Citation: Yu-Ting ZHAO, Lin SUN, Ying XU, Bing-Xin YANG, Qi LIU, Mei-Ling CHENG. Mn(Ⅱ)/Zn(Ⅱ) Complexes Based on 3, 4-Pyrazoledicarboxylic Acid: Syntheses, Structures, and Luminescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(12): 2530-2538. doi: 10.11862/CJIC.2022.248 shu

Mn(Ⅱ)/Zn(Ⅱ) Complexes Based on 3, 4-Pyrazoledicarboxylic Acid: Syntheses, Structures, and Luminescent Properties

Yu-Ting ZHAO ¹ ,
Lin SUN ¹ ,
Ying XU ¹ ,
Bing-Xin YANG ¹ ,
Qi LIU ^{1, 2} ,
Mei-Ling CHENG ^1,,

1.
School of Petrochemical Engineering, and Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University, Changzhou, Jiangsu 213164, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Corresponding author: Mei-Ling CHENG, chengmeiling01@163.com
Received Date: 18 July 2022
Revised Date: 23 September 2022

Figures(6)

In the presence of N ancillary ligands, imidazole (ImH) and 5-(4-pyridyl)tetrazole (4-PT), treatment of 3, 4-pyrazoledicarboxylic acid (H₃pdc) with corresponding Mn(Ⅱ)/Zn(Ⅱ) metal salts afforded two complexes, [Mn(Hpdc) (ImH)(H₂O)]_n (1) and [Zn(Hpdc)(4-PT)(H₂O)₃]·2H₂O (2). In the 1D coordination polymer 1 and mononuclear complex 2, the Hpdc^2- ligand adopted μ₂-κ∶O, N; κ∶O', O″ coordination mode and O, N-chelating mode, respectively, while the ImH and 4-PT ligands in 1 and 2 both acted as a monodentate ligand. In 1, in the influence of intermolecular N—H⋯O and O—H⋯O hydrogen bonds, the 1D coordination chains are packed into a 3D supramolecular structure. In 2, in the function of intermolecular O—H⋯O and O—H⋯N hydrogen bonds, the adjacent mononuclear components [Zn(Hpdc)(4-PT)(H₂O)₃] are packed into 2D structures, then these 2D layers and the lattice water molecules are interlinked and generated a 3D supramolecular architecture. Moreover, the luminescent properties of complexes 1 and 2 as well as the electrochemical property of 1 were also investigated.
- 3, 4-pyrazoledicarboxylic acid,
- synthesis,
- crystal structure,
- fluorescence
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