09.024
21. [21]
  Antolini E, Giorgi L, Pozio A, Passalacqua E. Influence of Nafion loading in the catalyst layer of gas-diffusion electrodes for PEFC[J]. J. Power Sources, 1999,77(2):136-142. doi: 10.1016/S0378-7753(98)00186-4
22. [22]
  Jukk K, Kozlova J, Ritslaid P, Sammelselg V, Alexeyeva N, Tammeveski K. Sputter-deposited Pt nanoparticle/multi-walled carbon nanotube composite catalyst for oxygen reduction reaction[J]. J. Electroanal. Chem., 2013,708:31-38.
23. [23]
  Yao R, Gu J, He H T, Yu T. Improved electrocatalytic activity and durability of Pt nanoparticles supported on boron-doped carbon black[J]. Catalysts, 2020,10(8)862.
24. [24]
  Glavee G N, Klabunde K J, Sorensen C M, Hadjapanayis G C. Borohydride reductions of metal ions. a new understanding of the chemistry leading to nanoscale particles of metals, borides, and metal borates[J]. Langmuir, 1992,8(3):771-773.
25. [25]
  He D P, Zhang L B, He D S, Zhou G, Lin Y, Deng Z X, Hong X, Wu Y E, Chen C, Li Y D. Amorphous nickel boride membrane on a platinum-nickel alloy surface for enhanced oxygen reduction reaction[J]. Nat. Commun., 2016,7(1)12362.
26. [26]
  Stamenkovic V, Mun B S, Mayrhofer K J, Ross P N, Markovic N M, Rossmeisl J, Greeley J, Nørskov J K. Changing the activity of electrocatalysts for oxygen reduction by tuning the surface electronic structure[J]. Angew. Chem. Int. Ed., 2006,45(18):2897-2901.
27. [27]
  Viswanathan V, Hansen H A, Rossmeisl J, Nørskov J K. Universality in oxygen reduction electrocatalysis on metal surfaces[J]. ACS Catal., 2012,2(8):1654-1660.
28. [28]
  He D P, Mu S C, Pan M. Perfluorosulfonic acid-functionalized Pt/carbon nanotube catalysts with enhanced stability and performance for use in proton exchange membrane fuel cells[J]. Carbon, 2011,49(1):82-88.
29. [29]
  Yin S B, Shen P K, Song S Q, Jiang S P. Functionalization of carbon nanotubes by an effective intermittent microwave heating-assisted HF/H₂O₂ treatment for electrocatalyst support of fuel cells[J]. Electrochim. Acta, 2009,54(27):6954-6958.
30. [30]
  Hussain S, Erikson H, Kongi N, Merisalu M, Ritslaid P, Sammelselg V, Tammeveski K. Heat-treatment effects on the ORR activity of Pt nanoparticles deposited on multi-walled carbon nanotubes using magnetron sputtering technique[J]. Int. J. Hydrog. Energy, 2017,42(9):5958-5970.
31. [31]
  He C X, Song S Q, Liu J C, Maragou V, Tsiakaras P. Koh-activated multi-walled carbon nanotubes as platinum supports for oxygen reduction reaction[J]. J. Power Sources, 2010,195(21):7409-7414.
32. [32]
  Molina-García M A, Rees N V. Effect of Catalyst carbon supports on the oxygen reduction reaction in alkaline media: A comparative study[J]. RSC Adv., 2016,6(97):94669-94681.
33. [33]
  Bogdanovskaya V, Vernigor I, Radina M, Andreev V, Korchagin O. Nanocomposite cathode catalysts containing platinum deposited on carbon nanotubes modified by O, N, and P atoms[J]. Catalysts, 2021,11(3)335.
34. [34]
  Kim H, Jeong N J, Lee S J, Song K S. Electrochemical deposition of Pt nanoparticles on CNTs for fuel cell electrode[J]. Korean J. Chem. Eng., 2008,25(3):443-445.
35. [35]
  Liu J, Yin J, Feng B, Xu T, Wang F. Enhanced electrocatalytic activity and stability toward the oxygen reduction reaction with unprotected Pt nanoclusters[J]. Nanomaterials, 2018,8(11)955.
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
3. [3]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
4. [4]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
5. [5]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
6. [6]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
7. [7]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
8. [8]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
9. [9]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
10. [10]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
11. [11]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
12. [12]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
13. [13]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
14. [14]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
15. [15]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
16. [16]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
17. [17]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
18. [18]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
19. [19]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
20. [20]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(492)
HTML views(27)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142